US4873286A
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Modified polyphenylene ether-polyamide compositions and process
Assignee: General Electric Co
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Filing: 1988-04-14
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Granted: 1989-10-10
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Expires: 2008-04-14
Abstract
Abstract Novel modified polyphenylene ether-polyamide compositions comprising polyphenylene ether, polyamide and a polycarboxylic acid and the reaction product thereof and an improved process for preparing the same.
Inventors
- 👤 Robert R. Gallucci
- 👤 Roelof van der Meer
- 👤 Roger W. Avakian
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 07:55
CPC Classifications
C; C08; C08L; C08L71/00; C08L71/08; C08L71/10; C08L71/12; C08K; C08K5/00; C08K5/04; C08K5/09; C08K5/092; C08K5/098; C08K5/10; C08K5/11; C08K5/16; C08K5/20; C08L71/123; C08L77/00; C08L67/00; C08L69/00; C08L71/02; C08L75/00; C08L79/00; C08L79/04; C08L79/08; C08L81/00; C08L83/00; Y; Y10; Y10S; Y10S525/00; Y10S525/905
Claims Analysis
Total Claims: 30
Claim 1
Independent Claim
261 words
An improved process for the preparation of polyphenylene ether-polyamide compositions wherein the improvement comprises precompounding from about 0.05 to about 4% by weight, based on the total composition, of one or more aliphatic polycarboxylic acid represented by the formula: (R.sup.I O).sub.m R(COOR.sup.II).sub.n (CONR.sup.III R.sup.IV).sub.s or derivatives thereof wherein R is a linear or branched chain, saturated aliphatic hydrocarbon of from 2 to 20 carbon atoms; R I is selected from the group consisting of hydrogen or an alkyl, aryl, acyl or carbonyl dioxy group of from 1 to 10 carbon atoms; each R II is independently selected from the group consisting of hydrogen or an alkyl or aryl group of from 1 to 20 carbon atoms; each R III and R IV is independently selected from the group consisting of hydrogen or an alkyl or aryl group of from 1 to 10 carbon atoms; m is equal to 1 and (n+s) is greater than or equal to 2, and n and s are each greater than or equal to 0; and wherein (OR I ) is alpha or beta to a carbonyl group and at least 2 carbonyl groups are separated by 2 to 6 carbon atoms, with the polyphenylene ether and a modifier resin prior to compounding with the polyamide in order to enhance the impact strength of the final composition; said modifier resin having been derived from vinyl aromatic monomers, the blending ratio of polyphenylene ether to polyamide being from 5 to 95 percent by weight of the former to 95 to 5 percent by weight of the latter.
Claim 2
Dependent Claim
261 words
An improved process for the preparation of polyphenylene ether-polyamide compositions wherein the improvement comprises precompounding from about 0.05 to about 4% by weight, based on the total composition, of one or more aliphatic polycarboxylic acid represented by the formula: (R.sup.I O).sub.m R(COOR.sup.II).sub.n (CONR.sup.III R.sup.IV).sub.s or derivatives thereof wherein R is a linear or branched chain, saturated aliphatic hydrocarbon of from 2 to 20 carbon atoms; R I is selected from the group consisting of hydrogen or an alkyl, aryl, acyl or carbonyl dioxy group of from 1 to 10 carbon atoms; each R II is independently selected from the group consisting of hydrogen or an alkyl or aryl group of from 1 to 20 carbon atoms; each R III and R IV is independently selected from the group consisting of hydrogen or an alkyl or aryl group of from 1 to 10 carbon atoms; m is equal to 1 and (n+s) is greater than or equal to 2, and n and s are each greater than or equal to 0; and wherein (OR I ) is alpha or beta to a carbonyl group and at least 2 carbonyl groups are separated by 2 to 6 carbon atoms, with the polyphenylene ether and a modifier resin prior to compounding with the polyamide in order to enhance the impact strength of the final composition; said modifier resin having been derived from vinyl aromatic monomers, the blending ratio of polyphenylene ether to polyamide being from 5 to 95 percent by weight of the former to 95 to 5 percent by weight of the latter.
