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US4861531A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for production of expansion-molded articles in a mold of linear low density polyethylene resins

Assignee: Kanegafuchi Chemical Industry Co Ltd
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Filing: 1988-02-16
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Granted: 1989-08-29
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Expires: 2008-02-16
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Abstract

Abstract The present invention provides a process for production of expansion-molded articles in a mold of a linear low density polyethylene resin which comprises compressing pre-expanded linear low density polyethylene resin beads having two melting points when measured by differential scanning calorimetry and, when the melting point at a low temperature side and the melting point at a high temperature side are designated T ML and T MH respectively, between said two melting points and the peak fusion area at said T ML is designated A L and the peak fusion area at said T MH is designated A H satisfying: 5%≦A.sub.H /A.sub.L ≦80% under a gaseous pressure, filling with said compressed beads a mold capable of closing but incapable of sealing, then venting from said mold and, heating and fusing with steam in such a state that a compressive rate of said pre-expanded beads immediately before said heating with steam to the original pre-expanded beads is maintained to 5 to 60% thereby to produce the molded article in the shape of said mold. According to the present invention, the molded articles of linear low density polyethylene having a minimized dimensional shrinkage rate (good dimensional accuracy) and excellent fusion rate and surface appearance can be produced in high productivity.

Inventors

  • 👤 Hirofumi Maeda

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 18:19
CPC Classifications
B; B29; B29C; B29C67/00; B29C67/20; C; C08; C08J; C08J9/00; C08J9/22; C08J9/228; C08J9/232; B29C44/00; B29C44/34; B29C44/36; B29C44/38; B29C44/44; B29C44/445; B29C67/24; B29C44/3415; B29C44/3426; B29K; B29K2023/00; B29K2023/04; B29K2023/06; B29K2995/00; B29K2995/0037; B29K2995/0063; C08J2323/00; C08J2323/02; C08J2323/04; C08J2323/06; Y; Y10; Y10S; Y10S264/00; Y10S264/09; Y10S264/13; Y10S264/15

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 175 words
A process for production of an expansion-molded article of a linear low density polyethylene resin in a mold, which comprises compressing in a pressure vessel pre-expanded linear low density polyethylene resin beads having two melting points when measured by differential scanning calorimetry and, when the melting point at a low temperature side and the melting point at a high temperature side are designated T ML and T MH respectively, between said two melting points and the peak fusion area at said T ML is designated A L and the peak fusion area at said T MH is designated A H satisfying: 5%<A.sub.H /A.sub.L <80% under a gaseous pressure, filling a mold capable of closing but incapable of sealing with said compressed beads, then venting excess gas from said mold and, heating and fusing with steam in such a state that a compressive rate of said pre-expanded beads immediately before said heating with steam to the original pre-expanded beads is maintained to 5 to 60%, thereby producing a molded article in the shape of the mold.
Claim 2
Dependent Claim 175 words
A process for production of an expansion-molded article of a linear low density polyethylene resin in a mold, which comprises compressing in a pressure vessel pre-expanded linear low density polyethylene resin beads having two melting points when measured by differential scanning calorimetry and, when the melting point at a low temperature side and the melting point at a high temperature side are designated T ML and T MH respectively, between said two melting points and the peak fusion area at said T ML is designated A L and the peak fusion area at said T MH is designated A H satisfying: 5%<A.sub.H /A.sub.L <80% under a gaseous pressure, filling a mold capable of closing but incapable of sealing with said compressed beads, then venting excess gas from said mold and, heating and fusing with steam in such a state that a compressive rate of said pre-expanded beads immediately before said heating with steam to the original pre-expanded beads is maintained to 5 to 60%, thereby producing a molded article in the shape of the mold.
Claim 3
Dependent Claim 53 words
A process as claimed in claim 1, wherein said linear low density polyethylene resin is a copolymer of ethylene having a melting point of 115° to 130° C., a density of 0.915 to 0.940 g/cm 2 , MI of 0.1 to 5 g/10 mins. with an α-olefin having 4 to 10 carbon atoms.
Claim 4
Dependent Claim 31 words
A process as claimed in claim 2, wherein said α-olefin having 4 to 10 carbon atoms is at least one member selected from 1-butene, 1-pentene, 1-hexene, 3,3-dimethyl-1-butene, 4-methyl-1-pentene, 4,4-dimethyl-1-pentene and 1-octene.
Claim 5
Dependent Claim 46 words
A process as claimed in claim 1 or 2, wherein said linear low density polyethylene resin contains at least one member selected from a phenol type antioxidant and a phosphorus type antioxidant in an amount of 0.01 to 0.5 wt % based on said polyethylene resin.
Claim 6
Dependent Claim 24 words
A process as claimed in claim 1, wherein said linear low density polyethylene resin bead has a bead weight of 0.5 to 20 mg/bead.

References Cited (Backward Citations)

US3953558A Cited
US4631159A Cited
US4704239A Cited
US4676939A Cited
US4695593A Cited
JPH05333996A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-08-28 1993-02-27 1993-08-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-08-28 1997-02-27 1997-08-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-08-28 2001-02-27 2001-08-29 $7700.00 Window Closed / Lapsed

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