US4837005A
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US
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Partially hydrolyzed, poly(N-acyl)alkylenimines in personal care
Assignee: Union Carbide Corp
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Filing: 1986-09-30
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Granted: 1989-06-06
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Expires: 2006-09-30
Abstract
Abstract Partially hydrolyzed, poly(N-acyl)alkylenimines), and novel nitrogen-substituted derivatives thereof, provide useful and improved personal care compositions and processes.
Inventors
- 👤 II George L. Brode
- 👤 II Frederick M. Merritt
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 14:28
CPC Classifications
C; C08; C08G; C08G73/00; C08G73/02; C08G73/0233; A; A61; A61K; A61K8/00; A61K8/18; A61K8/72; A61K8/84; A61Q; A61Q19/00; A61Q19/10; A61Q5/00; A61Q5/02; A61Q5/12
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
151 words
A personal care composition comprising carrier and an effective managing amount of partially hydrolyzed, poly(N-acyl alkylenimine) containing repeating units represented by the structural formula: ##STR9## wherein a is from about 1 to about 50 mole percent; and wherein for each repeating unit individually: Q is an anion; R 1 is hydrogen, alkyl, aryl, aralkyl or alkaryl; R 2 is hydrogen or a hydrocarbyl-containing group; R 3 is hydrogen, alkyl, aryl, aralkylo or alkaryl; v is equal to the valence of Q; x is 2 or 3; y is 0 or 1; and z is 0 or 1; provided that: (1) when R 3 is oxygen than y is 0, R 2 is a hydrcarbyl-containing group and z is 1; (2) when R 3 is not oxygen then y and z are 1; and (3) when all z values are 0 then at least one R 3 group is a hydrocarbyl-containing group.
Claim 2
Dependent Claim
151 words
A personal care composition comprising carrier and an effective managing amount of partially hydrolyzed, poly(N-acyl alkylenimine) containing repeating units represented by the structural formula: ##STR9## wherein a is from about 1 to about 50 mole percent; and wherein for each repeating unit individually: Q is an anion; R 1 is hydrogen, alkyl, aryl, aralkyl or alkaryl; R 2 is hydrogen or a hydrocarbyl-containing group; R 3 is hydrogen, alkyl, aryl, aralkylo or alkaryl; v is equal to the valence of Q; x is 2 or 3; y is 0 or 1; and z is 0 or 1; provided that: (1) when R 3 is oxygen than y is 0, R 2 is a hydrcarbyl-containing group and z is 1; (2) when R 3 is not oxygen then y and z are 1; and (3) when all z values are 0 then at least one R 3 group is a hydrocarbyl-containing group.
Claim 3
Dependent Claim
14 words
The composition of claim 1 wherein all R 2 and R 3 are hydrogen.
Claim 4
Dependent Claim
12 words
The composition of claim 1 wherein Q represents a mixture of anions.
Claim 5
Dependent Claim
18 words
The composition of claim 1 wherein at least one R 2 or R 3 is a hydrocarbyl-containing group.
Claim 6
Dependent Claim
17 words
The composition of claim 4 wherein at least one hydrocarbyl-conatining group has a cationic or anionic group.
Claim 7
Dependent Claim
50 words
The composition of claim 1 containing an effective amount of one or more suitable personal care ingredients sufficient to provide a soap, shampoo, cream, lotion, hair spray, hair or skin conditioner, mousse, antiperspirant, deodorant, hair set, hair wave, hair straightener, make-up, shave cream or gel, after shave lotion or balm.
Claim 8
Dependent Claim
52 words
The composition of claim 6 wherein said personal care ingredient is a surfactant, cleanser, colorant, preservative, moisturizer, pH adjustor, emulsifier, propellant, conditioner, thickener, fragrance, foaming agent, sunscreen, depilatory, flavor, astringent agent, antiseptic, deodorant, antiperspirant, insect repellant, bleach, anti-dandruff agent, adhesive, polish, strengthener, filler, barrier material, other personal care ingredient, or mixtures thereof.
