US4828790A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Inhibition of deposition of radioactive substances on nuclear power plant components
Assignee: Hitachi Ltd
•
Filing: 1987-11-06
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Granted: 1989-05-09
•
Expires: 2007-11-06
Abstract
Abstract A nuclear power plant wherein surfaces of components contacting with nuclear reactor cooling water containing radioactive substances are coated with an oxide film, preferably being charged positively and/or containing chromium in an amount of 12% by weight or more, is prevented effectively from the deposition of radioactive substances thereon.
Inventors
- 👤 Takashi Honda
- 👤 Yasumasa Furutani
- 👤 Kenya Ohashi
- 👤 Eiji Kashimura
- 👤 Akira Minato
- 👤 Katsumi Ohsumi
- 👤 Hisao Itou
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 15:52
CPC Classifications
G; G21; G21F; G21F9/00; G21F9/001; G21F9/002; G21F9/004
Claims Analysis
Total Claims: 43
Claim 1
Independent Claim
184 words
A process for inhibiting deposition of radioactive substances on nuclear power plant components which comprises forming a positively charged oxide film on surface of components contacting with nuclear reactor cooling water containing radioactive substances by treating the surface of components with a solution containing anions and polyvalent metal cations, the anions having a lower valence number than the cations at a time of forming an oxide film or after the formation of the oxide film, wherein the polyvalent metal cations are at least one member selected from the group consisting of Al 3+ , Fe 3+ , Ba 2+ , Ca 2+ , Co 2+ , Mg 2+ , Ni 2+ , Pb 2+ , Zn 2+ and Cu 2+ , and the anions are at least one member selected from the group consisting of HCO 3 - , H 2 PO 4 - , MnO 4 - , NO 2 - , NO 3 - , OH - , HCOO - , CH 3 COO - , MnO 4 2- , HPO 4 2- , SO 4 2- and WO 4 2- .
Claim 2
Dependent Claim
184 words
A process for inhibiting deposition of radioactive substances on nuclear power plant components which comprises forming a positively charged oxide film on surface of components contacting with nuclear reactor cooling water containing radioactive substances by treating the surface of components with a solution containing anions and polyvalent metal cations, the anions having a lower valence number than the cations at a time of forming an oxide film or after the formation of the oxide film, wherein the polyvalent metal cations are at least one member selected from the group consisting of Al 3+ , Fe 3+ , Ba 2+ , Ca 2+ , Co 2+ , Mg 2+ , Ni 2+ , Pb 2+ , Zn 2+ and Cu 2+ , and the anions are at least one member selected from the group consisting of HCO 3 - , H 2 PO 4 - , MnO 4 - , NO 2 - , NO 3 - , OH - , HCOO - , CH 3 COO - , MnO 4 2- , HPO 4 2- , SO 4 2- and WO 4 2- .
Claim 3
Dependent Claim
25 words
A process according to claim 1, wherein the solution containing the polyvalent metal cations and the anions has a temperature of 150° to 300° C.
Claim 4
Dependent Claim
22 words
A process according to claim 1, wherein the polyvalent metal cations are used in a concentration of 3 ppb to 1000 ppm.
Claim 5
Dependent Claim
92 words
A process according to claim 1, wherein said polyvalent metal cations are selected from the group consisting of Al 3+ , Fe 3+ , Ba 2+ , Ca 2+ , Co 2+ , Mg 2+ , Ni 2+ , Pb 2+ , Zn 2+ and Cu 2+ , and wherein the anions are selected from the group consisting of HCO 3 - , H 2 PO 4 - , MnO 4 - , NO 2 - , NO 3 - , OH - , HCOO - and CH 3 COO - .
Claim 6
Dependent Claim
51 words
A process according to claim 1, wherein said polyvalent metal cations are selected from the group consisting of Al 3+ and Fe 3+ , and wherein the anions are selected from the group consisting of MoO 4 2- , HPO 4 2- , SO 4 2- and WO 4 2- .
Claim 7
Dependent Claim
24 words
A process according to claim 3, wherein the positively charged iron oxide film is formed to have a thickness of at least 300 Å.
Claim 8
Dependent Claim
28 words
A process according to claim 1, wherein the components are formed of materials selected from the group consisting of stainless steel; carbon steel; cobalt-chromium-tungsten alloy; and nickel-chromium-iron alloy.
