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US4868004A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for creating a corrosion-resistant, largely absorption-free coating on the surface of a workpiece

Assignee: Balzers und Leybold Deutschland Holding AG
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Filing: 1988-02-03
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Granted: 1989-09-19
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Expires: 2008-02-03
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Abstract

Abstract In a method for creating a corrosion-resistant coating (27) of high reflectivity on the surface of a workpiece (22), especially a glass reflector insert, in an evacuable coating chamber with a vaporizing system disposed therein, a second coating (24) of aluminum is deposited cold from a vapor onto a first, cold-applied coating (23) forming an adhesion mediator of nickel-chromium oxide, and onto that a third coating (25) of SiO 2 is applied cold, and a fourth coating (26) of TiO 2 or Ta 2 O 5 is applied at a workpiece temperature of at least 250° C., and finally, as a fifth coating (27), a nickel-chromium oxide layer is deposited reactively from a vapor at a workpiece temperature of at least 250° C. The deposit of the first, third, fourth and fifth coatings (23, 25, 26, 27) from a vapor is performed by means of electron beam vaporizers and the vapor depositing of the second coating (24) is performed by means of a resistance vaporizer.

Inventors

  • 👤 Walter Zultzke
  • 👤 Andreas Grunewald

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 11:01
CPC Classifications
C; C03; C03C; C03C17/00; C03C17/34; C03C17/36; C03C17/3602; C03C17/3618; C03C17/3649; C03C17/3657; C23; C23C; C23C14/00; C23C14/06; C23C14/08; C23C14/083; C23C14/10; G02B1/105; G; G02; G02B; G02B1/00; G02B1/10; G02B1/14; C03C2217/00; C03C2217/70; C03C2217/78

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 173 words
A method for producing a corrosion-resistant, largely absorption-free coating on the surface of a substrate workpiece in an evacuable coating chamber having vaporizing means disposed therein, comprising depositing an adhesion mediator first layer comprising an 80/20 NiCr alloy onto said substrate to a thickness of about 100 Angstroms; applying from a vapor a second, reflection producing coating of aluminum to a thickness of abut 1000 Angstroms onto said first layer; applying a third coating of SiO 2 having a low refractive index at a thickness of λ/4; applying a fourth coating selected from the group consisting of TiO 2 or T 2 O 5 having a high refractive index at a temperature of at least 250° C. to a thickness of λ/4; and applying a fifth coating reactively from a vapor at a temperature of at least 250° C., said layer being applied as a 80/20 NiCr oxide coating to a thickness between 25 to 50 Angstroms onto said fourth coating of high refractive index, said NiCr alloy being evaporated for this purpose.
Claim 2
Independent Claim 173 words
A method for producing a corrosion-resistant, largely absorption-free coating on the surface of a substrate workpiece in an evacuable coating chamber having vaporizing means disposed therein, comprising depositing an adhesion mediator first layer comprising an 80/20 NiCr alloy onto said substrate to a thickness of about 100 Angstroms; applying from a vapor a second, reflection producing coating of aluminum to a thickness of abut 1000 Angstroms onto said first layer; applying a third coating of SiO 2 having a low refractive index at a thickness of λ/4; applying a fourth coating selected from the group consisting of TiO 2 or T 2 O 5 having a high refractive index at a temperature of at least 250° C. to a thickness of λ/4; and applying a fifth coating reactively from a vapor at a temperature of at least 250° C., said layer being applied as a 80/20 NiCr oxide coating to a thickness between 25 to 50 Angstroms onto said fourth coating of high refractive index, said NiCr alloy being evaporated for this purpose.
Claim 3
Dependent Claim 35 words
The method defined in claim 1 wherein said fourth layer has a refractive index between about 2.0 and 2.4 and said NiCr alloys comprising said fifth coating contain ratios between about 75/25 and about 85/15.
Claim 4
Independent Claim 24 words
The method defined in claim I wherein said vaporizing means for depositing said first, third, fourth and fifth coatings in an electron beam vaporizer.
Claim 5
Dependent Claim 20 words
The method defined in claim 1 wherein said vapor depositing of said second coating is performed by a resistance vaporizer.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-09-18 1993-03-20 1993-09-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-09-18 1997-03-20 1997-09-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-09-18 2001-03-20 2001-09-19 $7700.00 Window Closed / Lapsed

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