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US4833059A Expired / Lapsed US ⏱️ 0.0 years remaining

Developing method using one-component non-magnetic toner with positive frictional charge

Assignee: Toshiba Corp
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Filing: 1987-03-16
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Granted: 1989-05-23
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Expires: 2007-03-16
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Abstract

Abstract A developing method for converting an electrostatic latent image on the surface of an electrostatic latent image holder into a visible image by arranging the electrostatic latent image holder for holding the electrostatic latent image thereon and a toner conveyor for conveying non-magnetic one-component type toner thereon an extremely small space apart from each other; applying the non-magnetic one-component type toner onto the toner conveyor; and transferring the toner to the electrostatic image holder, satisfies the following requirements: the aforesaid developing agent is composed of non-magnetic type toner; the frictional charge quantity relative to the surface of the non-magnetic type toner is +30 100 μC; and fluidity is 5 g or less in terms of the toner amounting to 20 g but remaining on a 100-mesh sieve after it has been vibrated at a rate of 3,000 V.P.M. and an amplitude of 1 mm for 30 seconds. The non-magnetic one-component type toner may positively charged non-magnetic one-component type toner at least containing resin and a coloring agent, the resin satisfying the following requirements: the glass transition point is over 50° C.; the softening point is within the range of 110° C.-160° C.; and the frictional charge amount relative to the surface area is within the range of 25˜150 μC/m 2 . The non-magnetic one-component type toner may be prepared by treating the surface of toner containing binder resin whose glass transition point is over 50° C., and whose softening point is within the range of 110°˜160° C., and a coloring agent with a silane coupling agent having an amino group. According to the above method, development fog and the scattering of the toner are prevented so that a visible image of good quality can be formed.

Inventors

  • 👤 Shinya Tomura
  • 👤 Tetsuo Okuyama
  • 👤 Mitsunaga Saito
  • 👤 Tsutomu Uehara

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 21:24
CPC Classifications
G; G03; G03G; G03G13/00; G03G13/06; G03G13/08; G03G9/00; G03G9/08; G03G9/0821; G03G9/0823; G03G9/087; G03G9/08702; G03G9/08726; G03G9/08728; G03G9/097; G03G9/09733; G03G9/09775