Claim 3
Dependent Claim
156 words
The process of claim 1 wherein the polycarboxylic acid is represented by the formula: (R.sup.I O).sub.m R(COOR.sup.II).sub.n (CONR.sup.III R.sup.IV).sub.s or derivative thereof wherein R is a linear or branched chain, saturated aliphatic hydrocarbon of from 2 to 10 carbon atoms; R I is selected from the group consisting of hydrogen or an alkyl, aryl, acyl or carbonyl dioxy group of from 1 to 6 carbon atoms; each R II is independently selected from the group consisting of hydrogen or an alkyl or aryl group of from 1 to 10 carbon atoms; each R III and R IV is independently selected from the group consisting essentially of hydrogen or an alkyl or aryl group of from 1 to 6 carbon atoms; m is equal to 1 and (n+s) is equal to 2 or 3, and n and s are each greater than or equal to 0 and wherein (OR I ) is alpha to the carbonyl group.
Claim 4
Dependent Claim
105 words
The process of claim 1 wherein the polycarboxylic acid is represented by the formula: (R.sup.I O).sub.m R(COOR.sup.II).sub.n or derivative thereof wherein R is a linear or branched saturated aliphatic hydrocarbon of 2 to 10 carbon atoms, R I is selected from the group consisting of hydrogen or an alkyl, acyl or carbonyldioxy group of from 1 to 6 carbon atoms, R II is selected from the group consisting of hydrogen or an alkyl group of from 1 to 20 carbon atoms; m is equal to 1 and n is equal to 2 or 3 and wherein (OR I ) is alpha to the carbonyl group.
Claim 5
Dependent Claim
24 words
The process of claim 1 wherein the polycarboxylic acid is selected from the group consisting essentially of citric acid, malic acid and salts thereof.
Claim 6
Dependent Claim
29 words
The process of claim 1 wherein the amount of polycarboxylic acid employed is from about 0.1 to about 2% by weight based on the weight of the total composition.
Claim 7
Dependent Claim
32 words
The process of claim 1 wherein the ratio of polyphenylene ether to polyamide is from 30 to 70% by weight of the former to 70 to 30% by weight of the latter.
Claim 8
Dependent Claim
105 words
The process of claim 1 wherein the polyphenylene ether is a homoplymer or a copolymer having units with the repeating structural formula: ##STR3## wherein the oxygen ether atom of one unit is connected to the benzene nucleus of the next joining unit, and n is a positive integer and is at least 50, and each Q is independently a monovalent substituent selected from a group consisting of hydrogen, halogen, hydrocarbon and hydrocarbonoxy groups free of a tertiary alpha-carbon atom and halohydrocarbon and halohydrocarbonoxy groups free of a tertiary alpha-carbon atom and having at least 2 carbon atoms between the halogen atom and the phenyl nucleus.
Claim 9
Dependent Claim
12 words
The process of claim 1 wherein the polyphenylene ether is poly(2,6 dimethyl-1,4-phenylene)ether.
Claim 10
Dependent Claim
24 words
The process of claim 1 wherein the polyamide is selected from the group consisting of polyamide 6; polyamide 6,6; polyamide 12 and polyamide 6/10.
Claim 11
Dependent Claim
11 words
The process of claim 1 wherein the polyamide is polyamide 6/6.
Claim 12
Dependent Claim
21 words
The process of claim 1 which further comprises admixing therewith up to 3% by weight of a primary or secondary amine.
Claim 13
Dependent Claim
18 words
The process of claim 11 wherein the amine is precompounded with the polyphenylene ether and the polycarboxylic acid.
Claim 14
Dependent Claim
17 words
The process of claim 11 wherein the amine is prereacted with the polycarboxylic acid prior to precompounding.
Claim 15
Dependent Claim
250 words
An improved process for the preparation of polyphenylene ether-polyamide compositions wherein the improvement comprises precompounding one or more aliphatic polycarboxylic acid represented by the formula: (R.sup.I O).sub.m R(COOR.sup.II).sub.n (CONR.sup.III R.sup.IV).sub.s or derivatives thereof wherein R is a linear of branched chain, saturated aliphatic hydrocarbon of from 2 to 20 carbon atoms; R I is selected from the group consisting of hydrogen or an alkyl, aryl, acyl or carbonyl dioxy group of from 1 to 10 carbon atoms; each R II is independently selected from the group consisting of hydrogen or an alkyl or aryl group of from 1 to 20 carbon atoms; each R III and R IV is independently selected from the group consisting of hydrogen or an alkyl or aryl group of from 1 to 10 carbon atoms; m is equal to 1 and (n+s) is greater than or equal to 2, and n and s are each greater than or equal to 0; and wherein (OR I ) is alpha or beta to a carbonyl group and at least 2 carbonyl groups are separated by 2 to 6 carbon atoms in an amount sufficient to enhance the impact strength of the polyphenylene ether-polyamide composition, with the polyphenylene ether and a modifier resin prior to compounding with the polyamide, said modifier resin having been derived from vinyl aromatic monomers, the blending ratio of polyphenylene ether to polyamide being from 5 to 95 percent by weight of the former to 95 to 5 percent by weight of the latter.
