US4859753A
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Branched lipopeptide polymers forming thermotropic and lyotropic liquid crystals, their applications and corresponding monomers
Assignee: Centre National de la Recherche Scientifique
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Filing: 1986-07-11
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Granted: 1989-08-22
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Expires: 2006-07-11
Abstract
Abstract Branched polymers resulting from homopolymerization or copolymerization of monomers of formula I: <IMAGE> R is H or a lower alkyl group of C1 to C3; Z is O or NH; B has the formula: -(CH2)q1-Z1-(CH2)2- in which q1 and q2 are integers greater than or equal to 1, the sum of which is less than approximately 32 and Z1 represents a single bond or O, S, NH, CO or CO-NH; (AA)p represents a peptide radical comprising p linked aliphatic alpha-aminoacids, bound at B by its carboxyl group, each amino acid comprising less than 15 carbon atoms and being possibly substituted at one carbon atom of the chain by a carboxylic acid or ester, amide or amine group, the terminal amine group of the peptide radical being possibly acylated by a R'CO group, R' being an alkyl radical comprising 1 to 4 carbon atoms, or by any other group stable under the conditions of synthesis; and p represents a number ranging between 1 and 200. Application as thermotropic and lyotropic liquid crystals and emulsifying and foaming agents.
Inventors
- 👤 Bernard Gallot
- 👤 Andre Douy
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 02:41
CPC Classifications
C; C08; C08F; C08F20/00; C08F20/02; C08F20/52; C08F20/54; C08F20/60; C07; C07K; C07K1/00; C08F20/10; C08F20/34; C08F20/36; C09; C09K; C09K19/00; C09K19/04; C09K19/38; C09K19/3833; C09K19/3842; C09K19/3852; C09K19/3871; C09K23/00; C09K23/16; Y; Y10; Y10S; Y10S516/00; Y10S516/90
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
214 words
Polymers selected from the group consisting of: A. homopolymers of monomers having the formula: ##STR41## where: R is H or a lower alkyl group of C 1 to C 3 ; Z is O or NH; B represents an alkyl chain of C 2 to C 24 ; and (AA) p represents a peptide radical comprising p coupled aliphatic amino acids, and bound to B by the carboxyl group of the first amino acid, each amino acid comprising less than 15 carbon atoms and being unsubstituted or substituted at a carbon of the chain by an acid or carboxylic ester, amide or amine group, the terminal amine group being unsubstituted or acylated by a R'CO group, R' being an alkyl radical comprising 1 to 4 carbon atoms, or by a group stable under the condition of the synthesis; AA being derived from amino acids with a hydrophilic side chain; and p is less than 30; B. copolymers of the monomers of formula I with an alkyl acrylate of the formula: ##STR42## or with an acrylamide of the formula: ##STR43## where: R 3 is H or a lower alkyl group of C 1 to C 3 ; and R 4 represents alkyl or hydroxyalkyl groups of C 1 to C 18 ; and mixtures thereof.
Claim 2
Dependent Claim
214 words
Polymers selected from the group consisting of: A. homopolymers of monomers having the formula: ##STR41## where: R is H or a lower alkyl group of C 1 to C 3 ; Z is O or NH; B represents an alkyl chain of C 2 to C 24 ; and (AA) p represents a peptide radical comprising p coupled aliphatic amino acids, and bound to B by the carboxyl group of the first amino acid, each amino acid comprising less than 15 carbon atoms and being unsubstituted or substituted at a carbon of the chain by an acid or carboxylic ester, amide or amine group, the terminal amine group being unsubstituted or acylated by a R'CO group, R' being an alkyl radical comprising 1 to 4 carbon atoms, or by a group stable under the condition of the synthesis; AA being derived from amino acids with a hydrophilic side chain; and p is less than 30; B. copolymers of the monomers of formula I with an alkyl acrylate of the formula: ##STR42## or with an acrylamide of the formula: ##STR43## where: R 3 is H or a lower alkyl group of C 1 to C 3 ; and R 4 represents alkyl or hydroxyalkyl groups of C 1 to C 18 ; and mixtures thereof.
Claim 3
Dependent Claim
24 words
Polymers according to claim 1, characterized in that they are homopolymers and that AA is the derivative of sarcosine, or hydroxyethylglutamine or of hydroxyethylaspartamine.
Claim 4
Dependent Claim
14 words
Polymers according to claim 2, characterized in that AA is the derivative of sarcosine.
Claim 5
Dependent Claim
35 words
Polymers according to claim 1, characterized in that they are copolymers and that AA represents an amino acid derivative selected from the group consisting of sarcosine, lysine, ornithine, glutamic acid, aspartic acid, hydroxyethylglutamine and hydroxyethylaspartamine.
Claim 6
Dependent Claim
14 words
Polymers according to claim 4, characterized in that AA is the derivative of sarcosine.
Claim 7
Dependent Claim
28 words
Polymers according to any one of claims 1 and 2 to 5, characterized in that they result from the copolymerization of at least two monomers of formula (I).
Claim 8
Dependent Claim
33 words
Compositions of polymers according to any one of claims 1 and 2 to 5, characterized in that they are mixtures of polymers of different degrees of polymerization, or of different values of p.
Claim 9
Dependent Claim
17 words
Emulsifying and foaming agents comprising polymers according to any one of claims 1 and 2 to 5.
References Cited (Backward Citations)
EP0105777A1
Cited
US4600526A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1992-08-21 | 1993-02-20 | 1993-08-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-08-21 | 1997-02-20 | 1997-08-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-08-21 | 2001-02-20 | 2001-08-22 | $7700.00 | Window Closed / Lapsed |