Photographic element and process comprising a compound which comprises two timing groups in sequence

Claim 2

In a photographic element comprising a support, at least one photographic emulsion layer and at least one compound A capable upon reaction in a coupling position with an oxidized color developing agent of releasing a photographically useful group, the improvement wherein the compound A comprises at least two differing timing groups in sequence capable, upon activation, of timing the release of the photographically useful group and wherein two separate fragments are formed from the two differing timing groups upon processing the photographic element.

Claim 3

In a photographic element comprising a support, at least one photographic emulsion layer and at least one coupler capable upon reaction in a coupling position with an oxidized color developing agent of releasing a photographically useful group, the improvement wherein the coupler comprises at least two differing timing groups in sequence capable, upon activation, of timing the release of the photographically useful group and wherein two separate fragments are formed from the two differing timing groups upon processing the photographic element.

Claim 4

In a photographic element comprising a support, at least one photographic emulsion layer and at least one coupler capable upon reaction in a coupling position with an oxidized color developing agent of releasing a photographically useful group, the improvement wherein the coupler comprises at least two differing timing groups in sequence capable, upon activation, of timing the release of the photographically useful group and wherein two separate fragments are formed from the two differing timing groups upon processing the photographic element.

Claim 5

A photographic element as in claim 1 or 2 wherein one of the two differing groups in sequence is a group capable of intramolecular nucleophilic displacement of the remaining portion of the compound A.

Claim 6

A photographic element as in claim 1 or 2 wherein one of the two differing groups in sequence is a group capable of a reaction in which an electron is transferred down a conjugated chain to release the remaining portion of the compound A.

Claim 7

A photographic element as in claim 1 or 2 wherein the photographically useful group is a releasable development inhibitor, developing agent, development accelerator, bleach inhibitor, bleach accelerator, dye, dye precursor, stabilizer, nucleator, fixing agent, image toner, hardener, antifoggant, or ultraviolet radiation absorber.

Claim 8

A photographic element as in claim 1 or 2 wherein the compound A or coupler yields a colorless product on reaction with oxidized color developing agent.

Claim 9

A photographic element as in claim 2 wherein the coupler is represented by the structure: COUP--T.sub.1 --T.sub.2 --PUG wherein: COUP is a coupler moiety; T 1 is a first timing group capable of being released from COUP at the coupling position of COUP by reaction of COUP with oxidized color developer; T 2 is a second timing group capable of being released from said first timing group after said first timing group is released from COUP; and, PUG is a photographically useful group.

Claim 10

A photographic element comprising a support, at least one photographic silver halide emulsion layer and at least one coupler capable upon reaction with oxidized color developing agent of releasing a photographically useful group; wherein the coupler comprises at least two differing timing groups, in sequence capable, upon activation, of timing the release of the photographically useful group; wherein two separate fragments are formed from the two differing timing groups upon processing the photographic element; and the coupler is represented by the formula: ##STR80## wherein: R 26 is substituted or unsubstituted alkyl, or substituted or unsubstituted aryl; R 27 is hydrogen or a substituent which does not adversely affect timing of release of the other portions of the photographic coupler; R 28 is hydrogen or a substituent which advantageously influences the timing of release of PUG; COUP is a coupler moiety substituted in the coupling position by the remainder of the coupler; PUG is a photographically useful group; m and n are individually 0 or 1; Z 5 represents the atoms necessary to complete a carbocyclic or heterocyclic ring.

Claim 11

A photographic element comprising a support, at least one photographic silver halide emulsion layer and at least one coupler capable upon reaction with oxidized color developing agent of releasing a photographically useful group; wherein the coupler comprises at least two differing timing groups, in sequence capable, upon activation, of timing the release of the photographically useful group; wherein two separate fragments are formed from the two differing timing groups upon processing the photographic element; and the coupler is represented by the formula: ##STR80## wherein: R 26 is substituted or unsubstituted alkyl, or substituted or unsubstituted aryl; R 27 is hydrogen or a substituent which does not adversely affect timing of release of the other portions of the photographic coupler; R 28 is hydrogen or a substituent which advantageously influences the timing of release of PUG; COUP is a coupler moiety substituted in the coupling position by the remainder of the coupler; PUG is a photographically useful group; m and n are individually 0 or 1; Z 5 represents the atoms necessary to complete a carbocyclic or heterocyclic ring.