Claim 9
Dependent Claim
80 words
The composition of claim 1 wherein: a is from about 3 to about 30 mole percent; Q is selected from the group consisting of: halides, phosphites, phosphonates, phosphates nitrates, sulfates, sulfonates, carbonates, carboxylates, or mixtures thereof; R 1 is hydrogen, methyl, ethyl or propyl; each R 2 and R 3 is individually hydrogen, alkyl, aryl, alkaryl, aralkyl or alkyloxy which is unsubstituted or substituted with hydroxyl, sulfonato, amino, ammonio, carboxyl, carboxylate, or mixtures thereof; and v is 1 or 2.
Claim 10
Dependent Claim
48 words
The composition of claim 1 wherein each R 1 is ethyl and each x is 2, providing the poly(N-propionyl ethylenimine) containing repeating units represented by the structural formula: ##STR10## wherein a, Q, R 2 , R 3 , v, y and z are as defined in claim 1.
Claim 11
Dependent Claim
72 words
The composition of claim 9 wherein: a is from about 3 to about 30 mole percent; Q is selected from the group consisting of: halides, phosphites, phosphonates, phosphates, nitrates, sulfates, sulfonates, carbonates, carboxylates, or mixtures thereof; each R 2 and R 3 is individually hydrogen, alkyl, aryl, alkaryl, aralkyl or alkyloxy which is unsubstituted or substituted with hydroxyl, sulfonato, amino, ammonio, carboxyl, carboxylate, or mixtures thereof; and v is 1 or 2.
Claim 12
Dependent Claim
39 words
The composition of claim 10 wherein: a is about 12 mole percent; Q is chloride, propionate, or mixtures thereof; each R 2 and R 3 is individually hydrogen, 2-hydroxy-3-(trimethylammonio)propyl, 2-hydroxy-3-(dimethyldodecylammonio)propyl, 2-hydroxy-3-sulfonatopropyl, 2,3-dihydroxypropyl, or mixtures thereof; and v is 1.
Claim 13
Dependent Claim
158 words
A process for producing a personal care composition which comprises providing a carrier with an effective managing amount of partially hydrolyzed, poly(N-acyl alkylenimine) containing repeating units represented by the structural formula: ##STR11## wherein a is from about 1 to about 50 mole percent; and wherein for each repeating unit individually: Q is an anion; R 1 is hydrogen, alkyl, aryl, aralkyl or alkaryl; R 2 is hydrogen or a hydrocarbyl-containing group; R 3 is hydrogen, oxygen or a hydrocarbyl-containing group; v is equal to the valence of Q; x is 2 or 3; y is 0 is 1; and z is 0 or 1; provided that: (1) when R 3 is oxygen then y is 0, R 2 is a hydrocarbyl-containing group and z is 1; (2) when R 3 is not oxygen then y and z are 1; and (3) when all z values are 0 then at least one R 3 group is a hydrocarbyl-containing group.
Claim 14
Dependent Claim
158 words
A process for producing a personal care composition which comprises providing a carrier with an effective managing amount of partially hydrolyzed, poly(N-acyl alkylenimine) containing repeating units represented by the structural formula: ##STR11## wherein a is from about 1 to about 50 mole percent; and wherein for each repeating unit individually: Q is an anion; R 1 is hydrogen, alkyl, aryl, aralkyl or alkaryl; R 2 is hydrogen or a hydrocarbyl-containing group; R 3 is hydrogen, oxygen or a hydrocarbyl-containing group; v is equal to the valence of Q; x is 2 or 3; y is 0 is 1; and z is 0 or 1; provided that: (1) when R 3 is oxygen then y is 0, R 2 is a hydrocarbyl-containing group and z is 1; (2) when R 3 is not oxygen then y and z are 1; and (3) when all z values are 0 then at least one R 3 group is a hydrocarbyl-containing group.
Claim 15
Dependent Claim
72 words
The process of claim 12 wherein: a is from about 3 to about 30 mole percent; Q is selected from the group consisting of: halides, phosphites, phosphonates, phosphates, nitrates, sulfates, sulfonates, carbonates, carboxylates, or mixtures thereof; each R 2 and R 3 is individually hydrogen, alkyl, aryl, alkaryl, aralkyl or alkyloxy which is unsubstituted or substituted with hydroxyl, sulfonato, amino, ammonio, carboxyl, carboxylate, or mixtures thereof; and v is 1 or 2.
