Triiolide salts of cyanine dyes suitable for sensitization of photoconductive systems

Claim 2

A photoconductor composition comprising an organic photoconductor compound in admixture with a sensitising dye characterised in that the sensitising dye is a cyanine dye having a polymethine chain of at least 7 carbon atoms and at least 10 molar percent of the dye is in the form of a tri-iodide salt.

Claim 3

A photoconductor composition as claimed in claim 1 characterised in that the polymethine chain includes a fused cyclopentene or cyclohexene ring.

Claim 4

A photoconductor composition as claimed in claim 1 characterised in that at least 50 molar percent of the dye is in the form of a tri-iodide salt.

Claim 5

A photoconductor composition as claimed in claim 3 characterised in that substantially all of the dye is in the form of a tri-iodide salt.

Claim 6

A photoconductor composition as claimed in claim 3 in which the sensitising dye has the general formula ##STR9## in which: n and m are 0 or integers such that (n+m) is at least 2, each R 1 independently represents a substituent of up to 20 carbon atoms selected from the optionally substituted acyclic hydrocarbon groups, alkaryl groups and aryl groups, A is selected from -CH═CH-CH═ ##STR10## in which R 2 is selected from hydrogen, halogen, cyano, alkyl of up to 18 carbon atoms, alkoxy of up to 18 carbon atoms, phenoxy, aryl of up to 20 carbon atoms, amino, thiophenyl, thioalkyl of up to 18 carbon atoms, R 10 represents one or more substituents selected from alkyl groups of up to 4 carbon atoms, aryl of up to 20 carbon atoms, cyano, halogen and hydrogen, each Y is independently selected from S and CR 3 R 4 in which R 3 and R 4 independently represent a substituted or non-substituted, aliphatic group of up to 20 carbon atoms, or R 3 and R 4 together represent the necessary atoms to complete a 5- or 6-membered carbocyclic ring, each Z independently represents one or more substituents selected from hydrogen, halogen, nitro, cyano, optionally substituted alkylsulphonyl, optionally substituted arylsulphonyl and optionally substituted arylcarbonyl, in which the alkyl and aryl groups contain up to 12 carbon atoms, and X - represents a tri-iodide anion.

Claim 7

A photoconductor composition as claimed in claim 5 characterised in that R 1 represents an alkyl group of 1 to 13 carbon atoms, Y represent CR 3 R 4 and n=m=1.

Claim 8

A photoconductor composition as claimed in claim 5 characterised in that the dye is of the formula (II) ##STR11## in which: X - represents a tri-iodide anion, R 10 is as defined in claim 5, and R 5 represents C 6 H 5 SO 2 , CF 3 SO 2 , CH 3 SO 2 NO 2 or C 6 H 5 OSO 2 .

Claim 9

A photoconductor composition as claimed in claim 1 characterised in that the photoconductor compound comprises a bis(benzo-[a]carbazolyl)aryl methane.

Claim 10

A photoconductor composition as claimed in claim 8 characterised in that the photoconductor compound comprises Bis-(N-ethylbenzo-1,2,-carbazolyl)phenyl methane.

Claim 11

A photoconductor composition as claimed in claim 3 characterised in that the sensitising dye is present in the range 0.01 to 10% by weight of the photoconductor and the composition additionally comprises a binder in an amount up to 85% by weight of the composition.

Claim 12

A photosensitive element comprising a support, the surface of which is electrically conducting or is made electrically conductive by the provision of a conductive layer, the electrically conductive surface having coated thereon a photosensitive layer characterised in that the photosensitive layer comprises a photoconductive material as claimed in claim 2.