Claim 12

A photographic element as in claim 8 wherein the coupler is represented by the structure: ##STR81## wherein: R 29 is substituted or unsubstituted alkyl, substituted or unsubstituted aryl, or R 34 NH; R 30 is substituted or unsubstituted alkyl, or substituted or unsubstituted aryl; R 31 is a hydrogen or a ballast group; R 32 is alkyl; R 33 is unsubstituted or substituted alkyl, chlorine, bromine, nitro, or alkoxy; PUG is a photographically useful group; and n is 0, 1 or 2.

Claim 13

A photographic element as in claim 8 wherein the coupler is represented by the formula: ##STR82## wherein PUG is a photographically useful group.

Claim 14

A process of forming a photographic image which comprises developing an exposed photographic silver halide emulsion layer with a color developing agent in the presence of a compound A capable of releasing a photographically useful group, wherein the compound A comprises in a position that reacts with oxidized color developing agent at least two differing timing groups in sequence capable upon activation of timing the release of the photographically useful group and wherein two separate fragments are formed from the two differing timing groups.

Claim 15

A process of forming a photographic image which comprises developing an exposed photographic silver halide emulsion layer with a color developing agent in the presence of a compound A capable of releasing a photographically useful group, wherein the compound A comprises in a position that reacts with oxidized color developing agent at least two differing timing groups in sequence capable upon activation of timing the release of the photographically useful group and wherein two separate fragments are formed from the two differing timing groups.

Claim 16

A process as in claim 11 wherein one of the two differing timing groups in sequence is a group capable of intramolecular nucleophilic displacement release of the remaining portion of the compound A.

Claim 17

A process as in claim 11 wherein one of the two differing groups in sequence is a group capable of a type reaction in which an electron is transferred down a conjugated chain to release the remaining portion of the compound A.

Claim 18

A process as in claim 11 wherein the compound A is a coupler represented by the formula: COUP--T.sub.1 --T.sub.2 --PUG wherein: COUP is a coupler moiety; T 1 is a first timing group capable of being released from COUP at the coupling position of COUP by reaction of COUP with oxidized color developing agent; T 2 is a second timing group capable of being released from said first timing group after said first timing group is released from COUP; and, PUG is a photographically useful group.

Claim 19

A process of forming a photographic image which comprises developing an exposed photographic silver halide emulsion layer with a color developing agent in the presence of at least one coupler capable upon reaction with oxidized color developing agent of releasing a photographically useful group; wherein the coupler comprises at least two differing timing groups, in sequence capable, upon activation, of timing the release of the photographically useful group; wherein two separate fragments are formed from the two differing timing groups upon processing the photographic element; and, the coupler is represented by the formula: ##STR83## wherein: R 26 is substituted or unsubstituted alkyl, or substituted or unsubstituted aryl; R 27 is hydrogen or a substituent which does not adversely affect timing of release of the other portions of the photographic coupler; R 28 is hydrogen or a substituent which advantageously influences the timing of release of PUG; COUP is a coupler moiety substituted in the coupling position by the remainder of the coupler; PUG is a photographically useful group; m and n are individually 0 or 1; Z 5 represents the atoms necessary to complete a carbocyclic or heterocyclic ring.

Claim 20

A process of forming a photographic image which comprises developing an exposed photographic silver halide emulsion layer with a color developing agent in the presence of at least one coupler capable upon reaction with oxidized color developing agent of releasing a photographically useful group; wherein the coupler comprises at least two differing timing groups, in sequence capable, upon activation, of timing the release of the photographically useful group; wherein two separate fragments are formed from the two differing timing groups upon processing the photographic element; and, the coupler is represented by the formula: ##STR83## wherein: R 26 is substituted or unsubstituted alkyl, or substituted or unsubstituted aryl; R 27 is hydrogen or a substituent which does not adversely affect timing of release of the other portions of the photographic coupler; R 28 is hydrogen or a substituent which advantageously influences the timing of release of PUG; COUP is a coupler moiety substituted in the coupling position by the remainder of the coupler; PUG is a photographically useful group; m and n are individually 0 or 1; Z 5 represents the atoms necessary to complete a carbocyclic or heterocyclic ring.

Claim 21

A process as in claim 15 wherein the compound A is a coupler represented by the formula: ##STR84## wherein PUG is a photographically useful group.