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US4839228A Expired / Lapsed US ⏱️ 0.0 years remaining

Biconstituent polypropylene/polyethylene fibers

Assignee: Dow Chemical Co
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Filing: 1987-02-12
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Granted: 1989-06-13
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Expires: 2007-02-12
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Abstract

Abstract Extrudable blends of polypropylene and polyethylene, especially LLDPE, are prepared in a dynamic mixer and extruded as novel biconstituent fibers comprising polypropylene as one phase and polyethylene as another phase. Improved tenacity and hand are obtained, as compared to polypropylene alone.

Inventors

  • 👤 Zdravko Jezic
  • 👤 Gene P. Young

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 11:21
CPC Classifications
D; D01; D01F; D01F8/00; D01F8/04; D01F8/06; D01F6/00; D01F6/44; D01F6/46; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2913; Y10T428/298

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 104 words
A blend of highly crystalline polypropylene and LLDPE, said blend being in the form of biconstituent fibers produced in a fiber-making process which uses and intensive mixer-extruder in melt-blending and melt-extruding said blend of highly crystalline polypropylene and LLDPE, said LLDPE being characterized as having a melt flow rate in the range of about 12 to about 120 gms/10 min. as measured in accordance with ASTM D-1238(E), said polypropylene being characterized as being a constant rheology grade, with the ratio of polypropylene/LLDPE being within the range of about 78/22 to about 55/45, and wherein said fibers have a size less than about 30 denier.
Claim 2
Dependent Claim 104 words
A blend of highly crystalline polypropylene and LLDPE, said blend being in the form of biconstituent fibers produced in a fiber-making process which uses and intensive mixer-extruder in melt-blending and melt-extruding said blend of highly crystalline polypropylene and LLDPE, said LLDPE being characterized as having a melt flow rate in the range of about 12 to about 120 gms/10 min. as measured in accordance with ASTM D-1238(E), said polypropylene being characterized as being a constant rheology grade, with the ratio of polypropylene/LLDPE being within the range of about 78/22 to about 55/45, and wherein said fibers have a size less than about 30 denier.
Claim 3
Dependent Claim 18 words
The blend of claim 1 wherein the LLDPE has a melt flow rate of about 50+20 gms/10 min.
Claim 4
Dependent Claim 28 words
The blend of claim 1 wherein the LLDPE is a copolymer of ethylene/1-octene wherein the 1-octene comprises about 3 to about 20 percent by weight of the copolymer.
Claim 5
Dependent Claim 20 words
The blend of claim 1 wherein the ratio of polypropylene/LLDPE is in the range of about 75/25 to about 35/65.
Claim 6
Dependent Claim 28 words
The blend of claim 1 wherein the ethylene comprises about 25 to about 35 weight percent ratio of polypropylene/LLDPE is in the range of about 72/28 to 68/32.
Claim 7
Dependent Claim 27 words
The blend of claim 1 wherein the LLDPE is a copolymer of ethylene and 1-octene and comprises about 28 to about 32 weight percent of the total.
Claim 8
Dependent Claim 20 words
The biconstituent fibers of claim 1 wherein the size is in the denier range of about 0.5 to about 15.
Claim 9
Dependent Claim 20 words
The biconstituent fibers of claim 1 wherein the size is in the denier range of about 1 to about 5.
Claim 10
Dependent Claim 21 words
The blend of claim 1 wherein the LLDPE has a density in the range of about 0.92 to about 0.94 gms/cc.
Claim 11
Dependent Claim 15 words
The blend of claim 1 wherein the LLDPE has a density of about 0.925 gms/cc.
Claim 12
Dependent Claim 43 words
The biconstituent fibers of claim 1 comprising a polypropylene continuous phase of the fibers, and LLDPE dispersed in the polypropylene as a discontinuous phase in the form of fibrils wherein said fibrils are predominantly of a diameter of less than about 0.05 microns.
Claim 13
Dependent Claim 21 words
The biconstituent fibers of claim 1 wherein the tenacity of the fibers is greater than either of the constituents taken alone.
Claim 14
Dependent Claim 17 words
The biconstituent fiber of claim 1 wherein the softness is better than the polypropylene constituent taken alone.
Claim 15
Dependent Claim 127 words
A biconstituent fiber consisting essentially of highly crystalline polypropylene as a continuous phase, having distributed therein 22 to about 45 percent by weight of polyethylene fibrils as a dispersed phase arrayed in a substantially omni-directionally splayed manner, wherein said polyethylene is LLDPE having a melt flow rate in the range of about 20 to about 100 gms/10 min., a density in the range of about 0.92 to about 0.94 gms/cc, and an alkylene comonomer content in the range of about 3 to about 20 percent by weight of the LLDPE, and wherein the biconstituent fiber has a denier size of less than about 30, said biconstituent fiber having been produced in a fiber-making process which uses an intensive mixer-extruder in melt-blending and melt-extruding the polypropylene and LLDPE.
Claim 16
Dependent Claim 127 words
A biconstituent fiber consisting essentially of highly crystalline polypropylene as a continuous phase, having distributed therein 22 to about 45 percent by weight of polyethylene fibrils as a dispersed phase arrayed in a substantially omni-directionally splayed manner, wherein said polyethylene is LLDPE having a melt flow rate in the range of about 20 to about 100 gms/10 min., a density in the range of about 0.92 to about 0.94 gms/cc, and an alkylene comonomer content in the range of about 3 to about 20 percent by weight of the LLDPE, and wherein the biconstituent fiber has a denier size of less than about 30, said biconstituent fiber having been produced in a fiber-making process which uses an intensive mixer-extruder in melt-blending and melt-extruding the polypropylene and LLDPE.
Claim 17
Dependent Claim 21 words
The biconstituent fiber of claim 14 having a denier size in the fine denier range of about 0.5 to about 15.
Claim 18
Dependent Claim 20 words
The biconstituent fiber of claim 14 having a fine denier size in the range of about 1 to about 5.
Claim 19
Dependent Claim 19 words
The biconstituent fiber of claim 14 wherein the LLDPE has a melt flow rate of about 50±20 gms/10 min.
Claim 20
Dependent Claim 21 words
The biconstituent fiber of claim 14 wherein the LLDPE fibrils are predominantly of a diameter of less than about 0.05 microns.
Claim 21
Dependent Claim 13 words
The biconstituent fiber of claim 14 wherein the said alkylene comonomer is 1-octene.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-06-12 1992-12-12 1993-06-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-06-12 1996-12-12 1997-06-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-06-12 2000-12-12 2001-06-13 $7700.00 Window Closed / Lapsed

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