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US4867792A Expired / Lapsed US ⏱️ 0.0 years remaining

Tire balancing composition

Assignee: EVERBALANCE AG
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Filing: 1988-02-05
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Granted: 1989-09-19
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Expires: 2008-02-05
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Abstract

Abstract A thixotropic tire balancing composition having a yield stress value between 30 Pa and 260 Pa, preferably about 120 Pa, is capable of balancing air by being capable of flowing under the influence of the vibrations induced when a heavy spot on the tire contacts the road surface. The composition preferably comprises a mixture of: (1) a liquid di- or trihydric alcohol or a di-, tri-, or tetrameric oligomer thereof, optionally containing water; (2) a polymer soluble or dispersible in the alcohol; (3) hydrophilic fibers; and, optionally, ( 4) a hydrophilic filler. The alcohol 1) is preferably a diol of the general formula HO-(CH(R)-CH 2 -O) n -H wherein R is hydrogen or C 1-2 alkyl and n is an integer from 1 to 4.

Inventors

  • 👤 Alvin Ronlan

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 02:03
CPC Classifications
G; G01; G01M; G01M1/00; G01M1/30; G01M1/36; G01M1/365; B; B60; B60C; B60C19/00; B60C19/003; B60C5/00; B60C5/004; F; F16; F16F; F16F15/00; F16F15/10; F16F15/16; F16F15/32; F16F15/36; F16F15/366

