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US4829024A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of forming layered polysilicon filled contact by doping sensitive endpoint etching

Assignee: Motorola Solutions Inc
•
Filing: 1988-09-02
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Granted: 1989-05-09
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Expires: 2008-09-02
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Abstract

Abstract A semiconductor process is provided for the formation of a very low resistance contact. After a straight wall contact is formed conventionally above a silicon substrate, a blanket metal barrier layer is deposited. A plurality of planar polysilicon layers are deposited above the metal barrier layer. The polysilicon layers have varying doping levels and are etched away. A byproduct gas of the etch reaction is monitored and the transition between polysilicon layers can be accurately noted. In this way, a layer of doped polysilicon is left above the metal barrier in the contact region. Metal may then be patterned over the entire structure to provide a low resistance reliable contact.

Inventors

  • 👤 Jeffrey L. Klein
  • 👤 Stephen S. Poon
  • 👤 Mark S. Swenson
  • 👤 Sudhir K. Madan

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 04:55
CPC Classifications
H; H10; H10P; H10P50/00; H10P50/20; H10P50/26; H10P50/264; H10P50/266; H10P50/267; H10P50/268; H10D; H10D64/00; H10D64/01; H10D64/011; H10D64/0111; H10D64/0113; H10W; H10W20/00; H10W20/01; H10W20/031; H10W20/056; H10W20/057

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 210 words
A method of forming a layered polysilicon contact, comprising the steps of: providing a substrate material with a doped diffusion region in a portion of the substrate material and at a top surface of the substrate material; depositing a layer of electrically insulating material above the substrate material and doped diffusion region; forming a contact fill region with substantially vertical sidewalls by removing a portion of insulating material to expose a portion of a top surface of the doped diffusion region; forming a first layer of a first metal over both the layer of electrically insulating material and the top surface of the doped diffusion region; forming a layer of a metal barrier material over the layer of first metal; depositing a first layer of polysilicon having an impurity added thereto above the layer of metal barrier material; depositing a second layer of polysilicon having substantially less impurity added thereto above the first layer of polysilicon; depositing a third layer of polysilicon having the impurity added thereto above the second layer of polysilicon; etching away the second and third layers of polysilicon and maintaining the first layer of polysilicon; and forming a second layer of a second metal above the first layer of polysilicon substantially above the contact fill region.
Claim 2
Independent Claim 210 words
A method of forming a layered polysilicon contact, comprising the steps of: providing a substrate material with a doped diffusion region in a portion of the substrate material and at a top surface of the substrate material; depositing a layer of electrically insulating material above the substrate material and doped diffusion region; forming a contact fill region with substantially vertical sidewalls by removing a portion of insulating material to expose a portion of a top surface of the doped diffusion region; forming a first layer of a first metal over both the layer of electrically insulating material and the top surface of the doped diffusion region; forming a layer of a metal barrier material over the layer of first metal; depositing a first layer of polysilicon having an impurity added thereto above the layer of metal barrier material; depositing a second layer of polysilicon having substantially less impurity added thereto above the first layer of polysilicon; depositing a third layer of polysilicon having the impurity added thereto above the second layer of polysilicon; etching away the second and third layers of polysilicon and maintaining the first layer of polysilicon; and forming a second layer of a second metal above the first layer of polysilicon substantially above the contact fill region.
Claim 3
Dependent Claim 41 words
The method of claim 1 wherein the first layer of polysilicon is maintained after etching away the second and third layers of polysilicon by monitoring photoemissions provided from a chemical reaction used to etch the second and third layers of polysilicon.
Claim 4
Dependent Claim 13 words
The method of claim 1 wherein the metal barrier material is titanium nitride.
Claim 5
Dependent Claim 28 words
The method of claim 1 wherein the layer of electrically insulating material is dual layer comprising a layer of borophosphosilicate glass formed over a layer of undoped oxide.
Claim 6
Dependent Claim 26 words
The method of claim 1 wherein the third layer of polysilicon is deposited to a substantially larger thickness than the first and second layers of polysilicon.
Claim 7
Dependent Claim 16 words
The method of claim 1 wherein the first and second metals are the same metal material.
Claim 8
Independent Claim 237 words
A method of forming a polysilicon contact, comprising the steps of: providing a silicon substrate having a diffusion region contained therein and extending along a portion of a top surface of the substrate, said contact to provide electrical connectivity to the diffusion region; depositing a layer of electrically insulating material above the substrate and diffusion region; forming a contact fill region by removing a portion of the layer of electrically insulating material to expose a portion of a top surface of the substrate; depositing a layer of a first metal over both the electrically insulating material and the exposed top surface of the substrate; forming a layer of titanium nitride over the layer of metal; depositing polysilion above the layer of titanium nitride to completely fill said contact fill region, said polysilicon having at least two zones of differing impurity concentrations; selectively etching by a predetermined chemical reaction each of the at least two zones of polysilicon until etching to an endpoint indicating a zone of polysilicon immediately above the layer of titanium nitride adjacent the contact fill region, said endpoint being detected by monitoring a ratio of a product produced from the predetermined reaction and a reactant used in the predetermined reaction and detecting a variation in the ratio when said endpoint is reached; and forming a layer of a second metal above the polysilicon which is not etched and substantially above the contact fill region.
Claim 9
Independent Claim 237 words
A method of forming a polysilicon contact, comprising the steps of: providing a silicon substrate having a diffusion region contained therein and extending along a portion of a top surface of the substrate, said contact to provide electrical connectivity to the diffusion region; depositing a layer of electrically insulating material above the substrate and diffusion region; forming a contact fill region by removing a portion of the layer of electrically insulating material to expose a portion of a top surface of the substrate; depositing a layer of a first metal over both the electrically insulating material and the exposed top surface of the substrate; forming a layer of titanium nitride over the layer of metal; depositing polysilion above the layer of titanium nitride to completely fill said contact fill region, said polysilicon having at least two zones of differing impurity concentrations; selectively etching by a predetermined chemical reaction each of the at least two zones of polysilicon until etching to an endpoint indicating a zone of polysilicon immediately above the layer of titanium nitride adjacent the contact fill region, said endpoint being detected by monitoring a ratio of a product produced from the predetermined reaction and a reactant used in the predetermined reaction and detecting a variation in the ratio when said endpoint is reached; and forming a layer of a second metal above the polysilicon which is not etched and substantially above the contact fill region.
Claim 10
Dependent Claim 25 words
The method of claim 7 wherein the layer of electrically insulating material is a dual layer of borophosphosilicate glass over a layer of undoped oxide.
Claim 11
Dependent Claim 23 words
The method of claim 7 wherein the ratio is a ratio of a chemical compound containing fluorine and a chemical compound containing chlorine.
Claim 12
Dependent Claim 16 words
The method of claim 7 wherein the first and second metals are the same metal material.

References Cited (Backward Citations)

US4146902A Cited
US4364166A Cited
US4424578A Cited
JPS61156837A Cited
JPS61198764A Cited
JPS61216322A Cited
JPS61222125A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-05-08 1992-11-07 1993-05-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-05-08 1996-11-07 1997-05-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-05-08 2000-11-07 2001-05-09 $7700.00 Window Closed / Lapsed

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