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US4857430A Expired / Lapsed US ⏱️ 0.0 years remaining

Process and system for determining photoresist development endpoint by effluent analysis

Assignee: Texas Instruments Inc
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Filing: 1987-12-17
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Granted: 1989-08-15
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Expires: 2007-12-17
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Abstract

Abstract A system and method for determining the pattern development endpoint of a photoresist polymer during spin/spray processing of a semiconductor wafer utilizes the optical transmission of the waster developer liquid during the pattern develop process to determine when the developing is completed.

Inventors

  • 👤 Edwin G. Millis
  • 👤 Samuel J. Wood, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 23:23
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/26; G03F7/30; G03F7/3021; G03F7/3028

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 99 words
In a method of developing patterned photoresist polymer on a semiconductor wafer and detecting the endpoint of the develop process, the steps of spraying developer fluid onto a semiconductor wafer mounted and spinning on a spinning vacuum chuck, catching the developer fluid as it is spun from the surface of the semiconductor wafer, draining the developer fluid into an analysis chamber, analyzing the developer fluid for the amount of dissolved photoresist polymer therein, and rinsing the semiconductor wafer to remove developer fluid therefrom when the detected amount of dissolved photoresist polymer in the developer fluid reaches a predetermined amount.
Claim 2
Dependent Claim 99 words
In a method of developing patterned photoresist polymer on a semiconductor wafer and detecting the endpoint of the develop process, the steps of spraying developer fluid onto a semiconductor wafer mounted and spinning on a spinning vacuum chuck, catching the developer fluid as it is spun from the surface of the semiconductor wafer, draining the developer fluid into an analysis chamber, analyzing the developer fluid for the amount of dissolved photoresist polymer therein, and rinsing the semiconductor wafer to remove developer fluid therefrom when the detected amount of dissolved photoresist polymer in the developer fluid reaches a predetermined amount.
Claim 3
Dependent Claim 45 words
The method according to claim 1, wherein the analysis chamber measures the amount of photoresist polymer in the developer fluid by monitoring the ultraviolet light transparency of the developer fluid, which transparency is dependent upon the amount of photoresist polymer dissolved in the developer fluid.
Claim 4
Dependent Claim 50 words
The method according to claim 2, wherein said analysis chamber measures the transparency of the developer fluid by directing a beam of filtered light through the developer fluid to a photodetector, the amount of light from the beam reaching the photodetector being indicative of the transparency of the developer fluid.
Claim 5
Dependent Claim 37 words
The method according to claim 3, wherein a reference value is used in determining the ultraviolet light transparency of the developer fluid, said reference being the transparency of developer fluid that has no photoresist polymer dissolved therein.
Claim 6
Dependent Claim 21 words
The method according to claim 1, wherein the developer fluid drains at the rate of at least 1-3 milliliter per second.
Claim 7
Dependent Claim 108 words
In a method of developing patterned photoresist polymer on a semiconductor wafer and detecting the endpoint of the develop process, the steps of spraying developer fluid onto a semiconductor wafer mounted and spinning on a spinning vacuum chuck, catching the developer fluid in a steeply-sloped drain bowl as it is spun from the surface of the semiconductor wafer, draining the developer fluid from the drain bowl into an analysis chamber, analyzing the developer fluid for the amount of dissolved photoresist polymer therein, and rinsing the semiconductor wafer to remove developer fluid therefrom when the detected amount of dissolved photoresist polymer in the developer fluid reaches a predetermined amount.
Claim 8
Dependent Claim 108 words
In a method of developing patterned photoresist polymer on a semiconductor wafer and detecting the endpoint of the develop process, the steps of spraying developer fluid onto a semiconductor wafer mounted and spinning on a spinning vacuum chuck, catching the developer fluid in a steeply-sloped drain bowl as it is spun from the surface of the semiconductor wafer, draining the developer fluid from the drain bowl into an analysis chamber, analyzing the developer fluid for the amount of dissolved photoresist polymer therein, and rinsing the semiconductor wafer to remove developer fluid therefrom when the detected amount of dissolved photoresist polymer in the developer fluid reaches a predetermined amount.
Claim 9
Dependent Claim 46 words
The method according to claim 6, wherein the analysis chamber measures the changing amount of photoresist polymer in the developer fluid by monitoring the ultraviolet light transparency of the developer fluid, which transparency is dependent upon the amount of photoresist polymer dissolved in the developer fluid.
Claim 10
Dependent Claim 51 words
The method according to claim 7, wherein said analysis chamber measures the ultraviolet light transparency of the developer fluid by directing a beam of light through the developer fluid to a photodetector, the amount of light from the beam reaching the photodetector being indicative of the transparency of the developer fluid.
Claim 11
Dependent Claim 35 words
The method according to claim 8, wherein a reference value is used in determining the transparency of the developer fluid, said reference being the transparency of developer fluid that has no photoresist polymer dissolved therein.
Claim 12
Dependent Claim 30 words
The method according to claim 6, wherein the developer fluid is analyzed in the analysis chamber to determine the rate of change of the photoresist polymer in the developer fluid.
Claim 13
Dependent Claim 44 words
The method according to claim 10, wherein the endpoint of the develop process of the photoresist polymer on the semiconductor wafer is reached when the fluid transmission recovers substantially and the rate of change of the photoresist polymer in the developer fluid approaches zero.

References Cited (Backward Citations)

US4023193A Cited
US4166702A Cited
US4201579A Cited
GB2041569A Cited
JPS572042A Cited
US4593986A Cited
US4429983A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-08-14 1993-02-13 1993-08-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-08-14 1997-02-13 1997-08-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-08-14 2001-02-13 2001-08-15 $7700.00 Window Closed / Lapsed

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