Claims Analysis

Total Claims: 34
Claim 1
Independent Claim 140 words
A thixotropic tire balancing composition having a yield stress value between 30 Pa and 260 Pa at temperatures between -30° C. and +90° C. comprising the following components: (1) a liquid di- or trihydric alcohol, a di-, tri- or tetrameric oligomer of said alcohol or a mixture of water and said alcohol or said oligomer; (2) a polymer which is soluble or dispersible in component (1) selected from the group consisting of C 1-3 alkyl cellulose, hydroxy-C 1-3 alkyl cellulose, carboxymethyl cellulose, a polymer of an acid of the general formula R 1 HC=C(R 2 )COOH wherein R 1 and R 2 are independently hydrogen, C 1-2 alkyl, hydroxy-C 1-4 alkyl or carboxy-C 1-4 alkyl and mixtures thereof; and (3) a hydrophilic fiber selected from the group consisting of viscose, cotton, wool, cellulose, silk, a hemp fiber and mixtures thereof.
Claim 2
Dependent Claim 140 words
A thixotropic tire balancing composition having a yield stress value between 30 Pa and 260 Pa at temperatures between -30° C. and +90° C. comprising the following components: (1) a liquid di- or trihydric alcohol, a di-, tri- or tetrameric oligomer of said alcohol or a mixture of water and said alcohol or said oligomer; (2) a polymer which is soluble or dispersible in component (1) selected from the group consisting of C 1-3 alkyl cellulose, hydroxy-C 1-3 alkyl cellulose, carboxymethyl cellulose, a polymer of an acid of the general formula R 1 HC=C(R 2 )COOH wherein R 1 and R 2 are independently hydrogen, C 1-2 alkyl, hydroxy-C 1-4 alkyl or carboxy-C 1-4 alkyl and mixtures thereof; and (3) a hydrophilic fiber selected from the group consisting of viscose, cotton, wool, cellulose, silk, a hemp fiber and mixtures thereof.
Claim 3
Dependent Claim 20 words
The composition as claimed in claim 1 in which the yield stress value is between 40 Pa and 150 Pa.
Claim 4
Dependent Claim 17 words
The composition as claimed in claim 2 in which the yield stress value is about 120 Pa.
Claim 5
Dependent Claim 47 words
The composition as claimed in claim 11, in which component (1) is a liquid alcohol, wherein the alcohol is a diol of the general formula HO-(CH(R)-CH 2 -O) n -H, wherein R is hydrogen or C 1-2 alkyl and n is an integer from 1 to 4.
Claim 6
Dependent Claim 19 words
The composition as claimed in claim 1 having a pH value in the range of from 5 to 9.
Claim 7
Dependent Claim 27 words
The composition as claimed in claim 11, which further comprises component (4), wherein component (4) is a hydrophilic filler which is insoluble in water and component (1).
Claim 8
Dependent Claim 19 words
The composition as claimed in claim 5, wherein the pH is in the range of from 6 to 7.
Claim 9
Dependent Claim 33 words
The composition as claimed in claim 4 in which the diol is selected from the group consisting of ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, dipropylene glycol tripropylene glycol and mixtures thereof.
Claim 10
Dependent Claim 28 words
The composition as claimed in claim 1 in which the hydrophilic fibers have a length in the range 0.5-6 mm and a thickness in the range 1-25 μm.
Claim 11
Dependent Claim 23 words
The composition as claimed in claim 6 in which the hydrophilic filler of component (4) is a metal oxide, carbonate, hydroxide, or silicate.
Claim 12
Dependent Claim 37 words
The composition as claimed in claim 10 in which the hydrophilic filler is selected from the group consisting of CaCO 3 , BaCO 3 , MgO, Fe 3 O 4 , kaolin, TiO 2 and mixtures thereof.
Claim 13
Dependent Claim 24 words
The composition as claimed in claim 10 or 11 in which the hydrophilic filler has a particle size in the range of 5.25 μm.
Claim 14
Dependent Claim 18 words
The composition as claimed in claim 12, wherein the particle size is in the range of 10-15 μm.
Claim 15
Dependent Claim 18 words
The composition as claimed in claim 5 which further component (5), wherein component (5) is a pH-buffering agent.
Claim 16
Dependent Claim 24 words
The composition as claimed in 14 in which the buffering agent of component (5) is a soluble hydroxide, an amine or an amine derivative.
Claim 17
Dependent Claim 29 words
The composition as claimed in 15 in which the buffering agent is selected from the group consisting of NaOH, NH 4 OH, triethanol amine, diethanol amine and mixtures thereof.
Claim 18
Dependent Claim 62 words
The composition as claimed in claim 14 comprising 30-90% by weight of the alcohol of component (1), 3-40% by weight of the polymer of component (2), 0.5-6% by weight of component (3), 0-20% by weight of the filler of component (4) as defined in claim 7, and 0-10% by weight of the pH-buffering agent of component (5) as defined in claim 15.
Claim 19
Dependent Claim 39 words
The composition as claimed in claim 17 comprising 50-80% by weight of the alcohol, 5-20% by weight of the polymer, 2-5% by weight of the hydrophilic fibers, 5-15%, of the filler, and 0-10% by weight of the pH-buffering agent.