Claim 16
Dependent Claim
250 words
An improved process for the preparation of polyphenylene ether-polyamide compositions wherein the improvement comprises precompounding one or more aliphatic polycarboxylic acid represented by the formula: (R.sup.I O).sub.m R(COOR.sup.II).sub.n (CONR.sup.III R.sup.IV).sub.s or derivatives thereof wherein R is a linear of branched chain, saturated aliphatic hydrocarbon of from 2 to 20 carbon atoms; R I is selected from the group consisting of hydrogen or an alkyl, aryl, acyl or carbonyl dioxy group of from 1 to 10 carbon atoms; each R II is independently selected from the group consisting of hydrogen or an alkyl or aryl group of from 1 to 20 carbon atoms; each R III and R IV is independently selected from the group consisting of hydrogen or an alkyl or aryl group of from 1 to 10 carbon atoms; m is equal to 1 and (n+s) is greater than or equal to 2, and n and s are each greater than or equal to 0; and wherein (OR I ) is alpha or beta to a carbonyl group and at least 2 carbonyl groups are separated by 2 to 6 carbon atoms in an amount sufficient to enhance the impact strength of the polyphenylene ether-polyamide composition, with the polyphenylene ether and a modifier resin prior to compounding with the polyamide, said modifier resin having been derived from vinyl aromatic monomers, the blending ratio of polyphenylene ether to polyamide being from 5 to 95 percent by weight of the former to 95 to 5 percent by weight of the latter.
Claim 17
Dependent Claim
92 words
A process for the preparation of polyphenylene ether-polyamide compositions, said composition being derived from citric acid, a polyphenylene ether, a modifier resin and a polyamide, said process comprising precompounding said citric acid with said polyphenylene ether and said modifier resin prior to compounding with said polyamide, said modifier resin being selected from the group consisting of polymer resins derived from vinyl aromatic monomers, the blending ratio of polyphenylene ether to polyamide being from 5 to 95 percent by weight of the former to 95 to 5 percent by weight of the latter.
Claim 18
Dependent Claim
92 words
A process for the preparation of polyphenylene ether-polyamide compositions, said composition being derived from citric acid, a polyphenylene ether, a modifier resin and a polyamide, said process comprising precompounding said citric acid with said polyphenylene ether and said modifier resin prior to compounding with said polyamide, said modifier resin being selected from the group consisting of polymer resins derived from vinyl aromatic monomers, the blending ratio of polyphenylene ether to polyamide being from 5 to 95 percent by weight of the former to 95 to 5 percent by weight of the latter.
Claim 19
Dependent Claim
11 words
The process of claim 15, wherein said polyamide is polyamide 6,6.
Claim 20
Dependent Claim
12 words
The process of claim 15, wherein said polyphenylene ether is poly(2,6 dimethyl-1,4-phenylene)ether.
Claim 21
Dependent Claim
24 words
The process of claim 15 wherein said modifier resin is selected from the group consisting of polystyrene-polybutadiene; polystyrene-polyisoprene; poly(alpha-methylstyrene)-polybutadiene; polystyrene-polybutadiene-polystyrene; polystyrene-polyisoprene-polystyrene; poly(alpha-methylstyrene)-polybutadiene-poly-(alpha-methylstyrene); and poly(alpha-methylstyrene)-polyisoprene-poly-(alpha-methystyrene).
Claim 22
Dependent Claim
93 words
A process for the preparation of polyphenylene ether-polyamide composition, said composition being derived from citric acid, a polyphenylene ether, a modifier resin and a polyamide, said process comprising precompounding said citric acid with said polyphenylene ether and said modifier resin prior to compounding with said polyamide, said polyphenylene ether being poly(2,6 dimethyl-1,4-phenylene)-ether, said modifier resin being polystyrene-polybutadiene-polystyrene triblock copolymer, said polyamide being polyamide 6,6, the blending ratio of polyphenylene ether to polyamide being from 5 to 95 percent by weight of the former to 95 to 5 percent by weight of the latter.
