US4853548A
Expired / Lapsed
US
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Ultrasensitive radiation dosimeter and dosimetry system
Assignee: Individual
•
Filing: 1987-11-13
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Granted: 1989-08-01
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Expires: 2007-11-13
Abstract
Abstract A device including a dosimeter badge containing a preset quantity of an aromatic endoperoxide, AO 2 , for example the endoperoxide of rubrene or of 9,10-di-phenylanthracene in an organic matrix containing atoms of a high atomic number such as liquid O-dichlorobenzene or solid-P-dichlorobenzene. When exposed to ionizing radiation the aromatic endoperoxide decomposes to produce the fluorescent aromatic. After exposure, the badge is fluorometrically detected by exposing the pre-set quantity of light radiation and the fluorometric result measured, and a system for doing this is also disclosed. The badge preferably is constructed so as to contain two identical samples of the AO 2 , one of which is shielded from ionizing radiation (by, e.g., lead foil envelope) during exposure use, and the other of which is unshielded to such hard radiation while both samples are shielded against light and untraviolet radiation. The two samples are thereafter unshielded and fluorescence of the two samples is compared and measured against an absolute scale in a conventional fluorimeter.
Inventors
- 👤 Brian Stevens
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 17:21
CPC Classifications
G; G01; G01T; G01T1/00; G01T1/02; G01T1/10; G01T1/04
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
199 words
A process for determining the dosage of ionizing radiation received by a location over a period of time comprising the steps of: (a) providing a sensing element containing an effective quantity of unexposed-to-ionizing radiation endoperoxide AO 2 in close association with dispersed heavy atoms, that is atoms of high atomic number which is equal to or greater than the atomic number of the element chlorine wherein A is a fluorescent aromatic hydrocarbon and which when exposed to ionizing radiation undergoes the transformation: AO.sub.2 + ionizing radiation =A + O.sub.2 (b) exposing, over the period of time, aid sensing element and its effective quantity of AO 2 and its associated high atomic number atoms to any ionizing radiation presented to the location so that such transformation may occur while keepping said element effectively shielded from non-ionizing radiation; (c) thereafter, exposing the sensing element to a predetermined quantity of light from the ultraviolet through visible light spectra and sensing the intensity, if any, of fluoresence produced by free A present in response to that exposure, (d) correlating that fluorescence sensed with a measure of the exposure to ionizating radiation to compute the dosage of such ionizing radiation received by the location.
Claim 2
Dependent Claim
199 words
A process for determining the dosage of ionizing radiation received by a location over a period of time comprising the steps of: (a) providing a sensing element containing an effective quantity of unexposed-to-ionizing radiation endoperoxide AO 2 in close association with dispersed heavy atoms, that is atoms of high atomic number which is equal to or greater than the atomic number of the element chlorine wherein A is a fluorescent aromatic hydrocarbon and which when exposed to ionizing radiation undergoes the transformation: AO.sub.2 + ionizing radiation =A + O.sub.2 (b) exposing, over the period of time, aid sensing element and its effective quantity of AO 2 and its associated high atomic number atoms to any ionizing radiation presented to the location so that such transformation may occur while keepping said element effectively shielded from non-ionizing radiation; (c) thereafter, exposing the sensing element to a predetermined quantity of light from the ultraviolet through visible light spectra and sensing the intensity, if any, of fluoresence produced by free A present in response to that exposure, (d) correlating that fluorescence sensed with a measure of the exposure to ionizating radiation to compute the dosage of such ionizing radiation received by the location.
Claim 3
Dependent Claim
23 words
The process of claim 1 wherein said predetermined quantity of light is of a nature that the AO 2 is transparent to it.
Claim 4
Dependent Claim
107 words
A badge for sensing the dosage of ionizing radiation received by it comprising at least one element comprising an effective quantity of an endoperoxide AO 2 in a matrix having an effective amount of heavy atoms, that is atoms having a high aromatic number element which is equal to or greater than the element chlorine wherein A is a fluorescent aromatic hydrocarbon which when exposed to ionizing radiation undergoes the transformation: AO.sub.2 + ionizing radiation =A + O.sub.2 such that the dosage may be derived by measuring the presence of A by fluorometric analysis and said badge including removable means for shielding said element from non-ionizing radiation.