Claim 9
Dependent Claim
14 words
A process according to claim 7, wherein the components are formed of carbon steel.
Claim 10
Dependent Claim
24 words
A process according to claim 7, wherein the components are formed of materials selected from the group consisting of cobalt-chromium-tungsten alloy and nickel-chromium-iron alloy.
Claim 11
Dependent Claim
29 words
A process according to claim 1, wherein said treating is performed by pouring said solution into said cooling water, whereby solution-containing cooling water treats the surfaces of the components.
Claim 12
Dependent Claim
16 words
A process according to claim 10, wherein said surfaces of components are made of stainless steel.
Claim 13
Dependent Claim
185 words
A process for inhibiting deposition of radioactive substances on nuclear power plant components which comprises forming a positively charged iron oxide film containing metallic elements giving polyvalent metal cations and chromium on surfaces of components contacting with nuclear reactor cooling water containing radioactive substances, the positively charged iron oxide film being formed by contacting said surfaces of components with a solution containing said polyvalent metal cations and anions having a lower valence number than the cations, wherein the polyvalent metal cations are at least one member selected from the group consisting of Al 3+ , Fe 3+ , Ba 2+ , Ca 2+ , Co 2+ , Mg 2+ , Ni 2+ , Pb 2+ , Zn 2+ and Cu 2+ , and the anions are at least one member selected from the group consisting of HCO 3 - , H 2 PO 4 - , MnO 4 - , NO 2 - , NO 3 - , OH - , HCOO - , CH 3 COO - , MnO 4 2- , HPO 4 2- , SO 4 2- and WO 4 2- .
Claim 14
Dependent Claim
185 words
A process for inhibiting deposition of radioactive substances on nuclear power plant components which comprises forming a positively charged iron oxide film containing metallic elements giving polyvalent metal cations and chromium on surfaces of components contacting with nuclear reactor cooling water containing radioactive substances, the positively charged iron oxide film being formed by contacting said surfaces of components with a solution containing said polyvalent metal cations and anions having a lower valence number than the cations, wherein the polyvalent metal cations are at least one member selected from the group consisting of Al 3+ , Fe 3+ , Ba 2+ , Ca 2+ , Co 2+ , Mg 2+ , Ni 2+ , Pb 2+ , Zn 2+ and Cu 2+ , and the anions are at least one member selected from the group consisting of HCO 3 - , H 2 PO 4 - , MnO 4 - , NO 2 - , NO 3 - , OH - , HCOO - , CH 3 COO - , MnO 4 2- , HPO 4 2- , SO 4 2- and WO 4 2- .
Claim 15
Dependent Claim
21 words
A process according to claim 12, wherein the chromium content in the iron oxide film is 12% by weight or more.
Claim 16
Dependent Claim
22 words
A process according to claim 12, wherein the polyvalent metal cations are used in a concentration of 3 ppb to 1000 ppm.
Claim 17
Dependent Claim
14 words
A process according to claim 14, wherein the components are made of stainless steel.
Claim 18
Dependent Claim
17 words
A process according to claim 15, wherein the solution has a temperature of 150° to 300° C.
Claim 19
Dependent Claim
120 words
A process for inhibiting deposition of radioactive substances on nuclear power plant components made of an iron series material and contacting with reactor cooling water containing radioactive substances, which comprises treating surfaces of components made of a chromium-containing iron series material with heated water or heated steam to form an oxide film containing chromium in an amount of 12% by weight or more. formed thereon, prior to operation of the plant to provide nuclear heating, the oxide film having a chromium content of at least 12% by weight, wherein said oxide film is a positively charged oxide film, formed by contacting said surfaces with a solution containing polyvalent metal cations and anions having a lower valence number than the cations.
Claim 20
Dependent Claim
120 words
A process for inhibiting deposition of radioactive substances on nuclear power plant components made of an iron series material and contacting with reactor cooling water containing radioactive substances, which comprises treating surfaces of components made of a chromium-containing iron series material with heated water or heated steam to form an oxide film containing chromium in an amount of 12% by weight or more. formed thereon, prior to operation of the plant to provide nuclear heating, the oxide film having a chromium content of at least 12% by weight, wherein said oxide film is a positively charged oxide film, formed by contacting said surfaces with a solution containing polyvalent metal cations and anions having a lower valence number than the cations.
