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US4842936A Expired / Lapsed US ⏱️ 0.0 years remaining

Composite basic resin particles, its preparation and resinous composition for coating use containing the same

Assignee: Nippon Paint Co Ltd
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Filing: 1986-11-18
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Granted: 1989-06-27
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Expires: 2006-11-18
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Abstract

Abstract Composite basic resin particles each of which comprises a granular body portion of crosslinked polymer having a mean diameter of 0.01 to 10 mu and a number of linear polymer chains, a part of the respective linear polymer chain penetrating into the inside of the granular body portion and the remaining part extending outwardly therefrom, and at least part of said linear polymer chains bearing basic functional groups selected from amino groups and ammonium group. A dispersion of said composite basic resin particles in an organic solvent is useful as a resinous vehicle for coating compositions.

Inventors

  • 👤 Akio Kashihara
  • 👤 Keizou Ishii
  • 👤 Shinichi Ishikura

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 22:54
CPC Classifications
C; C08; C08F; C08F291/00; C08F8/00; C08F8/30; C08F8/32; C08F8/44; Y; Y10; Y10S; Y10S524/00; Y10S524/923; Y10T; Y10T428/00; Y10T428/29; Y10T428/2982; Y10T428/2991; Y10T428/2998

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 94 words
Composite basic resin particles each of which comprises a granular body portion of crosslinked polymer having a means diameter of 0.01 to 10μ and a number of linear polymer chains, said crosslinked polymer selected from the group consisting of polyester resin, epoxy resin, amino resin, acrylic resin and vinyl resin, a part of the respective linear polymer chain penetrating into the inside of said granular body portion and the remaining part extending outwardly therefrom, and at least part of said linear polymer chains bearing basic functional groups selected from amino groups and ammonium group.
Claim 2
Dependent Claim 94 words
Composite basic resin particles each of which comprises a granular body portion of crosslinked polymer having a means diameter of 0.01 to 10μ and a number of linear polymer chains, said crosslinked polymer selected from the group consisting of polyester resin, epoxy resin, amino resin, acrylic resin and vinyl resin, a part of the respective linear polymer chain penetrating into the inside of said granular body portion and the remaining part extending outwardly therefrom, and at least part of said linear polymer chains bearing basic functional groups selected from amino groups and ammonium group.
Claim 3
Dependent Claim 56 words
The composite basic resin particles according to claim 1 wherein each of the linear polymer chains is composed of a polymer or a copolymer of addition polymerizable ethylenic compounds, and 0.02 to 100% by weight of the total addition polymerizable ethylenic compounds that constitute said linear polymer chains are the ethylenic compounds having basic functional groups.
Claim 4
Independent Claim 167 words
A method of preparing composite basic resin particles each of which comprises a granular body portion of crosslinked polymer having a means diameter of 0.01 to 10μ and a number of linear polymer chains, said crosslinked polymer selected from the group consisting of polyester resin, epoxy resin, amino resin, acrylic resin and vinyl resin, a part of the respective linear polymer chain penetrating into the inside of said granular body portion and the remaining part extending outwardly therefrom, and at least part of said linear polymer chains bearing basic functional groups selected from amino groups and ammonium group, which is characterized in that addition polymerizable ethylenic compounds, at least part of which are ethylenic compounds having basic functional groups selected from amino groups and ammonium group are subjected to a solution polymerization in the presence of crosslinked polymer particles having a means diameter of 0.01 to 10μ, said crosslinked polymer selected from the group consisting of polyester resin, epoxy resin, amino resin, acrylic resin and vinyl resin.
Claim 5
Independent Claim 167 words
A method of preparing composite basic resin particles each of which comprises a granular body portion of crosslinked polymer having a means diameter of 0.01 to 10μ and a number of linear polymer chains, said crosslinked polymer selected from the group consisting of polyester resin, epoxy resin, amino resin, acrylic resin and vinyl resin, a part of the respective linear polymer chain penetrating into the inside of said granular body portion and the remaining part extending outwardly therefrom, and at least part of said linear polymer chains bearing basic functional groups selected from amino groups and ammonium group, which is characterized in that addition polymerizable ethylenic compounds, at least part of which are ethylenic compounds having basic functional groups selected from amino groups and ammonium group are subjected to a solution polymerization in the presence of crosslinked polymer particles having a means diameter of 0.01 to 10μ, said crosslinked polymer selected from the group consisting of polyester resin, epoxy resin, amino resin, acrylic resin and vinyl resin.
Claim 6
Dependent Claim 40 words
The method according to claim 3, wherein the ethylenic compounds having basic functional groups selected from amino groups and ammonium group are used in an amount corresponding to 0.2 to 100% by weight of the total addition polymerizable ethylenic compounds.
Claim 7
Dependent Claim 17 words
The method according to claim 3 wherein the solution polymerization is carried out in multiple reaction steps.
Claim 8
Dependent Claim 108 words
A resinous composition for coating use comprising composite basic resin particles dispersed in an organic solvent, each of the resin particles comprising a granular body portion of crosslinked polymer having a mean diameter of 0.01 to 10μ and a number of linear polymer chains, said crosslinked polymer selected from the group consisting of polyester resin, epoxy resin, amino resin, acrylic resin and vinyl resin, a part of the respective liner polymer chain penetrating into the inside of said granular body portion and the remaining part extending outwardly therefrom, and at least part of said linear polymer chains bearing basic functional groups selected from amino groups and ammonium group.
Claim 9
Dependent Claim 108 words
A resinous composition for coating use comprising composite basic resin particles dispersed in an organic solvent, each of the resin particles comprising a granular body portion of crosslinked polymer having a mean diameter of 0.01 to 10μ and a number of linear polymer chains, said crosslinked polymer selected from the group consisting of polyester resin, epoxy resin, amino resin, acrylic resin and vinyl resin, a part of the respective liner polymer chain penetrating into the inside of said granular body portion and the remaining part extending outwardly therefrom, and at least part of said linear polymer chains bearing basic functional groups selected from amino groups and ammonium group.
Claim 10
Dependent Claim 27 words
The composition according to claim 6 wherein the organic solvent is selected from the group consisting of an aromatic hydrocarbon, aliphatic hydrocarbon, alcohol, ether, ketone and ester.

References Cited (Backward Citations)

US4119581A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-06-26 1992-12-26 1993-06-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-06-26 1996-12-26 1997-06-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-06-26 2000-12-26 2001-06-27 $7700.00 Window Closed / Lapsed

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