Thermosetting resin systems containing secondary amine-terminated siloxane modifiers

Claim 2

A process for toughening a heat-curable resin system, comprising adding thereto a toughening amount of an organosilicone toughener selected from the group consisting of (a) ##STR20## wherein each R 1 is individually selected from the group consisting of alkyl; alkoxy; halogenated alkyl; acetoxy; and substituted and unsubstituted cycloalkyl, aryl, and aralkyl; ##STR21## wherein k is an integer from 3 to about 5; wherein n is a natural number from 1 to about 10,000; wherein m is a natural number from 1 to about 10,000; wherein the sum m+n is less than about 10,000; and wherein at least one of R 1 or R 2 is ##STR22## wherein R is selected from the group consisting of substituted and unsubstituted alkyl, cycloalkyl, aryl and aralkyl radicals carrying no primary amino groups; and wherein each R 2 is individually selected from the group consisting of alkyl; alkoxy; halogenated alkyl; acetoxy; and substituted and unsubstituted cycloalkyl, aryl, and aralkyl; (b) a prereact comprising the reaction product of (a) with a resin reactive therewith, said resin selected from the group consisting of epoxy, cyanate, and bismaleimide resins and mixtures thereof; and (c) mixtures of (a) and (b).

Claim 3

The process of claim 1 wherein said heat-curable resin system is selected from the group consisting of: (a) epoxy resin systems, (b) cyanate resin systems, (c) bismaleimide resin systems, and (d) mixtures thereof.

Claim 4

The process of claim 2 wherein each R 1 is individually selected from the group consisting of methyl radicals, phenyl radicals, and ##STR23##

Claim 5

The process of claim 2 wherein said heat-curable resin system is an adhesive.

Claim 6

A heat-curable resin composition, comprising (a) a heat-curable resin system, and (b) a silicone modifier selected from the group consisting of (i) secondary amine-functionalized organosilicones having the formula ##STR24## wherein each R 1 is individually selected from the group consisting of alkyl; alkoxy; halogenated alkyl; acetoxy; and substituted and unsubstituted cycloalkyl, aryl, and aralkyl; ##STR25## wherein k is an integer from 3 to about 5; wherein n is a natural number from 1 to about 10,000; wherein m is a natural number from 1 to about 10,000; wherein the sum m+n is less than about 10,000; wherein at least one of R 1 or R 2 is ##STR26## wherein R is selected from the group consisting of substituted and unsubstituted alkyl, cycloalkyl, aryl and aralkyl radicals carrying no primary amino groups; and wherein each R 2 is individually selected from the group consisting of alkyl; alkoxy; halogenated alkyl; acetoxy; and substituted and unsubstituted cycloalkyl, aryl, and aralkyl; (ii) a prereact prepared by reacting the secondary amine-functionalized organo-silicone of (b)(i) with a resin reactive therewith, said resin selected from the group consisting of epoxy resins, cyanate resins, bismaleimide resins, and (iii) mixtures thereof.

Claim 7

A heat-curable resin composition, comprising (a) a heat-curable resin system, and (b) a silicone modifier selected from the group consisting of (i) secondary amine-functionalized organosilicones having the formula ##STR24## wherein each R 1 is individually selected from the group consisting of alkyl; alkoxy; halogenated alkyl; acetoxy; and substituted and unsubstituted cycloalkyl, aryl, and aralkyl; ##STR25## wherein k is an integer from 3 to about 5; wherein n is a natural number from 1 to about 10,000; wherein m is a natural number from 1 to about 10,000; wherein the sum m+n is less than about 10,000; wherein at least one of R 1 or R 2 is ##STR26## wherein R is selected from the group consisting of substituted and unsubstituted alkyl, cycloalkyl, aryl and aralkyl radicals carrying no primary amino groups; and wherein each R 2 is individually selected from the group consisting of alkyl; alkoxy; halogenated alkyl; acetoxy; and substituted and unsubstituted cycloalkyl, aryl, and aralkyl; (ii) a prereact prepared by reacting the secondary amine-functionalized organo-silicone of (b)(i) with a resin reactive therewith, said resin selected from the group consisting of epoxy resins, cyanate resins, bismaleimide resins, and (iii) mixtures thereof.

Claim 8

The composition of claim 5 wherein said heat-curable resin system is selected from the group consisting of (a) epoxy resin systems, (b) cyanate resin systems, (c) maleimide-group-containing resin systems, and (d) mixtures thereof.

Claim 9

The composition of claim 6 wherein each R 1 is individually selected from the group consisting of methyl radicals, phenyl radicals, and ##STR27##

Claim 10

The heat-curable resin composition of claim 6 wherein said composition is an adhesive.

Claim 11

The heat-curable resin composition of claim 5, further comprising from 40 to about 90 percent by weight, relative to the weight of the total composition, or reinforcement seclected from the group consisting of woven and nonwoven yarn, tape, and cloth comprising fiberglass, carbon/graphite, boron, or thermoplastic fiber wherein said reinforcement contributes substantially to the strength of the cured composition.

Claim 12

The composition of claim 9 wherein said thermoplastic reinforcement is selected from the group consisting of high modulus polyolefin, aramid, polyetherketone, polyetheretherketone, polyetherketoneketone, polyethersulfone, polyphenylenesulfide, polyketonesulfone, and polyetherketonesulfone.

Claim 13

The composition of claim 9 wherein said thermoplastic fiber has a glass transition temperature Tg above 150° C.

Claim 14

The heat-curable resin composition of claim 5, further comprising from 1 to about 25 percent by weight, relative to the weight of the total composition, of support selected from the group consisting of woven and nonwoven yarn, tape, and cloth comprising fiberglass, carbon/graphite, boron, or thermoplastic fiber wherein said support does not contribute substantially to the strength of the cured composition.