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US4844948A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of manufacturing nickel hydroxide electrode for alkaline storage cell

Assignee: Sanyo Electric Co Ltd
•
Filing: 1988-03-01
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Granted: 1989-07-04
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Expires: 2008-03-01
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Abstract

Abstract A method of manufacturing a nickel hydroxide electrode for use in an alkaline storage cell. The disclosed method comprises a first step of forming cobalt hydroxide on surfaces of a porous nickel sintered plaque, a second step of changing the cobalt hydroxide into cobalt oxyhydroxide, and a third step of carrying out an active material filling operation for the sintering plaque formed with the cobalt oxyhydroxide.

Inventors

  • 👤 Shinsuke Nakahori
  • 👤 Hironori Honda

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 16:44
CPC Classifications
H; H01; H01M; H01M4/00; H01M4/02; H01M4/24; H01M4/26; H01M4/28; H01M4/32; Y; Y02; Y02E; Y02E60/00; Y02E60/10; Y02P; Y02P70/00; Y02P70/50

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 98 words
A method of manufacturing a nickel hydroxide electrode for use in an alkaline storage cell, comprising: a first step of forming cobalt hydroxide on the surface of a porous nickel sintered plaque by impregnating the sintered plaque with a cobalt salt and then immersing the sintered plaque in an alkali solution, a second step of heat-treating the sintered plaque having the cobalt hydroxide formed on its surface in presence of an alkali solution and oxygen, and a third step of carrying out an active material filling operation for impregnating the heat-treated sintered plaque with an acidic nickel salt.
Claim 2
Independent Claim 98 words
A method of manufacturing a nickel hydroxide electrode for use in an alkaline storage cell, comprising: a first step of forming cobalt hydroxide on the surface of a porous nickel sintered plaque by impregnating the sintered plaque with a cobalt salt and then immersing the sintered plaque in an alkali solution, a second step of heat-treating the sintered plaque having the cobalt hydroxide formed on its surface in presence of an alkali solution and oxygen, and a third step of carrying out an active material filling operation for impregnating the heat-treated sintered plaque with an acidic nickel salt.
Claim 3
Dependent Claim 24 words
A method as claimed in claim 1, wherein the porous nickel sintered plaque used in the first step is sintered in a reducing atmosphere.
Claim 4
Dependent Claim 19 words
A method as claimed in claim 1, wherein the sintered plaque is heated while immersed in the alkali solution.
Claim 5
Dependent Claim 25 words
A method as claimed in claim 1, wherein the heat treatment in the second step is effected at a temperature of at least 50° C.
Claim 6
Dependent Claim 24 words
A method as claimed in claim 1, wherein the heat treatment in the second step is effected at a temperature not exceeding 250° C.
Claim 7
Dependent Claim 31 words
A method as claimed in claim 1, wherein the heat treatment in the second step is effected in the air at a temperature of 90° C. and a humidity of 80%.
Claim 8
Dependent Claim 42 words
A method as claimed in claim 1, wherein the active material filling operation in the third step is carried out by impregnating the porous nickel sintered plaque with the acidic nickel salt and thereafter subjecting the sintered plaque to an alkali treatment.
Claim 9
Dependent Claim 44 words
A method as claimed in claim 1, wherein the active material filling operation in the third step is carried out by immersing the sintered plaque in a heated aqueous solution of nickel nitrate and thereafter immersing the sintered plaque in a caustic soda solution.
Claim 10
Independent Claim 100 words
A method of manufacturing a nickel hydroxide electrode for use in an alkaline storage cell, comprising a first step of forming cobalt hydroxide on the surface of a porous nickel sintered plaque by impregnating the sintered plaque with a cobalt salt and immersing the sintered plaque in an alkali solution, a second step of changing the cobalt hydroxide formed on the surface of the sintered plaque into cobalt oxyhydroxide or cobalt oxyhydroxide and cobaltosic oxide having a reduced crystallinity, and a third step of carrying out an active material filling operation for the sintered plaque formed with the cobalt oxyhydroxide.
Claim 11
Independent Claim 100 words
A method of manufacturing a nickel hydroxide electrode for use in an alkaline storage cell, comprising a first step of forming cobalt hydroxide on the surface of a porous nickel sintered plaque by impregnating the sintered plaque with a cobalt salt and immersing the sintered plaque in an alkali solution, a second step of changing the cobalt hydroxide formed on the surface of the sintered plaque into cobalt oxyhydroxide or cobalt oxyhydroxide and cobaltosic oxide having a reduced crystallinity, and a third step of carrying out an active material filling operation for the sintered plaque formed with the cobalt oxyhydroxide.
Claim 12
Dependent Claim 24 words
A method as claimed in claim 9, wherein the porous nickel sintered plaque used in the first step is sintered in a reducing atmosphere.
Claim 13
Dependent Claim 19 words
A method as claimed in claim 9, wherein the sintered plaque is heated while immersed in the alkali solution.
Claim 14
Dependent Claim 35 words
A method as claimed in claim 9, wherein the cobalt oxyhydroxide is formed in the second step by effecting a heat treatment without removing alkali solution from the sintered plaque prepared in the first step.
Claim 15
Dependent Claim 25 words
A method as claimed in claim 12, wherein the heat treatment in the second step is effected at a temperature of at least 50° C.
Claim 16
Dependent Claim 24 words
A method as claimed in claim 12, wherein the heat treatment in the second step is effected at a temperature not exceeding 250° C.
Claim 17
Dependent Claim 41 words
A method as claimed in claim 9, wherein the active material filling operation in the third step is carried out by impregnating the porous nickel sintered with the acidic nickel salt and thereafter subjecting the sintered plaque to an alkali treatment.
Claim 18
Dependent Claim 44 words
A method as claimed in claim 9, wherein the active material filling operation in the third step is carried out by immersing the sintered plaque in a heated aqueous solution of nickel nitrate and thereafter immersing the sintered plaque in a caustic soda solution.

References Cited (Backward Citations)

US3951686A Cited
US4029132A Cited
JPS5388929A Cited
JPS53126131A Cited
JPS56141172A Cited
JPS575018A Cited
US4603094A Cited
JPS6237874A Cited
JPS6258566A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-07-03 1993-01-02 1993-07-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-07-03 1997-01-02 1997-07-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-07-03 2001-01-02 2001-07-04 $7700.00 Window Closed / Lapsed

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