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US4831005A
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Method for intercalating organic-swelled layered metal chalcogenide with a polymeric chalcogenide by plural treatments with polymeric chalcogenide precursor
Assignee: ExxonMobil Oil Corp
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Filing: 1988-01-04
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Granted: 1989-05-16
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Expires: 2008-01-04
Abstract
Abstract Organic-swelled layered metal chalcogenides, e.g., titanometallates or silicotitanates, are intercalated with polymeric chalcogenide by plural treatments with hydrolyzable, electrically neutral polymeric chalcogenide precursor, e.g., tetraethylorthosilicate, to provide products of improved surface area.
Inventors
- 👤 Brent A. Aufdembrink
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 08:11
CPC Classifications
B; B01; B01J; B01J29/00; B01J29/04; B01J29/049; C; C01; C01B; C01B13/00; C01B13/14; C01B13/145; C01B17/00; C01B17/20; C01B17/42; C01B19/00; C01B19/007; C01G; C01G23/00; C01G23/003; C07; C07C; C07C2/00; C07C2/02; C07C2/04; C07C2/06; C07C2/08; C07C2/10; C10; C10G; C10G45/00; C10G45/02; C10G45/04; C01P; C01P2002/00; C01P2002/02; C01P2002/20; C01P2002/22; C01P2002/70; C01P2002/72; C01P2002/74; C01P2002/78; C01P2006/00; C01P2006/12; C01P2006/42; C01P2006/80; C07C2521/00; C07C2521/06; C07C2521/08; C07C2521/12; Y; Y10; Y10S; Y10S502/00; Y10S502/525
Claims Analysis
Total Claims: 20
Claim 1
Independent Claim
60 words
A method for intercalating an organic-swelled layered metal chalcogenide with a polymeric chalcogenide which comprises: (a) providing between the layers of the layered metal chalcogenide an electrically neutral, organic compound capable of conversion to said polymeric chalcogenide by hydrolysis; and converting said compound in the presence of water to the interspathic polymeric chalcogenide and (b) repeating (a) at least once.
Claim 2
Independent Claim
60 words
A method for intercalating an organic-swelled layered metal chalcogenide with a polymeric chalcogenide which comprises: (a) providing between the layers of the layered metal chalcogenide an electrically neutral, organic compound capable of conversion to said polymeric chalcogenide by hydrolysis; and converting said compound in the presence of water to the interspathic polymeric chalcogenide and (b) repeating (a) at least once.
Claim 3
Dependent Claim
10 words
The method of claim 1 wherein (a) is repeated twice.
Claim 4
Dependent Claim
12 words
The method of claim 1 wherein the product of (b) is calcined.
Claim 5
Dependent Claim
24 words
The method of claim 1 wherein said interspathic polymeric chalcogenide is an interspathic polymeric oxide and said layered metal chalcogenide is a layered oxide.
Claim 6
Dependent Claim
15 words
The method of claim 1 wherein said converting is effected by the addition of water.
Claim 7
Dependent Claim
13 words
The method of claim 1 wherein said interspathic polymeric oxide comprises polymeric silica.
Claim 8
Dependent Claim
73 words
The method of claim 1 wherein said layered metal chalcogenide is titanometallate-type layered metal oxide product comprising a layered metal oxide wherein each layer of the metal oxide has the general formula [M.sub.x [].sub.y Z.sub.2-(x+y) O.sub.4 ].sup.q- wherein M is at least one metal of valence n wherein n is an integer between 0 and 7, [] represents a vacancy site, Z is a tetravalent metal, preferably titanium, and wherein q=4y-x(n-4), and 0<x+y<2
Claim 9
Dependent Claim
20 words
The method of claim 1 wherein said n is 2 or 3 and q ranges between about 0.6 and 0.9.
Claim 10
Dependent Claim
13 words
The method of claim 1 wherein said layered metal chalcogenide is a trititanate.
Claim 11
Dependent Claim
15 words
The method of claim 9 wherein said titanate comprises Ti 3 O 7 -2 layers.
Claim 12
Dependent Claim
16 words
The method of claim 1 wherein said layered metal chalcogenide is a high silica alkali silicate.
Claim 13
Dependent Claim
26 words
The method of claim 11 wherein said silicate is selected from the group consisting of magadiite, natrosilite, kenyaite, makatite, nekoite, kanemite, okenite, dehayelite, macdonaldite and rhodesite.
Claim 14
Dependent Claim
10 words
The method of claim 12 wherein said silicate is magadiite.
Claim 15
Dependent Claim
12 words
The method of claim 1 wherein said electrically neutral compound is tetraalkylorthosilicate.
Claim 16
Dependent Claim
12 words
The method of claim 1 wherein said electrically neutral compound is tetraethylorthosilicate.
Claim 17
Dependent Claim
12 words
The method of claim 1 wherein said swelling organic is an alkylamine.
Claim 18
Dependent Claim
11 words
The method of claim 1 wherein said swelling organic is n-octylamine.
Claim 19
Dependent Claim
13 words
The method of claim 1 wherein said swelling organic is an alkylammonium ion.
Claim 20
Dependent Claim
13 words
The method of claim 1 wherein said swelling organic is the n-octylammonium ion.
References Cited (Backward Citations)
US4600503A
Cited
US4650779A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1992-05-15 | 1992-11-14 | 1993-05-16 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-05-15 | 1996-11-14 | 1997-05-16 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-05-15 | 2000-11-14 | 2001-05-16 | $7700.00 | Window Closed / Lapsed |