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 218 words
A developing method for converting an electrostatic latent image on the surface of an electrostatic latent image holder into a visible image, comprising the steps of: arranging the electrostatic latent image holder for holding the electrostatic latent image thereon and a toner conveyer for conveying positively-charged non-magnetic one-component type toner thereon an extremely small space apart from each other; applying the non-magnetic one-component type toner onto the toner conveyer and contacting the toner with a blade to form a thin layer of toner on the conveyer and frictionally charge the toner; and transferring the toner to the electrostatic latent image holder; wherein the frictional charge quantity relative to the surface of the non-magnetic type toner is +30˜100 mC/m 2 ; and fluidity is not more than 5 g in terms of the toner amounting to 20 g but remaining on a 100-mesh sieve after it has been vibrated at a rate of 3,000 V.P.M. and an amplitude of 1 mm for 30 seconds, and wherein the positively-charged toner contains a resin and a coloring agent, said resin being a styrene-(meth)acrylamino methacrylic copolymer having a glass transition point over 50° C.; a softening point within the range of 110° C.-160° C.; and a frictional charge amount relative to the surface area within the range of 25˜150 μC/m 2 .
Claim 2
Dependent Claim 218 words
A developing method for converting an electrostatic latent image on the surface of an electrostatic latent image holder into a visible image, comprising the steps of: arranging the electrostatic latent image holder for holding the electrostatic latent image thereon and a toner conveyer for conveying positively-charged non-magnetic one-component type toner thereon an extremely small space apart from each other; applying the non-magnetic one-component type toner onto the toner conveyer and contacting the toner with a blade to form a thin layer of toner on the conveyer and frictionally charge the toner; and transferring the toner to the electrostatic latent image holder; wherein the frictional charge quantity relative to the surface of the non-magnetic type toner is +30˜100 mC/m 2 ; and fluidity is not more than 5 g in terms of the toner amounting to 20 g but remaining on a 100-mesh sieve after it has been vibrated at a rate of 3,000 V.P.M. and an amplitude of 1 mm for 30 seconds, and wherein the positively-charged toner contains a resin and a coloring agent, said resin being a styrene-(meth)acrylamino methacrylic copolymer having a glass transition point over 50° C.; a softening point within the range of 110° C.-160° C.; and a frictional charge amount relative to the surface area within the range of 25˜150 μC/m 2 .
Claim 3
Dependent Claim 24 words
A developing method as claimed in claim 1, wherein said non-magnetic one-component type toner contains 0.05˜5 parts by weight of positively charged colloidal silica.
Claim 4
Dependent Claim 188 words
A developing method for converting an electrostatic latent image on the surface of an electrostatic latent image holder into a visible image, comprising the steps of: arranging the electrostatic latent image holder for holding the electrostatic latent image thereon and a toner conveyer for conveying non-magnetic one-component type toner thereon an extremely small space apart from each other; applying the non-magnetic one-component type toner onto the toner conveyer; and transferring the toner to the electrostatic image holder, wherein said non-magnetic one-component type toner is prepared by treating the surface of toner containing binder resin whose glass transition point is over 50° C. and whose softening point is within the range of 110°˜160° C. and a coloring agent with a silane coupling agent having an amino group, and wherein the frictional charge quantity relative to the surface of the non-magnetic type toner is +30-100 mC/m 2 ; and fluidity is not more than 5 g in terms of the toner amounting to 20 g but remaining on 100-mesh sieve after it has been vibrated at a rate of 3,000 V.P.M. and an amplitude of 1 mm for 30 seconds.
Claim 5
Dependent Claim 188 words
A developing method for converting an electrostatic latent image on the surface of an electrostatic latent image holder into a visible image, comprising the steps of: arranging the electrostatic latent image holder for holding the electrostatic latent image thereon and a toner conveyer for conveying non-magnetic one-component type toner thereon an extremely small space apart from each other; applying the non-magnetic one-component type toner onto the toner conveyer; and transferring the toner to the electrostatic image holder, wherein said non-magnetic one-component type toner is prepared by treating the surface of toner containing binder resin whose glass transition point is over 50° C. and whose softening point is within the range of 110°˜160° C. and a coloring agent with a silane coupling agent having an amino group, and wherein the frictional charge quantity relative to the surface of the non-magnetic type toner is +30-100 mC/m 2 ; and fluidity is not more than 5 g in terms of the toner amounting to 20 g but remaining on 100-mesh sieve after it has been vibrated at a rate of 3,000 V.P.M. and an amplitude of 1 mm for 30 seconds.
Claim 6
Dependent Claim 72 words
A developing method as claimed in claim 3, wherein said silane coupling agent having an amino group is expressed by the following formula: ##STR6## wherein R 1 1 designates --H, --CH 3 , --C 2 H 5 , --CH 2 CH 2 OH, ##STR7## R 2 1 designates --(CH 2 )n--, ##STR8## R 3 1 designates --CH 3 , --OCH 3 , --OC 2 H 5 , and n designates 1˜4 integers.
Claim 7
Dependent Claim 24 words
A developing method as claimed in claim 4, wherein said non-magnetic one-component type toner contains 0.05˜5 parts by weight of positively charged colloidal silica.

References Cited (Backward Citations)

US2895847A Cited
US3152012A Cited
US3731146A Cited
US3909258A Cited
US4345015A Cited
US4121931A Cited
US4486559A Cited
US4557991A Cited
US4680245A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-05-22 1992-11-21 1993-05-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-05-22 1996-11-21 1997-05-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-05-22 2000-11-21 2001-05-23 $7700.00 Window Closed / Lapsed

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