Claim 5
Dependent Claim
107 words
A badge for sensing the dosage of ionizing radiation received by it comprising at least one element comprising an effective quantity of an endoperoxide AO 2 in a matrix having an effective amount of heavy atoms, that is atoms having a high aromatic number element which is equal to or greater than the element chlorine wherein A is a fluorescent aromatic hydrocarbon which when exposed to ionizing radiation undergoes the transformation: AO.sub.2 + ionizing radiation =A + O.sub.2 such that the dosage may be derived by measuring the presence of A by fluorometric analysis and said badge including removable means for shielding said element from non-ionizing radiation.
Claim 6
Dependent Claim
24 words
The badge of claim 3 wherein said high atomic number chemical containing matrix is one of the following liquid O-dichlorobenzene, solid P-dichlorobenzene, or bromobenzene.
Claim 7
Dependent Claim
13 words
the badge of claim 4 said AO 2 is the endoperoxide of rubrene.
Claim 8
Dependent Claim
14 words
The badge of claim 3 wherein said AO 2 is the endoperoxide of rubrene.
Claim 9
Dependent Claim
186 words
A process for determining the dosage of ionizing radiation received by a location over a period of time comprising the steps of: (a) providing a sensing element containing an effective quantity of unexposed-to-ionizing radiation endoperoxide AO 2 wherein A is a fluorescent aromatic hydrocarbon and which when exposed to ionizing radiation undergoes the transformation: AO.sub.2 + ionizing radiation =A + O.sub.2 which endoperoxide AO 2 is in an effective amount of organic matrix containing atoms of high atomic number which is equal to or greater than the element chlorine; (b) exposing, over the period of time, said element and its effective quantity of AO 2 to any ionizing radiation presented to the locations so that such transformation may occur while effectively shielding said element from non-ionizing radiation; (c) thereafter, exposing the element to a predetermined quantity of light and sensing either the fluorescence produced by the free A or the absorption of such light by the free A or both; (d) correlating that output sensed with a measure of the exposure to ionizating radiation to compute the dosage of such ionizing radiation received by the location.
Claim 10
Dependent Claim
186 words
A process for determining the dosage of ionizing radiation received by a location over a period of time comprising the steps of: (a) providing a sensing element containing an effective quantity of unexposed-to-ionizing radiation endoperoxide AO 2 wherein A is a fluorescent aromatic hydrocarbon and which when exposed to ionizing radiation undergoes the transformation: AO.sub.2 + ionizing radiation =A + O.sub.2 which endoperoxide AO 2 is in an effective amount of organic matrix containing atoms of high atomic number which is equal to or greater than the element chlorine; (b) exposing, over the period of time, said element and its effective quantity of AO 2 to any ionizing radiation presented to the locations so that such transformation may occur while effectively shielding said element from non-ionizing radiation; (c) thereafter, exposing the element to a predetermined quantity of light and sensing either the fluorescence produced by the free A or the absorption of such light by the free A or both; (d) correlating that output sensed with a measure of the exposure to ionizating radiation to compute the dosage of such ionizing radiation received by the location.
Claim 11
Dependent Claim
19 words
The process of claim 7 wherein said matrix is one of the following liquid O-dichlorobenzene, solid P-dichlorobenzene, or bromobenzene.
Claim 12
Dependent Claim
14 words
The process of claim 8 wherein said AO 2 is the endoperoxide of rubrene.
Claim 13
Dependent Claim
14 words
The process of claim 7 wherein said AO 2 is the endoperoxide of rubrene.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1992-07-31 | 1993-01-30 | 1993-08-01 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-07-31 | 1997-01-30 | 1997-08-01 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-07-31 | 2001-01-30 | 2001-08-01 | $7700.00 | Window Closed / Lapsed |