Process for preparing a web with an abrasion resistant resilient backing

Claim 2

A process for preparing a flexible web backed with a dense abrasion resistant, dimensionally stable foam comprising: (a) applying substantially uniformly over a planar surface of said web a first layer of material selected from the group consisting of: (i) a frothed gellable compound having a density of from 200-1000 g/l based on a latex of a rubbery polymer; and (ii) a uniform non-woven fleece having a thickness from about 0.6 to 7.6 cm. and weighing from about 8 to 210 g/m 2 ; (b) applying substantially uniformly over said first layer, a second layer of material which is the material not used for the first layer; provided that the compound saturates the fleece and the surface of the web and the dry weight of the compound and web is from 16 to 2100 g/m 2 ; (c) compressing said web and said layers to not less than one third of their original thickness of the web and the layers; (d) gelling said compound before said fleece significantly expands; and (e) drying and vulcanizing said backing.

Claim 3

A process for preparing a flexible web backed with a dense abrasion resistant, dimensionally stable foam comprising: (a) applying substantially uniformly over a planar surface of said web a first layer of material selected from the group consisting of: (i) a frothed gellable compound having a density of from 200-000 g/l based on a latex of a rubbery polymer; and (ii) a uniform non-woven fleece having a thickness from about 0.6 to 7.6 cm and weighing from about 8 to 210 g/m 2 ; (b) applying substantially uniformly over said first layer, a second layer of material which is the material not used for the first layer; provided that the compound saturates the fleece and the surface of the web and the dry weight of the compound and web is from 16 to 2100 g/m 2 ; (c) compressing said web and said layers to not less than one third of their original thickness of the web and the layers; (d) gelling said compound before said fleece significantly expands; and (e) drying and vulcanizing said backing; and further characterized in that said rubbery polymer is selected from the group consisting of: (a) polymers comprising: (i) from 15 to 60 weight percent of a C 8-12 vinyl or vinylidene aromatic monomer which may be unsubstituted or substituted of a C 1-4 alkyl radical or a chlorine or bromine atom; and (ii) from about 85 to 40 weight percent of a C 4-6 aliphatic conjugated diolefin which may be unsubstituted or substituted by a chlorine atom; (b) polymers comprising: (i) from 5 to 40 weight percent of a C 3-8 alkenyl nitrile; and (ii) from 95 to 60 weight to a C 4-6 aliphatic conjugated diolefin. (c) polymers comprising: (i) from 70 to 100 weight percent of one or more monomers selected from the group consisting of C 1-8 alkyl and hydroxyalkyl esters of C 3-6 ethylenically unsaturated carboxylic acids; and (ii) up to 30 eight percent of a C 8-12 vinyl or vinylidene aromatic monomer which may be unsubstituted or substituted by a C 1-4 alkyl radical or a chlorine atom; and (d) polymers comprising: (i) from 5 to 40 weight percent of a C 2-3 olefin; and (ii) from 95 to 60 weight percent of one or more monomers selected from the group consisting of C 2-8 alkenyl or hydroxy alkenyl esters of C 1-8 saturated carboxylic acids and C 1-8 alkyl and hydroxyalkyl esters of C 3-6 ethylenically unsaturated carboxylic acids.

Claim 4

A process for preparing a flexible web backed with a dense abrasion resistant, dimensionally stable foam comprising: (a) applying substantially uniformly over a planar surface of said web a first layer of material selected from the group consisting of: (i) a frothed gellable compound having a density of from 200-000 g/l based on a latex of a rubbery polymer; and (ii) a uniform non-woven fleece having a thickness from about 0.6 to 7.6 cm and weighing from about 8 to 210 g/m 2 ; (b) applying substantially uniformly over said first layer, a second layer of material which is the material not used for the first layer; provided that the compound saturates the fleece and the surface of the web and the dry weight of the compound and web is from 16 to 2100 g/m 2 ; (c) compressing said web and said layers to not less than one third of their original thickness of the web and the layers; (d) gelling said compound before said fleece significantly expands; and (e) drying and vulcanizing said backing; and further characterized in that said rubbery polymer is selected from the group consisting of: (a) polymers comprising: (i) from 15 to 60 weight percent of a C 8-12 vinyl or vinylidene aromatic monomer which may be unsubstituted or substituted of a C 1-4 alkyl radical or a chlorine or bromine atom; and (ii) from about 85 to 40 weight percent of a C 4-6 aliphatic conjugated diolefin which may be unsubstituted or substituted by a chlorine atom; (b) polymers comprising: (i) from 5 to 40 weight percent of a C 3-8 alkenyl nitrile; and (ii) from 95 to 60 weight to a C 4-6 aliphatic conjugated diolefin. (c) polymers comprising: (i) from 70 to 100 weight percent of one or more monomers selected from the group consisting of C 1-8 alkyl and hydroxyalkyl esters of C 3-6 ethylenically unsaturated carboxylic acids; and (ii) up to 30 eight percent of a C 8-12 vinyl or vinylidene aromatic monomer which may be unsubstituted or substituted by a C 1-4 alkyl radical or a chlorine atom; and (d) polymers comprising: (i) from 5 to 40 weight percent of a C 2-3 olefin; and (ii) from 95 to 60 weight percent of one or more monomers selected from the group consisting of C 2-8 alkenyl or hydroxy alkenyl esters of C 1-8 saturated carboxylic acids and C 1-8 alkyl and hydroxyalkyl esters of C 3-6 ethylenically unsaturated carboxylic acids.