Claim 23
Dependent Claim
93 words
A process for the preparation of polyphenylene ether-polyamide composition, said composition being derived from citric acid, a polyphenylene ether, a modifier resin and a polyamide, said process comprising precompounding said citric acid with said polyphenylene ether and said modifier resin prior to compounding with said polyamide, said polyphenylene ether being poly(2,6 dimethyl-1,4-phenylene)-ether, said modifier resin being polystyrene-polybutadiene-polystyrene triblock copolymer, said polyamide being polyamide 6,6, the blending ratio of polyphenylene ether to polyamide being from 5 to 95 percent by weight of the former to 95 to 5 percent by weight of the latter.
Claim 24
Dependent Claim
116 words
A process for the preparation of polyphenylene ether-polyamide composition, said composition being derived from citric acid, a polyphenylene ether, a modifier resin and a polyamide, said process comprising precompounding said citric acid with said polyphenylene ether and said modifier resin prior to compounding with said polyamide, said polyphenylene ether being poly(2,6 dimethyl-1,4-phenylene)ether, said modifier resin being polystyrene-polybutadiene-polystyrene triblock copolymer, said polyamide being polyamide 6,6, wherein said polyphenylene ether is present at a level of about 45 percent by weight of said composition, said polyamide is present at a level of about 45 percent by weight of said composition, and said citric acid is present at a level of about 0.7 percent by weight of said composition.
Claim 25
Dependent Claim
116 words
A process for the preparation of polyphenylene ether-polyamide composition, said composition being derived from citric acid, a polyphenylene ether, a modifier resin and a polyamide, said process comprising precompounding said citric acid with said polyphenylene ether and said modifier resin prior to compounding with said polyamide, said polyphenylene ether being poly(2,6 dimethyl-1,4-phenylene)ether, said modifier resin being polystyrene-polybutadiene-polystyrene triblock copolymer, said polyamide being polyamide 6,6, wherein said polyphenylene ether is present at a level of about 45 percent by weight of said composition, said polyamide is present at a level of about 45 percent by weight of said composition, and said citric acid is present at a level of about 0.7 percent by weight of said composition.
Claim 26
Dependent Claim
128 words
A process for the preparation of a composition derived from melt blending polyphenylene ether resin, polyamide resin, citric acid and a modifier resin derived from vinyl aromatic monomers, the blending ratio of polyphenylene ether to polyamide being 5 to 95 percent by weight of the former to 95 to 5 percent by weight of the latter, the citric acid being present at a level of from 0.05 to 4 percent by weight based on the total composition, said modifier resin being present at a level of from 5 to 50 parts by weight based on 100 parts by weight of the combined weight of polyphenylene ether and polyamide, said process comprising: (a) precompounding the citric acid with polyphenylene ether; (b) compounding polyamide with the precompounded citric acid/polyphenylene ether.
Claim 27
Dependent Claim
128 words
A process for the preparation of a composition derived from melt blending polyphenylene ether resin, polyamide resin, citric acid and a modifier resin derived from vinyl aromatic monomers, the blending ratio of polyphenylene ether to polyamide being 5 to 95 percent by weight of the former to 95 to 5 percent by weight of the latter, the citric acid being present at a level of from 0.05 to 4 percent by weight based on the total composition, said modifier resin being present at a level of from 5 to 50 parts by weight based on 100 parts by weight of the combined weight of polyphenylene ether and polyamide, said process comprising: (a) precompounding the citric acid with polyphenylene ether; (b) compounding polyamide with the precompounded citric acid/polyphenylene ether.
Claim 28
Dependent Claim
14 words
The process of claim 21 wherein said citric acid is a citric acid ester.
Claim 29
Dependent Claim
14 words
The process of claim 21 wherein said modifier resin is a styrene-butadiene-styrene triblock copolymer.
Claim 30
Dependent Claim
34 words
The process of claim 21 wherein the blending ratio of polyphenylene ether to polyamide is 30 to 70 percent by weight of the former to 70 to 30 percent by weight of the latter.
References Cited (Backward Citations)
US3379792A
Cited
US3356761A
Cited
US3700630A
Cited
US4071494A
Cited
US4373064A
Cited
US4338421A
Cited
US4315086A
Cited
EP0046040A1
Cited
US4419478A
Cited
JPS5966452A
Cited
JPH117250A
Cited
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