Patent US4863801A successfully refreshed from Google Patents.
US4863801A
Expired / Lapsed
US
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Surface treatment of pet film
Assignee: 3M Co
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Filing: 1987-11-20
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Granted: 1989-09-05
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Expires: 2007-11-20
Abstract
Abstract Antistatic protection can be provided to a substrate by providing two coatings or layers to the substrate. The first layer is a blend of two different polymers or copolymers that crosslink within the coating and the second layer is a subbing layer. This coated substrate is particularly useful for photographic media.
Inventors
- 👤 Angelo Vallarino
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 11:36
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/76; G03C1/795; G03C1/7954; G03C1/91; G03C1/93; Y; Y10; Y10S; Y10S428/00; Y10S428/913; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31511; Y10T428/31515; Y10T428/31652; Y10T428/31663; Y10T428/31786; Y10T428/31797
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
118 words
A support layer for use with photosensitive media comprising (a) polyester film, (b) on at least one surface of said polyester film, a primer layer comprising a crosslinked blend of at least two polymers, one of said polymers containing a reactive epoxy group and the other of said polymers containing a free hydrogen containing group or salified free hydrogen containing group, and (c) on said primer layer a subbing layer comprising a carrying medium and an ambifunctional silane coupling agent having the formula: (Q).sub.n --R--Si(OR.sup.1).sub.3 wherein R 1 is alkyl or aryl, R is an organic group with (n+1) external bonds, n is 0, 1, or 2 and Q is a moiety reactive with photographic hardeners or gelatin.
Claim 2
Dependent Claim
118 words
A support layer for use with photosensitive media comprising (a) polyester film, (b) on at least one surface of said polyester film, a primer layer comprising a crosslinked blend of at least two polymers, one of said polymers containing a reactive epoxy group and the other of said polymers containing a free hydrogen containing group or salified free hydrogen containing group, and (c) on said primer layer a subbing layer comprising a carrying medium and an ambifunctional silane coupling agent having the formula: (Q).sub.n --R--Si(OR.sup.1).sub.3 wherein R 1 is alkyl or aryl, R is an organic group with (n+1) external bonds, n is 0, 1, or 2 and Q is a moiety reactive with photographic hardeners or gelatin.
Claim 3
Dependent Claim
22 words
The support layer of claim 1 wherein said carrying medium comprises either colloidal silica or a mixture of gelatin and sulfonated polymer.
Claim 4
Dependent Claim
21 words
The support layer of claim 1 wherein said carrying medium comprises a continuous, porous network of gelled inorganic metal oxide particles.
Claim 5
Dependent Claim
18 words
The support layer of claim 1 wherein said carrying medium comprises a mixture of gelatin and sulfonated polymer.
Claim 6
Dependent Claim
13 words
The support layer of claim 1 wherein said polyester film comprises polyethyleneterephthalate film.
Claim 7
Dependent Claim
13 words
The support layer of claim 4 wherein said polyester film comprises polyethyleneterephthalate film.
Claim 8
Dependent Claim
55 words
The support layer of claim 1 wherein said polymer containing a reactive epoxy group comprises from 5 to 50% by weight of units derived from monomers which contain reactive epoxy groups and said free hydrogen group containing polymer comprises from 0.5% to 20% by weight of units derived from monomers containing free hydrogen containing groups.
Claim 9
Dependent Claim
55 words
The support layer of claim 3 wherein said polymer containing a reactive epoxy group comprises from 5 to 50% by weight of units derived from monomers which contain reactive epoxy groups and said free hydrogen group containing polymer comprises from 0.5% to 20% by weight of units derived from monomers containing free hydrogen containing groups.
Claim 10
Dependent Claim
56 words
The support layer of claim 5 wherein said polymer containing a reactive epoxy group comprises from 10 to 40 percent by weight of units derived from monomers which contain reactive epoxy groups and said free hydrogen group containing polymer comprises from 1 to 10% by weight of units derived from monomers containing free hydrogen containing groups.
Claim 11
Dependent Claim
29 words
The support layer of claim 1 wherein said free hydrogen containing groups are selected from the group consisting of hydroxyl groups, carboxylic acid groups, and primary and secondary amines.
Claim 12
Dependent Claim
29 words
The support layer of claim 2 wherein said free hydrogen containing groups are selected from the group consisting of hydroxyl groups, carboxylic acid groups, and primary and secondary amines.
Claim 13
Dependent Claim
29 words
The support layer of claim 3 wherein said free hydrogen containing groups are selected from the group consisting of hydroxyl groups, carboxylic acid groups, and primary and secondary amines.
Claim 14
Dependent Claim
29 words
The support layer of claim 9 wherein said free hydrogen containing groups are selected from the group consisting of hydroxyl groups, carboxylic acid groups, and primary and secondary amines.
Claim 15
Dependent Claim
27 words
The support layer of claim 1 wherein R 1 is an alkyl of 1 to 10 carbon atoms and R is an aliphatic or aromatic bridging group.
Claim 16
Dependent Claim
17 words
The support layer of claim 14 wherein Q comprises an epoxy, primary amino, or secondary amino group.
Claim 17
Dependent Claim
29 words
The support layer of claim 15 wherein R is selected from alkylene, arylene, alkarylene, and aralkylene of 1 to 12 carbon atoms which may contain ether or nitrogen linkages.
Claim 18
Dependent Claim
55 words
The support layer of claim 2 wherein R 1 is an alkyl of 1 to 10 carbon atoms, Q comprises an epoxy, primary amino, or secondary amino group, and R is selected from the group consisting of alkylene, arylene, alkarylene, and arylalkylene of 1 to 12 carbon atoms which may contain ether or nitrogen linkages.
Claim 19
Dependent Claim
55 words
The support layer of claim 3 wherein R 1 is an alkyl of 1 to 10 carbon atoms, Q comprises an epoxy, primary amino, or secondary amino group, and R is selected from the group consisting of alkylene, arylene, alkarylene, and arylalkylene of 1 to 12 carbon atoms which may contain ether or nitrogen linkages.
Claim 20
Dependent Claim
55 words
The support layer of claim 4 wherein R 1 is an alkyl of 1 to 10 carbon atoms, Q comprises an epoxy, primary amino, or secondary amino group, and R is selected from the group consisting of alkylene, arylene, alkarylene, and arylalkylene of 1 to 12 carbon atoms which may contain ether or nitrogen linkages.
Claim 21
Dependent Claim
55 words
The support layer of claim 5 wherein R 1 is an alkyl of 1 to 10 carbon atoms, Q comprises an epoxy, primary amino, or secondary amino group, and R is selected from the group consisting of alkylene, arylene, alkarylene, and arylalkylene of 1 to 12 carbon atoms which may contain ether or nitrogen linkages.
Claim 22
Dependent Claim
55 words
The support layer of claim 7 wherein R 1 is an alkyl of 1 to 10 carbon atoms, Q comprises an epoxy, primary amino, or secondary amino group, and R is selected from the group consisting of alkylene, arylene, alkarylene, and arylalkylene of 1 to 12 carbon atoms which may contain ether or nitrogen linkages.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1992-09-04 | 1993-03-06 | 1993-09-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-09-04 | 1997-03-06 | 1997-09-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-09-04 | 2001-03-06 | 2001-09-05 | $7700.00 | Window Closed / Lapsed |