US4843105A
Expired / Lapsed
US
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Process for the preparation of filler-containing, antionically modified polyurethane (urea) compositions, the polyurethane (urea) compositions so-obtained, and the use thereof
Assignee: Bayer AG
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Filing: 1986-07-11
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Granted: 1989-06-27
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Expires: 2006-07-11
Abstract
Abstract The invention is directed to the formation of filler containing anionically modified polyurethane (urea) compositions by reacting suitable polyurethane (urea) forming ingredients in the presence of from 5 to 97% by weight of fillers selected from the group consisting of (i) finely divided or lumpy foam particles, (ii) fossile lignocelluloses, (iii) carbon powder, and (iv) mixtures thereof, said filler-containing polyurethane (urea) having a water absorbability of from 33 to 97% by weight, and having an anionic group content of from 10 to 3000 milliequivalents of anionic groups and/or groups capable of anionic group formation per 1000 grams of said polyurethane (urea) components.
Inventors
- 👤 Artur Reischl
- 👤 Kurt Mack
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 18:58
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/08; C08G18/0804; C08G18/0819; C02; C02F; C02F3/00; C02F3/02; C02F3/06; C02F3/10; C08G18/10; C02F3/08; C02F3/085; Y; Y02; Y02W; Y02W10/00; Y02W10/10
Claims Analysis
Total Claims: 21
Claim 1
Independent Claim
247 words
A process for the production of filler-containing polyurethane (urea) compositions comprising reacting: (A) at least one di- and/or polyfunctional isocyanate-terminated prepolymer having an isocyanate group content of from 1 to 12% by weight, (B) from 0 to 50% by weight based on the weight of (A) of a lower molecular weight organic di- and/or polyisocyanate, with the mixture of (A) and (B) having anisocyanate group content of 30% by weight or less. (C) a stoichiometric excess quantity of water, and (D) from 0 to 50 equivalent % based on the total isocyanate equivalents in (A) and (B) of a member selected from the group consisting of (i) organic di- and/or polyamines, (ii) organic compounds containing at least one group which is reactive with an isocyanate group and at least one anionic group or group capable of forming an anionic group, and (iii) mixtures thereof, in the presence of (E) from 5 to 97% by weight of fillers selected from the group consisting of (i) finely divided or lumpy foam particles, (ii) fossil lignocelluloses, (iii) carbon powder, and (iv) mixtures thereof, said % by weight of component (E) being based on the total moisture-free weight of components (A), (B), (D) and (E), said filler-containing polyurethane (urea) having a water absorbability of from 33 to 97% by weight, and having an anionic group content of from 10 to 3000 milliequivalents of anionic groups and/or groups capable of anionic group formation per 1000 grams of components (A), (B) and (D).
Claim 2
Dependent Claim
247 words
A process for the production of filler-containing polyurethane (urea) compositions comprising reacting: (A) at least one di- and/or polyfunctional isocyanate-terminated prepolymer having an isocyanate group content of from 1 to 12% by weight, (B) from 0 to 50% by weight based on the weight of (A) of a lower molecular weight organic di- and/or polyisocyanate, with the mixture of (A) and (B) having anisocyanate group content of 30% by weight or less. (C) a stoichiometric excess quantity of water, and (D) from 0 to 50 equivalent % based on the total isocyanate equivalents in (A) and (B) of a member selected from the group consisting of (i) organic di- and/or polyamines, (ii) organic compounds containing at least one group which is reactive with an isocyanate group and at least one anionic group or group capable of forming an anionic group, and (iii) mixtures thereof, in the presence of (E) from 5 to 97% by weight of fillers selected from the group consisting of (i) finely divided or lumpy foam particles, (ii) fossil lignocelluloses, (iii) carbon powder, and (iv) mixtures thereof, said % by weight of component (E) being based on the total moisture-free weight of components (A), (B), (D) and (E), said filler-containing polyurethane (urea) having a water absorbability of from 33 to 97% by weight, and having an anionic group content of from 10 to 3000 milliequivalents of anionic groups and/or groups capable of anionic group formation per 1000 grams of components (A), (B) and (D).
