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US4842677A Expired / Lapsed US ⏱️ 0.0 years remaining

Excimer laser patterning of a novel resist using masked and maskless process steps

Assignee: Lockheed Martin Corp
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Filing: 1988-07-26
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Granted: 1989-06-27
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Expires: 2008-07-26
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Abstract

Abstract A dual layer resist configuration is employed for photopatterning high resolution conductive patterns on underlying polymeric or ceramic substrates, particularly substrates exhibiting surface roughness and non-planar design features such as channels, bosses and ridges. More particularly, a thin underlayer of ablatable photoabsorptive polymer is disposed on a metal coated substrate, after which a thicker layer of substantially transparent material is disposed over the polymer. A beam of laser energy, such as that produced by an ultraviolet excimer layer, is directed through the upper layer and is absorbed by the lower layer which is ablated and simultaneously removes the thick layer above it. This results in the ability to etch high resolution features on polymeric and other substrates, particularly copper coated polyetherimide circuit boards. The resist system is also applicable to VLSI wafers even though such wafers usually do not exhibit surface roughness on the scale generally considered herein. It is also equally applicable in various high density interconnect systems used for the direct connection of chip devices. A mask for patterning and a method for making it are also seen to be desirable because of the high laser energy densities generally desired for thorough ablation. An alternate method is also disclosed which employs two laser exposure steps with the first step being a masked operation on only an ablatable layer and with the second step being an unmasked operation on a dual layer material.

Inventors

  • 👤 Robert J. Wojnarowski
  • 👤 Charles W. Eichelberger

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 23:33
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/20; G03F7/2002; G03F7/2014; G03F7/2016; G03F7/202; G03F7/004; G03F7/09; G03F7/095; B; B44; B44C; B44C1/00; B44C1/22; G03F7/027; G03F7/2004; G03F7/2006; G03F7/2051; G03F7/2053; H; H05; H05K; H05K3/00; H05K3/0073; H05K3/0082; H10; H10W; H10W70/00; H10W70/60; H10W70/611; H10W70/614; H05K2203/00; H05K2203/05; H05K2203/0502; H05K2203/0505; H05K2203/0562; H05K2203/0577; H05K2203/10; H05K2203/107; H05K3/0011; H05K3/0017; H05K3/0026; H05K3/0032; H05K3/02; H05K3/06; H05K3/061; H05K3/064

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 140 words
A method for photopatterning conductive patterns, said method comprising the steps of: disposing a thin layer of ablatable photoabsorptive polymer on a substrate having a conductive layer thereon, so that said polymer material is in contact with said conductive layer; directing a beam of laser energy on said ablatable polymer, through a mask so as to ablate said polymer layer, whereby said conductive layer is partially exposed; disposing a thick layer of substantially transparent material over said partially ablated polymer layer and said exposed conductive layer, said photoabsorptivity and said transparency being determined with respect to the same frequency range; directing a beam of laser energy through said thick layer so as to ablate said polymer layer and so as to simultaneously remove said thick layer above said ablated polymer layer, whereby select portions of said conductive layer are exposed.
Claim 2
Independent Claim 140 words
A method for photopatterning conductive patterns, said method comprising the steps of: disposing a thin layer of ablatable photoabsorptive polymer on a substrate having a conductive layer thereon, so that said polymer material is in contact with said conductive layer; directing a beam of laser energy on said ablatable polymer, through a mask so as to ablate said polymer layer, whereby said conductive layer is partially exposed; disposing a thick layer of substantially transparent material over said partially ablated polymer layer and said exposed conductive layer, said photoabsorptivity and said transparency being determined with respect to the same frequency range; directing a beam of laser energy through said thick layer so as to ablate said polymer layer and so as to simultaneously remove said thick layer above said ablated polymer layer, whereby select portions of said conductive layer are exposed.
Claim 3
Dependent Claim 18 words
The method of claim 1 in which said thin layer is selected from the group consisting of polysulfones.
Claim 4
Dependent Claim 21 words
The method of claim 1 in which said thick layer is selected from the group consisting of polymethylmethacrylate, polyethylmethacrylate and polycarbonates.
Claim 5
Dependent Claim 16 words
The method of claim 1 in which said laser energy is produced by an excimer laser.
Claim 6
Dependent Claim 16 words
The method of claim 1 in which said laser energy is in the ultraviolet frequency region.
Claim 7
Dependent Claim 21 words
The method of claim 1 in which said thin layer is between about 0.1 microns and about 10 microns in thickness.
Claim 8
Dependent Claim 20 words
The method of claim 1 in which said thick layer is between approximately 1 and approximately 100 microns in thickness.
Claim 9
Dependent Claim 16 words
The method of claim 1 further including the step of etching said finally exposed conductive layer.
Claim 10
Dependent Claim 20 words
The method of claim 8 further including the step of removing any remaining material of said thick and thin layers.
Claim 11
Dependent Claim 23 words
The method of claim 1 further including the step of depositing additional conductive layer material on the exposed portion of said conductive layer.
Claim 12
Dependent Claim 16 words
The method of claim 1 further including the step of removing said thick and thin layers.
Claim 13
Dependent Claim 23 words
The method of claim 1 in which said second laser beam exposure is performed using a higher powered laser than said first exposure.
Claim 14
Dependent Claim 16 words
The method of claim 1 in which said second laser exposure is performed without a mask.
Claim 15
Dependent Claim 12 words
The method of claim 1 in which said conductive layer comprises copper.
Claim 16
Dependent Claim 16 words
The method of claim 1 in which said mask is not in contact with said substrate.
Claim 17
Dependent Claim 13 words
The method of claim 1 in which said substrate exhibits a non-planar surface.
Claim 18
Dependent Claim 12 words
The method of claim 1 in which said substrate contains feed-through apertures.
Claim 19
Dependent Claim 18 words
The method of claim 1 further including removing said ablated material by vacuum means as it is produced.
Claim 20
Dependent Claim 19 words
The method of claim 1 further including removing said ablated material by blowing it away from the ablation side.

References Cited (Backward Citations)

US4414059A Cited
US4780177A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-06-26 1992-12-26 1993-06-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-06-26 1996-12-26 1997-06-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-06-26 2000-12-26 2001-06-27 $7700.00 Window Closed / Lapsed

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