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Patent US4855124A successfully refreshed from Google Patents.
US4855124A
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Process for the desulfurization of gas containing hydrogen sulfide
Assignee: JGC Corp
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Filing: 1987-11-04
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Granted: 1989-08-08
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Expires: 2007-11-04
Abstract
Abstract It has been believed that the Claus reaction in water without additive gives no more than very low conversion and some additive such as buffer or catalyst must be used to attain satisfactory H 2 S conversion. However, it was discovered that when H 2 S and SO 2 are introduced in water simultaneously and continuously for hours, the conversion increased gradually and became steady at high level. The present invention was accomplished base on this inventive knowledge.
Inventors
- 👤 Hiroo Matsuoka
- 👤 Tsutomu Toida
- 👤 Takao Takinami
- 👤 Senji Takenaka
- 👤 Tetsuo Fujita
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 20:49
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/46; B01D53/48; B01D53/52; B01D53/523; C; C01; C01B; C01B17/00; C01B17/02; C01B17/04; C01B17/05
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
125 words
A process for the desulfurization of gas containing hydrogen sulfide comprising: (a) introducing the gas containing hydrogen sulfide together with a gas containing sulfur dioxide simultaneously and continuously into a water medium free from any additive and pressurized at a pressure of 10 Kg/cm 2 gauge or higher in a reactor having no mechanical agitating means until the pH of the water medium falls in a range of 0.1 to below 2.0; and (b) continuing the simultaneous introduction of the gas containing hydrogen sulfide and the gas containing sulfur dioxide into said water medium having a pH in a range of 0.1 to below 2.0, and subjecting the resulting medium to liquid phase Clause reaction to form elemental sulfur in a form of sulfur-in-water dispersion.
Claim 2
Dependent Claim
125 words
A process for the desulfurization of gas containing hydrogen sulfide comprising: (a) introducing the gas containing hydrogen sulfide together with a gas containing sulfur dioxide simultaneously and continuously into a water medium free from any additive and pressurized at a pressure of 10 Kg/cm 2 gauge or higher in a reactor having no mechanical agitating means until the pH of the water medium falls in a range of 0.1 to below 2.0; and (b) continuing the simultaneous introduction of the gas containing hydrogen sulfide and the gas containing sulfur dioxide into said water medium having a pH in a range of 0.1 to below 2.0, and subjecting the resulting medium to liquid phase Clause reaction to form elemental sulfur in a form of sulfur-in-water dispersion.
Claim 3
Dependent Claim
22 words
A process for the desulfurization of gas containing hydrogen sulfide according to claim 1, wherein the pressure is 10-80 Kg/cm 2 gauge.
Claim 4
Dependent Claim
32 words
A process for the desulfurization of gas containing hydrogen sulfide according to claim 1, wherein the length of contact time of the gases in the water medium are shorter than 0.024 hr.
Claim 5
Dependent Claim
60 words
A process for the desulfurization of gas containing hydrogen sulfide according to claim 1, wherein the sulfur-in-water dispersion from the liquid phase Claus reaction zone is subjected to separation into sulfur phase and water phase, the water phase being recycled to the reaction zone so as to maintain the water medium for the liquid phase Claus reaction below pH 2.
Claim 6
Dependent Claim
65 words
A process for the desulfurization of gas containing hydrogen sulfide according to claim 1, wherein a part of the sulfur in a form of sulfur-in-water dispersion is burned with oxygen-containing gas to generate sulfur dioxide, keeping the combustion temperature below 2000° C. by adjusting the water content of the sulfur-in-water dispersion and then the generated sulfur dioxide is provided to the liquid phase Claus reaction.
Claim 7
Dependent Claim
37 words
A process for the desulfurization of gas containing hydrogen sulfide according to claim 1, wherein the liquid phase Claus reaction is conducted at a temperature over 120° C. to recover sulfur in a form of molten state.
Claim 8
Dependent Claim
73 words
A process for the desulfurization of gas containing hydrogen sulfide according to claim 1, wherein the amount of either hydrogen sulfide or sulfur dioxide being introduced into the pressurized water is adjusted so that it exists in an excess amount compared to the other component regarding the stoichiometric relation of the Claus reaction and then the component in excess which has not taken part in the reaction is eliminated in a finishing process.
Claim 9
Dependent Claim
38 words
A process for the desulfurization of gas containing hydrogen sulfide according to claim 7, wherein the component existing in an excess amount is hydrogen sulfide, and the component to be eliminated in the finishing process is hydrogen sulfide.
Claim 10
Dependent Claim
38 words
A process for the desulfurization of gas containing hydrogen sulfide according to claim 7, wherein the component existing in an excess amount is sulfur dioxide and the component to be eliminated in the finishing process is sulfur dioxide.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1992-08-07 | 1993-02-06 | 1993-08-08 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-08-07 | 1997-02-06 | 1997-08-08 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-08-07 | 2001-02-06 | 2001-08-08 | $7700.00 | Window Closed / Lapsed |