Claim 21
Dependent Claim
73 words
A process according to claim 17, further comprising the step of treating said surfaces of components with a solution containing polyvalent metal cations and anions having a lower valence number than the cations so as to form a positively charged iron oxide film on said surfaces of components, whereby said surfaces have a positively charged iron oxide film and an oxide film containing chromium in an amount of 12% by weight or more.
Claim 22
Dependent Claim
112 words
A process according to claim 18, wherein the polyvalent metal cations are at least one member selected from the group consisting of Al 3+ , Fe 3+ , Ba 2+ , Ca 2+ , Mg 2+ , Ni 2+ , Pb 2+ , Zn 2+ and Cu 2+ , and the anions are at least one member selected from the group consisting of HCO 3 - , H 2 PO 4 - , MnO 4 - , NO 2 - , NO 3 - , OH - , HCOO - , CH 3 COO - , MnO 4 2- , HPo 4 2- , SO 4 2- and WO 4 2- .
Claim 23
Dependent Claim
22 words
A process according to claim 19, wherein the polyvalent metal cations are used in a concentration of 3 ppb to 1000 ppm.
Claim 24
Dependent Claim
18 words
A process according to claim 20, wherein the heated water or the heated steam contains a reducing agent.
Claim 25
Dependent Claim
18 words
A process according to claim 17, wherein the heated water has a temperature of 150° to 300° C.
Claim 26
Dependent Claim
18 words
A process according to claim 17, wherein the heated steam has a temperature of 150° to 1000° C.
Claim 27
Dependent Claim
34 words
A process according to claim 17, wherein said surfaces are a coating of chromium or chromium-containing iron series material, said coating being a chromium plated film, chromizing treated film or chromium vapor deposited film.
Claim 28
Dependent Claim
29 words
A process according to claim 17, wherein the components are formed of materials selected from the group consisting of stainless steel; carbon steel; and cobalt-chromium-tungsten alloy; and nickel-chromium-iron alloy.
Claim 29
Dependent Claim
14 words
A process according to claim 25, wherein the components are formed of carbon steel.
Claim 30
Dependent Claim
24 words
A process according to claim 25, wherein the components are formed of materials selected from the group consisting of cobalt-chromium-tungsten alloy and nickel-chromium-iron alloy.
Claim 31
Dependent Claim
15 words
A process according to claim 21, wherein the reducing agent is also a chelating agent.
Claim 32
Dependent Claim
24 words
A process according to claim 21, wherein the reducing agent is a Ni salt of ethylenediamine-tetraacetic acid or a nickel salt of nitrilotriacetic acid.
Claim 33
Dependent Claim
85 words
In a nuclear power plant comprising a reactor, a turbine, a condenser, a condensed water demineralizer, a supplying water heater, a demineralizer for a reactor cleaning system, and a reactor re-circulation piping system, the improvement wherein a positively charged iron oxide film is formed on surfaces which contact with nuclear reactor cooling water in said plant, the positively charged iron oxide film being formed by contacting said surfaces with a solution containing polyvalent metal cations and anions having a lower valence number than the cations.
Claim 34
Dependent Claim
85 words
In a nuclear power plant comprising a reactor, a turbine, a condenser, a condensed water demineralizer, a supplying water heater, a demineralizer for a reactor cleaning system, and a reactor re-circulation piping system, the improvement wherein a positively charged iron oxide film is formed on surfaces which contact with nuclear reactor cooling water in said plant, the positively charged iron oxide film being formed by contacting said surfaces with a solution containing polyvalent metal cations and anions having a lower valence number than the cations.
Claim 35
Dependent Claim
114 words
A nuclear power plant according to claim 30, wherein the polyvalent metal cations are at least one member selected from the group consisting of Al 3+ , Fe 3+ , Ba 2+ , Co 2+ , Mg 2+ , Ni 2+ , Pb 2+ , Zn 2+ and Cu 2+ , and the anions are at least one member selected from the group consisting of HCO 3 - , H 2 PO 4 - , MnO 4 - , NO 2 - , NO 3 - , OH - , HCOO - , CH 3 COO - , MnO 4 2- , HPO 4 2- , SO 4 2- and WO 4 2- .
