Photosensitive composition based on a diazonium salt polycondensation product with an ester polymer binder having urethane group

Claim 2

A photosensitive composition comprising (i) a photosensitive diazonium salt polycondensation product in an amount sufficient to render said composition photosensitive and (ii) a non-photosensitive polymeric binder with carboxyl side groups which is soluble or swellable in aqueous-alkaline solutions and which is present in an amount sufficient to impart layer-forming capability to a coating solution of said composition, said polymeric binder comprising the reaction product of a monofunctional intramolecular anhydride of an organic polycarboxylic acid with a polymer containing hydroxyl groups as the only functional groups capable of reaction with acid anhydrides, wherein the acid anhydride is a compound of the general formula (I) ##STR5## wherein R 1 is an alkylene group having from 2 to 6 carbon atoms, R 2 is a hydrogen atom, a substituted or unsubstituted alkyl, cycloalkyl, aryl or heteroyl group, X is a single bond or one of the groups CH 2 , SO 2 and O═P-R 3 , R 3 is an alkyl, alkenyl or aryl group, and n is a number from 1 to 6.

Claim 3

A photosensitive composition as claimed in claim 1, wherein the anhydride is a compound of the general formula I, in which n denotes a number from 1 to 3.

Claim 4

A photosensitive composition as claimed in claim 1, wherein the polymer containing hydroxyl groups has a hydroxyl number of at least 30.

Claim 5

A photosensitive composition as claimed in claim 1, wherein the polymer containing hydroxyl groups is selected from the group consisting of a polyvinyl acetal, a polyvinyl acetate having free hydroxyl groups, a copolymer of a hydroxyalkyl acrylate, and a copolymer of a hydroxyalkyl methacrylate.

Claim 6

A photosensitive composition as claimed in claim 1, wherein the binder has an acid number from 10 to 120.

Claim 7

A photosensitive composition as claimed in claim 1, wherein the negative-working diazonium salt polycondensation product comprises recurrent units A-N 2 Q and B which are linked by intermediate members derived from condensible carbonyl compounds, wherein A comprises the radical of an aromatic diazonium compound which is capable of condensation with formaldehyde and B comprises the radical of a compound which is free of diazonium groups and is capable of condensation with formaldehyde.

Claim 8

A photosensitive composition according to claim 6, wherein B is the radical of a compound selected from the group consisting of an aromatic amine, a phenol, a phenol ether, aromatic heterocyclic compound and an organic acid amide.

Claim 9

A photosensitive composition as claimed in claim 6, wherein the units A-N 2 Q are derived from compounds corresponding to the general formula (R.sup.6 --R.sup.7 --).sub.p R.sup.8 --N.sub.2 Q wherein Q is the anion of the diazonium compound, p is an integer from 1 to 3, R 6 is an aromatic radical which is capable of condensation with an active carbonyl compound, in at least one position, R 8 is an unsubstituted or substituted phenylene group, and R 7 is a single bond or one of the groups: --(CH 2 ) q --NR 9 -- --O--(CH 2 ) r --NR 9 --, --S--(CH 2 ) r --NR 9 --, --S--CH 2 CO--NR 9 --, --O--R 10 --O--, --O--, --S--, or --CO--NR 9 --, wherein q ia a number from 0 to 5, r is a number from 2 to 5, R 9 is a hydrogen atom, an alkyl group having from 1 to 5 carbon atoms, an aralkyl group having from 7 to 12 carbon atoms or an aryl group having from 6 to 12 carbon atoms, and R 10 is an arylene group having from 6 to 12 carbon atoms, and wherein B is the radical of an aromatic amine, phenol, thiophenol, phenolether, aromatic thioether, aromatic hydrocarbon, an aromatic heterocyclic compound, or an organic acid amide, which is free of diazonium groups.

Claim 10

Photosensitive recording material comprising a support and a photosensitive layer, wherein the photosensitive layer comprises a composition as claimed in claim 1.

Claim 11

A photosensitive recording material as claimed in claim 9, wherein the support comprises aluminum or an aluminum alloy.

Claim 12

A photosensitive composition according to claim 6, wherein the intermediate members are methylene groups.

Claim 13

A photosensitive composition according to claim 2, wherein X is selected from the group consisting of a single bond and SO 2 .

Claim 14

A photosensitive composition as claimed in claim 1, wherein said composition comprises from about 5 to 90% by weight of said diazonium salt polycondensation product and from about 30 to 90% by weight of said polymeric binder.