Claim 16
Dependent Claim
49 words
The process of claim 13 wherein each R 1 is ethyl and each x value is 2 providing the poly(N-propionyl ethylenimine) containing repeating units represented by the structural formula: ##STR12## wherein a, Q, R 2 , R 3 , v, y and z are as defined in claim 12.
Claim 17
Dependent Claim
39 words
The process of claim 14 wherein: a is about 12 mole percent; Q is chloride, propionate, or mixtures thereof; each R 2 and R 3 is individually hydrogen, 2-hydroxy-3-(trimethylammonio)propyl, 2-hydroxy-3-(dimethyldodecylammonio)propyl, 2-hydroxy-3-sulfonatopropyl, 2,3-dihydroxypropyl, or mixtures thereof; and v is 1.
Claim 18
Dependent Claim
155 words
A process for managing keratinous substrate comprising applying to said substrate an effective managing amount of partially hydrolyzed, poly(N-acyl alkylenimine) containing repeating units represented by the structural formula: ##STR13## wherein a is from about 1 to about 50 mole percent; and wherein for each repeating unit individually: Q is an anion; R 1 is hydrogen, alkyl, aryl, aralkyl or alkaryl; R 2 is hydrogen or a hydrocarbyl-containing group; R 3 is hydrogen, oxygen or a hydrocarbyl-containing group; v is equal to the valence of Q; x is 2 or 3; y is 0 or 1 and z is 0 or 1; provided that: (1) when R 3 is oxygen than y is 0, R 2 is a hydrocarbyl-containing group and z is 1; (2) when R 3 is not oxygen then y and z are 1; and (3) when all z values are 0 then at least one R 3 group is a hydrocarbyl-containing group.
Claim 19
Dependent Claim
155 words
A process for managing keratinous substrate comprising applying to said substrate an effective managing amount of partially hydrolyzed, poly(N-acyl alkylenimine) containing repeating units represented by the structural formula: ##STR13## wherein a is from about 1 to about 50 mole percent; and wherein for each repeating unit individually: Q is an anion; R 1 is hydrogen, alkyl, aryl, aralkyl or alkaryl; R 2 is hydrogen or a hydrocarbyl-containing group; R 3 is hydrogen, oxygen or a hydrocarbyl-containing group; v is equal to the valence of Q; x is 2 or 3; y is 0 or 1 and z is 0 or 1; provided that: (1) when R 3 is oxygen than y is 0, R 2 is a hydrocarbyl-containing group and z is 1; (2) when R 3 is not oxygen then y and z are 1; and (3) when all z values are 0 then at least one R 3 group is a hydrocarbyl-containing group.
Claim 20
Dependent Claim
72 words
The process of claim 16 wherein: a is from about 3 to about 30 mole percent; Q is selected from the group consisting of: halides, phosphites, phosphonates, phosphates, nitrates, sulfates, sulfonates, carbonates, carboxylates, or mixtures thereof; each R 2 and R 3 is individually hydrogen, alkyl, aryl, alkaryl, aralkyl or alkyloxy which is unsubstituted or substituted with hydroxyl, sulfonato, amino, ammonio, carboxyl, carboxylate, or mixtures thereof; and v is 1 or 2.
Claim 21
Dependent Claim
46 words
The process of claim 17 wherein each R 1 is ethyl and each x value is 2 providing the poly(N-propionyl ethylenimine) containing repeating units represented by the structural formula: ##STR14## wherein a, Q, R 1 , v, y and z are as defined in claim 16.
Claim 22
Dependent Claim
39 words
The process of claim 18 wherein: a is about 12 mole percent; Q is chloride, propionate, or mixtures thereof; each R 2 and R 3 is individually hydrogen, 2-hydroxy-3-(trimethylammonio)propyl, 2-hydroxy-3-(dimethyldodecylammonio)propyl, 2-hydroxy-3-sulfonatopropyl, 2,3-dihydroxypropyl, or mixtures thereof; and v is 1.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1992-06-05 | 1992-12-05 | 1993-06-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-06-05 | 1996-12-05 | 1997-06-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-06-05 | 2000-12-05 | 2001-06-06 | $7700.00 | Window Closed / Lapsed |