Claim 5

A process according to claim 2 where in said compound contains a gelling system selected from the group consisting of: (a) from about 2 to 10 parts by weight per 100 parts by weight of polymer of a silicon polyether of the formula I ##STR3## wherein: R is a C 1-4 alkyl radical R' is a C 1-7 alkyl radical or a C 6-12 aryl radical; A is a C 1-7 divalent hydrocarbon radical; a has a value from 0.5 to 1 inclusive; b has a value from 1.12 to 1.90 inclusive; and the sum of a+b is from 2.02 to 2.40 inclusive; n is an integer from 2 to 4 inclusive; and x is from 10 to 100, (b) a mixture comprising per 100 parts by weight of polymer 0.05 to 1.0 parts by weight of a silicone ether of formula I in combination with from 4 to 20 parts by weight of an aromatic sulfate of the formula II: R--[A--SO.sub.3 ]--M (II) wherein: R is a C 8-20 alkyl or alkenyl radical; A is a benzene ring; and M is an alkali or alkaline earth metal; (c) from about 1 to 20 parts by weight per 100 parts by weight of polymer of a tertiary ether of the formula III ##STR4## wherein: a is zero or one; x and y are integers and the sum of x+y is from 5 to 30, and R is a fatty acid radical optionally in combination with: from 0.5 to 2 parts by weight per 100 parts by weight of polymer of a silicon either of formula I; or from 1 to 10 parts by weight per 100 parts by weight of polymer of an aromatic sulfate of formula II; (d) from 0.3 to 8 parts by weight per 100 parts by weight of polymer of an ammonium or alkali metal silicofluoride optionally in combination with 6 parts of weight per 100 parts by weight of polymer of one or more members selected from the group consisting of ammonium sulfate, ammonium sulfamates; C 1-4 alkyl amine sulfates; C 1-4 alkyl amine sulfamates; and (e) per 100 parts by weight of polymer a sufficient amount of one or more of the following compounds to provide from 0.1 to 6 parts by weight of ammonium ions; ammonia, ammonium hydroxide, ammonium chloride, ammonium salts of C 1-6 alphatic carboxylic acids; ammonium sulfate; and C 1-4 alkyl amines together with from 0.1 to 10 parts by weight of a bivalent metal ion.

Claim 6

A process, according to claim 3, wherein the first layer is a fleece about 1.2 to 3.8 cm. thick, weighing from 65 to 15 g/m 2 .

Claim 7

A process according to claim 4, therein said fleece is made of one or more fibers selected from the group consisting of: polyester, polyamide, cellulose, regenerated cellulose, and glass.

Claim 8

A process, according to claim 5, wherein the polymer comprises: from about 20 to 40 weight percent of styrene and from about 80 to 60 weight percent of butadiene.

Claim 9

A process, according to claim 4, wherein the compound contains per 100 parts of polymer up to about 150 parts by weight of one or more fillers, selected from the group consisting of calcium carbonate, talc, clay, aluminum trihydrate and barytes, and the compound is frothed to a density from 450 to 500 g/l.

Claim 10

A process, according to claim 7, wherein the gelling agent is selected from the group consisting of alkali, metal salts of silicofluorides and binary mixtures of ammonium salts (of C 1-6 carboxylic acids) ammonium hydroxyide or a C 1-4 alkyl amine in the presence of a bivalent metal ion.

Claim 11

A process, according to claim 8, wherein the gelling agent is present is an amount from 0.5 to 2.5 parts by weight per 100 parts of polymer and is sodium silicofluoride.

Claim 12

A process, according to claim 8, wherein the gelling agent is a binary gelling agent, one member being selected from the group ammonia, ammonium hydroxide and ammonium acetate, being present in an amount to provide from 0.3 to 4 parts of ammonia or ammonium ions per 100 parts of polymer and the second member selected from the group consisting zinc oxide and cadmium oxide in an amount from about 1 to 5 parts by weight per 100 parts by weight of polymer.

Claim 13

A process, according to claim 9, wherein said compound further comprises from 0.1 to 4.0 parts by weight of ammonium sulfamate per 100 parts by weight of polymer.

Claim 14

A process, according to claim 10, wherein said compound further comprises from 0.1 to 4.0 parts by weight of ammonium sulfamate per 100 parts by weight of polymer.

Claim 15

A process, according to claim 11, wherein the crushing and gelling stages are conducted simultaneously by passing the web and the two layers around a drum laminator at a temperature from 75° to 150°.

Claim 16

A process, according to claim 12, wherein the crushing and gelling stages are conducted simultaneously by passing the web and the two layers around a drum laminator at a temperature from 75° to 150°.

Claim 17

A process, according to claim 12, wherein said fleece and foamed compound are crushed; heated from 75° to 150° C. for not more than 10 minutes to gel the compound, then dried and vulcanized in a hot air circulating oven at temperatures from 275° to 325°.

Claim 18

A process, according to claim 13, wherein said fleece and foamed compound are crushed; heated from 75° to 150° C. not more than 10 minutes to gel the compound, then dried and vulcanized in a hot air circulating oven at temperatures from 275° to 325°.