Claim 20
Independent Claim 247 words
A method for preparing a thixotropic tire balancing composition having a yield stress value between 30 Pa and 260 Pa at temperatures between -30° C. and +90° C. comprising a reaction product produced by reacting a reaction mixture, which comprises forming a reaction mixture comprising: (1) a liquid di- or trihydric alcohol, a di-, tri- or tetrameric oligomer of said alcohol or a mixture of water and said alcohol or said oligomer; (2) a polymer containing free carboxy groups and which is soluble or dispersible in component (1) selected from the group consisting of carboxymethyl cellulose, a polymer of an acid of the general formula R 1 HC=C(R 2 )COOH wherein R 1 and R 2 are independently hydrogen, C 1-2 alkyl, hydroxy-C 1-4 alkyl or carboxy-C 1-4 alkyl and mixtures thereof; and (3) a hydrophilic fiber optionally containing free hydroxy groups selected from the group consisting of viscose, cotton, a cellulose fiber and mixtures thereof, said method comprising the following steps: (a) dispersing the hydrophilic fiber of component (3) in component (1); (b) adding the polymer of component (2); (c) stirring until a homogenous mixture is obtained forming the reaction mixture, adding a cross-linking catalyst to the reaction mixture and subjecting said reaction mixture to a crosslinking reaction; (d) optionally dispersing component (4), wherein component (4) is a hydrophilic filler which is insoluble in water and component (1), in the resulting product of the crosslinking reaction of step (c); and optionally (e) inactivating the crosslinking catalyst.
Claim 21
Independent Claim 247 words
A method for preparing a thixotropic tire balancing composition having a yield stress value between 30 Pa and 260 Pa at temperatures between -30° C. and +90° C. comprising a reaction product produced by reacting a reaction mixture, which comprises forming a reaction mixture comprising: (1) a liquid di- or trihydric alcohol, a di-, tri- or tetrameric oligomer of said alcohol or a mixture of water and said alcohol or said oligomer; (2) a polymer containing free carboxy groups and which is soluble or dispersible in component (1) selected from the group consisting of carboxymethyl cellulose, a polymer of an acid of the general formula R 1 HC=C(R 2 )COOH wherein R 1 and R 2 are independently hydrogen, C 1-2 alkyl, hydroxy-C 1-4 alkyl or carboxy-C 1-4 alkyl and mixtures thereof; and (3) a hydrophilic fiber optionally containing free hydroxy groups selected from the group consisting of viscose, cotton, a cellulose fiber and mixtures thereof, said method comprising the following steps: (a) dispersing the hydrophilic fiber of component (3) in component (1); (b) adding the polymer of component (2); (c) stirring until a homogenous mixture is obtained forming the reaction mixture, adding a cross-linking catalyst to the reaction mixture and subjecting said reaction mixture to a crosslinking reaction; (d) optionally dispersing component (4), wherein component (4) is a hydrophilic filler which is insoluble in water and component (1), in the resulting product of the crosslinking reaction of step (c); and optionally (e) inactivating the crosslinking catalyst.
Claim 22
Dependent Claim 31 words
The method as claimed in claim 19 in which the crosslinking catalyst is an acid, and the inactivation of the catalyst is carried out by neutralizing the acid with a base.
Claim 23
Dependent Claim 56 words
A method for balancing a motor vehicle assembly comprising a tire, which comprises: applying a tire thixotropic balancing composition as defined in claim 1 to the inner surface of the tire, mounting the wheel assembly on a motor vehicle, and driving the vehicle for a distance sufficient to allow the composition to balance the wheel assembly.
Claim 24
Dependent Claim 25 words
The method as claimed in claim 21 in which the balancing composition is applied in a layer having a thickness of up to 6 mm.
Claim 25
Dependent Claim 29 words
The composition as in claim 11 in which the polymer of component (2) is selected from the group consisting of methyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose and mixtures thereof.
Claim 26
Independent Claim 203 words
A method for preparing a thixotropic tire balancing composition having a yield stress value between 30 Pa and 260 Pa at temperatures between -30° C. and +90° C. comprising the following components: (1) a liquid di- or trihydric alcohol, a di-, tri- or tetrameric oligomer of said alcohol or a mixture of water and said alcohol or said oligomer; (2) a polymer which is soluble or dispersible in component (1) selected from the group consisting of C 1-3 alkyl cellulose, hydroxy-C 1-3 alkyl cellulose, carboxymethyl cellulose, a polymer of an acid of the general formula R 1 HC=C(R 2 )COOH wherein R 1 and R 2 are independently hydrogen, C 1-2 alkyl, hydroxy-C 1-4 alkyl or carboxy-C 1-4 alkyl and mixtures thereof; and (3) a hydrophilic fiber selected from the group consisting of viscose, cotton, wool, cellulose, silk, a hemp fiber and mixtures thereof; and optionally (4) a hydrophilic filler which is insoluble in water and component (1), said method comprising the following steps: (a) dispersing the hydrophilic fiber of component (3) in component (1); (b) adding the polymer of component (2); (c) stirring until a homogenous mixture is obtained; and optionally (d) dispersing the hydrophilic filler of component (4) in said mixture.
