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US4838267A Expired / Lapsed US ⏱️ 0.0 years remaining

Glycolide/p-dioxanone block copolymers

Assignee: Ethicon Inc
•
Filing: 1988-02-12
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Granted: 1989-06-13
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Expires: 2008-02-12
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Abstract

Abstract Block copolymers of glycolide and p-dioxanone are produced by reacting poly(p-dioxanone) that is substantially free of p-dioxanone monomer with glycolide.

Inventors

  • 👤 Dennis D. Jamiolkowski
  • 👤 Shalaby W. Shalaby
  • 👤 Rao S. Bezwada
  • 👤 Hugh D. Newman, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 18:53
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/02; C08G63/06; C08G63/08; A; A61; A61L; A61L17/00; A61L17/06; A61L17/10; A61L17/12; A61L31/00; A61L31/04; A61L31/06; Y; Y10; Y10S; Y10S525/00; Y10S525/937

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 63 words
A glycolide/p-dioxanone block copolymer which consists essentially of from 40 to 90 weight percent polymerized glycolide, the remainder being polymerized p-dioxanone, and which has an overall crystallinity of from about 25 to 45 percent, a glycolide-based crystallinity of from about 15 to 40 percent, and a melting temperature, by hot stage microscopy, within the range of from 140° C. to about 230° C.
Claim 2
Dependent Claim 63 words
A glycolide/p-dioxanone block copolymer which consists essentially of from 40 to 90 weight percent polymerized glycolide, the remainder being polymerized p-dioxanone, and which has an overall crystallinity of from about 25 to 45 percent, a glycolide-based crystallinity of from about 15 to 40 percent, and a melting temperature, by hot stage microscopy, within the range of from 140° C. to about 230° C.
Claim 3
Dependent Claim 18 words
The glycolide/p-dioxanone block copolymer of claim 1 wherein said copolymer contains greater than 50 weight percent polymerized glycolide.
Claim 4
Dependent Claim 18 words
The glycolide/p-dioxanone block copolymer of claim 1 wherein said copolymer contains greater than 60 weight percent polymerized glycolide.
Claim 5
Dependent Claim 55 words
A dimensionally stable, drawn, and oriented surgical filament comprising the block copolymer of claim 1, said filament having a straight tensile strength greater than about 30,000 psi and Young's modulus below about 700,000 psi, and wherein said filament loses from 50 to 100 percent of its strength within two weeks after implantation in the body.
Claim 6
Dependent Claim 55 words
A dimensionally stable, drawn, and oriented surgical filament comprising the block copolymer of claim 2, said filament having a straight tensile strength greater than about 30,000 psi and Young's modulus below about 700,000 psi, and wherein said filament loses from 50 to 100 percent of its strength within two weeks after implantation in the body.
Claim 7
Dependent Claim 50 words
A dimensionally stable, drawn, and oriented surgical filament comprising the block copolymer of claim 3, said tensile strength greater than 30,000 psi and Young's modulus below about 700,000 psi, and wherein said filament loses from 50 to 100 percent of its strength within two weeks after implantation in the body.
Claim 8
Dependent Claim 11 words
The filament of claim 4 in the form of a monofilament.
Claim 9
Dependent Claim 11 words
The filament of claim 4 in the form of a braid.
Claim 10
Dependent Claim 12 words
The filament of claim 4 in the form of a sterile suture.
Claim 11
Dependent Claim 11 words
The sterile suture of claim 9 attached to a surgical needle.

References Cited (Backward Citations)

US3297033A Cited
US4052988A Cited
US4300565A Cited
US4137921A Cited
US4157437A Cited
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US4643191A Cited
US4653497A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-06-12 1992-12-12 1993-06-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-06-12 1996-12-12 1997-06-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-06-12 2000-12-12 2001-06-13 $7700.00 Window Closed / Lapsed

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