Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
217 words
A process for preparing an acrylamidoacyl or methacrylamidoacyl oligomer comprising the steps: (a) admixing (1) at least one alkenyl azlactone having the formula: ##STR9## wherein R 1 is hydrogen, chlorine, or a methyl group; R 2 is a single bond or a methylene or ethylene group that can be substituted by an alkyl group having 1 to 6 carbon atoms or a phenyl group; R 3 and R 4 are independently hydrogen, an alkyl or cycloalkyl group having 1 to 12 carbon atoms, a phenyl group or an alkyl-substituted phenyl group having 6 to 12 carbon atoms, or R 3 and R 4 taken together with the carbon atom to which they are attached form a 5- to 12-membered carbocyclic ring; and (2) per mole of alkenylazlactone about 0.8 to 1.2 equivalent weights of at least one nucleophilic group-substituted oligomer having a molecular weight in the range of 200 to 20,000 selected from a group consisting of (1) polyether polyols, (2) polyester polyols, (3) polyoxyalkylene polyamines (4) hydroxy- and amino-functional derivatives of polymerized fatty acids, (5) hydroxy- or amino-functional olefin polymers and copolymers, (6) primary or secondary amino-functional polyamides, (7) polyethyleneimines; (8) polyvinyl alcohol and other hydrolyzed or partially hydrolyzed vinyl acetate homo- and interpolymers, and (9) polysiloxane polyols; and (b) isolating said acrylamidoacyl or methacrylamidoacyl oligomer.
Claim 2
Dependent Claim
217 words
A process for preparing an acrylamidoacyl or methacrylamidoacyl oligomer comprising the steps: (a) admixing (1) at least one alkenyl azlactone having the formula: ##STR9## wherein R 1 is hydrogen, chlorine, or a methyl group; R 2 is a single bond or a methylene or ethylene group that can be substituted by an alkyl group having 1 to 6 carbon atoms or a phenyl group; R 3 and R 4 are independently hydrogen, an alkyl or cycloalkyl group having 1 to 12 carbon atoms, a phenyl group or an alkyl-substituted phenyl group having 6 to 12 carbon atoms, or R 3 and R 4 taken together with the carbon atom to which they are attached form a 5- to 12-membered carbocyclic ring; and (2) per mole of alkenylazlactone about 0.8 to 1.2 equivalent weights of at least one nucleophilic group-substituted oligomer having a molecular weight in the range of 200 to 20,000 selected from a group consisting of (1) polyether polyols, (2) polyester polyols, (3) polyoxyalkylene polyamines (4) hydroxy- and amino-functional derivatives of polymerized fatty acids, (5) hydroxy- or amino-functional olefin polymers and copolymers, (6) primary or secondary amino-functional polyamides, (7) polyethyleneimines; (8) polyvinyl alcohol and other hydrolyzed or partially hydrolyzed vinyl acetate homo- and interpolymers, and (9) polysiloxane polyols; and (b) isolating said acrylamidoacyl or methacrylamidoacyl oligomer.
Claim 3
Dependent Claim
27 words
The process according to claim 1 further comprising admixing an amount of a catalyst selected from Lewis acids and strong bases sufficient to cause a ring-opening reaction.
Claim 4
Dependent Claim
163 words
The process according to claim 1 wherein R 5 is a hydrocarbyl group selected from an alkyl or cycloalkyl group having 1 to 12 carbon atoms and is substituted by a cyano, hydroxyl, an alkoxy group having 1 to 4 carbon atoms, or A, wherein A is an acrylamido-acyl group or a methacrylamido-acyl group having the formula ##STR10## wherein R 1 is hydrogen, chlorine, or a lower alkyl group of 1 to 4 carbon atoms; R 2 is a single bond or a methylene or ethylene group, the last two of which can be substituted by an alkyl group having 1 to 6 carbon atoms or a phenyl group; R 3 and R 4 are independently hydrogen, an alkyl or cycloalkyl group having 1 to 12 carbon atoms, an aryl or aralkyl group having 6 to 12 carbon atoms, or R 3 and R 4 taken together with the carbon atom to which they are attached form a 5- to 12-membered carbocyclic ring.
Claim 5
Dependent Claim
26 words
The process according to claim 1 wherein the admixture further comprises a thermally or photochemically activatable free radical generator sufficient to initiate polymerization of the admixture.
Claim 6
Dependent Claim
20 words
The process according to claim 4 wherein the admixture further comprises at least one monomer containing free-radically polymerizable ethylenic unsaturation.
Claim 7
Dependent Claim
24 words
The process according to claim 5 further comprising the step of subjecting the admixture to thermal or activating radiation to provide a polymeric composition.