Claim 27
Independent Claim 203 words
A method for preparing a thixotropic tire balancing composition having a yield stress value between 30 Pa and 260 Pa at temperatures between -30° C. and +90° C. comprising the following components: (1) a liquid di- or trihydric alcohol, a di-, tri- or tetrameric oligomer of said alcohol or a mixture of water and said alcohol or said oligomer; (2) a polymer which is soluble or dispersible in component (1) selected from the group consisting of C 1-3 alkyl cellulose, hydroxy-C 1-3 alkyl cellulose, carboxymethyl cellulose, a polymer of an acid of the general formula R 1 HC=C(R 2 )COOH wherein R 1 and R 2 are independently hydrogen, C 1-2 alkyl, hydroxy-C 1-4 alkyl or carboxy-C 1-4 alkyl and mixtures thereof; and (3) a hydrophilic fiber selected from the group consisting of viscose, cotton, wool, cellulose, silk, a hemp fiber and mixtures thereof; and optionally (4) a hydrophilic filler which is insoluble in water and component (1), said method comprising the following steps: (a) dispersing the hydrophilic fiber of component (3) in component (1); (b) adding the polymer of component (2); (c) stirring until a homogenous mixture is obtained; and optionally (d) dispersing the hydrophilic filler of component (4) in said mixture.
Claim 28
Dependent Claim 12 words
The thixotropic tire balancing composition produced by the method of claim 19.
Claim 29
Dependent Claim 56 words
A method for balancing a motor vehicle assembly comprising a tire, which comprises: applying a tire thixotropic balancing composition as defined in claim 19 to the inner surface of the tire, mounting the wheel assembly on a motor vehicle, and driving the vehicle for a distance sufficient to allow the composition to balance the wheel assembly.
Claim 30
Dependent Claim 25 words
The method as claimed in claim 26 in which the balancing composition is applied in a layer having a thickness of up to 6 mm.
Claim 31
Dependent Claim 142 words
A thixotropic tire balancing composition having a yield stress value between 30 pa and 260 Pa at temperatures between -30° C. and +90° C. consisting essentially of the following components: (1) a liquid di or trihydric alcohol, a di-, tri- or tetrameric oligomer of said alcohol or a mixture of water and said alcohol or said oligomer; (2) a polymer which is soluble or dispersible in component (1) selected from the group consisting of C 1-3 alkyl cellulose, hydroxy-C 1-3 alkyl cellulose, carboxymethyl cellulose, a polymer of an acid of the general formula R 1 HC=C(R 2 )COOH wherein R 1 and R 2 are independently hydrogen, C 1-2 alkyl, hydroxy-C 1-4 alkyl or carboxy-C 1-4 alkyl and mixtures thereof; and (3) a hydrophilic fiber selected from the group consisting of viscose, cotton, wool, cellulose, silk, a hemp fiber and mixtures thereof.
Claim 32
Dependent Claim 142 words
A thixotropic tire balancing composition having a yield stress value between 30 pa and 260 Pa at temperatures between -30° C. and +90° C. consisting essentially of the following components: (1) a liquid di or trihydric alcohol, a di-, tri- or tetrameric oligomer of said alcohol or a mixture of water and said alcohol or said oligomer; (2) a polymer which is soluble or dispersible in component (1) selected from the group consisting of C 1-3 alkyl cellulose, hydroxy-C 1-3 alkyl cellulose, carboxymethyl cellulose, a polymer of an acid of the general formula R 1 HC=C(R 2 )COOH wherein R 1 and R 2 are independently hydrogen, C 1-2 alkyl, hydroxy-C 1-4 alkyl or carboxy-C 1-4 alkyl and mixtures thereof; and (3) a hydrophilic fiber selected from the group consisting of viscose, cotton, wool, cellulose, silk, a hemp fiber and mixtures thereof.
Claim 33
Dependent Claim 24 words
A wheel assembly comprising a tire having a tire-thixotropic balancing composition as defined in claim 11 deposited on the inner surface of the tire.
Claim 34
Dependent Claim 24 words
A wheel assembly comprising a tire having a tire-thixotropic balancing composition as defined in claim 19 deposited on the inner surface of the tire.

References Cited (Backward Citations)

US4139395A Cited
US4101494A Cited
US4701016A Cited
US4713114A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-09-18 1993-03-20 1993-09-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-09-18 1997-03-20 1997-09-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-09-18 2001-03-20 2001-09-19 $7700.00 Window Closed / Lapsed

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