Claim 3
Dependent Claim
30 words
The process of claim 1, wherein the anionic group content of said filler-containing polyurethane (urea) is supplied via component (A), via component (D), or both component (A) and component (D).
Claim 4
Dependent Claim
75 words
The process of claim 1, wherein said component (A) is prepared by reacting (a) organic materials having two or more hydrogen atoms which are reactive with isocyanate groups and having molecular weights of from 400 to 10,000, (b) from 0 to 5 moles per mole of (a) of materials having two or more hydrogen atoms which are reactive with isocyanate groups and having molecular weights of from 32 to 399, (c) organic di- and/or polyisocyanates.
Claim 5
Dependent Claim
56 words
The process of claim 3, wherein said component (A) is prepared by reacting (a), (b), (c) and (d) an organic compound containing (i) either at least one hydrogen atom which is reactive with an isocyanate group or at least one isocyanate group and (ii) at least one anionic group or group capable of anionic group formation.
Claim 6
Dependent Claim
18 words
The process of claim 3 wherein said component (b) has a molecular weight of from 62 to 254.
Claim 7
Dependent Claim
14 words
The process of claim 3, wherein said component (b) is a di- and/or polyol.
Claim 8
Dependent Claim
17 words
The process of claim 1, wherein said component (A) has an isocyanate functionality of 2.1 or more.
Claim 9
Dependent Claim
26 words
The process of claim 1 wherein said component (C) is used in an amount of at least 0.5 times the weight of components (A) and (B).
Claim 10
Dependent Claim
28 words
The process of claim 8, wherein said component (C) is used in an amount of from 2 to about 60 times the weight of components (A) and (B).
Claim 11
Dependent Claim
12 words
The process of claim 1 wherein component (E) comprises polyurethane foam particles.
Claim 12
Dependent Claim
13 words
The process of claim 1 wherein component (E) comprises powdered lignite and/or peat.
Claim 13
Dependent Claim
14 words
The process of claim 1 wherein component (E) comprises active carbon and/or lignite coke.
Claim 14
Dependent Claim
19 words
The process of claim 1 wherein component (E) comprises polyurethane foam particles and either finely divided lignite or peat.
Claim 15
Dependent Claim
9 words
The process of claim 13 further including carbon powder.
Claim 16
Dependent Claim
43 words
The process of claim 1 wherein organic compounds containing at least one hydrogen atom which is reactive with an isocyanate group and at least one anionic group or group capable of anionic group formation is used in the preparation of said component (A).
Claim 17
Dependent Claim
50 words
The process of claim 15 wherein said organic compound is selected from the group consisting of diol sulphonates, diol carboxylic acids, and diol carboxylates, and wherein said filler-containing polyurethane (urea) has an anionic group content of from 30 to 1500 milliequivalents per 1000 grams of components (A), (B) and (D).
Claim 18
Dependent Claim
28 words
The process of claim 16 wherein component (D)(ii) is selected from the group consisting of diaminosulphonic acids, diaminocarboxylic acids, and the alkali metal, ammonium or amine salts thereof.
Claim 19
Dependent Claim
28 words
The process of claim 1 wherein component (D)(ii) is selected from the group consisting of diaminosulphonic acids, diaminocarboxylic acids, and the alkali metal, ammonium or amine salts thereof.
Claim 20
Dependent Claim
21 words
The process of claim 3, wherein component (a) is a polyether polyol containing less than 20% by weight of oxyethylene groups.
Claim 21
Dependent Claim
12 words
The filler-containing polyurethane (urea) produced according to the process of claim 1.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1992-06-26 | 1992-12-26 | 1993-06-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-06-26 | 1996-12-26 | 1997-06-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-06-26 | 2000-12-26 | 2001-06-27 | $7700.00 | Window Closed / Lapsed |