Claim 36
Dependent Claim
101 words
In a nuclear power plant comprising a reactor, a turbine, a condenser, a condensed water demineralizer, a supplying water heater, a demineralizer for a reactor cleaning system, and a reactor re-circulation piping system, the improvement wherein a positively charged iron oxide film is formed on surfaces which contact with nuclear reactor cooling water in said plant, the positively charged iron oxide film being formed by contacting said surfaces with a solution containing polyvalent metal cations and anions having a lower valence number than the cations, after the construction of said plant and prior to the operation thereof to provide nuclear heating.
Claim 37
Dependent Claim
101 words
In a nuclear power plant comprising a reactor, a turbine, a condenser, a condensed water demineralizer, a supplying water heater, a demineralizer for a reactor cleaning system, and a reactor re-circulation piping system, the improvement wherein a positively charged iron oxide film is formed on surfaces which contact with nuclear reactor cooling water in said plant, the positively charged iron oxide film being formed by contacting said surfaces with a solution containing polyvalent metal cations and anions having a lower valence number than the cations, after the construction of said plant and prior to the operation thereof to provide nuclear heating.
Claim 38
Dependent Claim
117 words
A nuclear power plant according to claim 32, wherein the polyvalent metal cations are at least one member selected from the group consisting of Al 3+ , Fe 3+ , Ba 2+ , Ca 2+ , Co 2+ , Mg 2+ , Ni 2+ , Pb 2+ , Zn 2+ and Cu 2+ , and the anions are at least one member selected from the group consisting of HCO 3 - , H 2 PO 4 - , MnO 4 - , NO 2 - , NO 3 - , OH - , HCOO - , CH 3 COO - , MnO 4 2- , HPO 4 2- , SO 4 2- and WO 4 2- .
Claim 39
Dependent Claim
92 words
In a nuclear power plant comprising a reactor, a turbine, a condenser, a condensed water demineralizer, a supplying water heater, a demineralizer for a reactor cleaning system, and a reactor re-circulation piping system, the improvement wherein a positively charged iron oxide film is formed on surfaces which contact with nuclear reactor cooling water contaminated with radioactive substances after the operation of said plant, the positively charged iron oxide film being formed by contacting said surfaces with a solution containing polyvalent metal cations and anions having a lower valence number than the cations.
Claim 40
Dependent Claim
92 words
In a nuclear power plant comprising a reactor, a turbine, a condenser, a condensed water demineralizer, a supplying water heater, a demineralizer for a reactor cleaning system, and a reactor re-circulation piping system, the improvement wherein a positively charged iron oxide film is formed on surfaces which contact with nuclear reactor cooling water contaminated with radioactive substances after the operation of said plant, the positively charged iron oxide film being formed by contacting said surfaces with a solution containing polyvalent metal cations and anions having a lower valence number than the cations.
Claim 41
Dependent Claim
117 words
A nuclear power plant according to claim 34, wherein the polyvalent metal cations are at least one member selected from the group consisting of Al 3+ , Fe 3+ , Ba 2+ , Ca 2+ , Co 2+ , Mg 2+ , Ni 2+ , Pb 2+ , Zn 2+ and Cu 2+ , and the anions are at least one member selected from the group consisting of HCO 3 - , H 2 PO 4 - , MnO 4 - , NO 2 - , NO 3 - , OH - , HCOO - , CH 3 COO - , MnO 4 2- , HPO 4 2- , SO 4 2- and WO 4 2- .
Claim 42
Dependent Claim
108 words
In a nuclear power plant comprising a reactor, a turbine, a condenser, a condensed water demineralizer, a supplying water heater, a demineralizer for a reactor cleaning system, and a reactor re-circulation piping system, the improvement wherein surfaces of the plant which contact with nuclear reactor cooling water have an oxide film formed thereon, prior to operation of the plant to provide nuclear heating, the oxide film having a chromium content of at least 12% by weight, wherein said oxide film is a positively charged oxide film, formed by contacting said surfaces with a solution containing polyvalent metal cations and anions having a lower valence number than the cations.
Claim 43
Dependent Claim
108 words
In a nuclear power plant comprising a reactor, a turbine, a condenser, a condensed water demineralizer, a supplying water heater, a demineralizer for a reactor cleaning system, and a reactor re-circulation piping system, the improvement wherein surfaces of the plant which contact with nuclear reactor cooling water have an oxide film formed thereon, prior to operation of the plant to provide nuclear heating, the oxide film having a chromium content of at least 12% by weight, wherein said oxide film is a positively charged oxide film, formed by contacting said surfaces with a solution containing polyvalent metal cations and anions having a lower valence number than the cations.
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