Patent US4828749A successfully refreshed from Google Patents.
US4828749A
Expired / Lapsed
US
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Multilayer detergent tablets for dishwashing machines
Assignee: Henkel AG and Co KGaA
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Filing: 1986-11-17
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Granted: 1989-05-09
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Expires: 2006-11-17
Abstract
Abstract A multilayer detergent tablet for dishwashing machines based on alkali metal metasilicates, pentaalkali metal triphosphates, active chlorine compound, and surfactant. The tablet comprises a first cold water-soluble layer of alkali metal metasilicate nonahydrate, pentaalkali metal triphosphate, and a low-foaming nonionic surfactant; and a second layer which dissolves rapidly at increasing water temperatures comprising alkali metal metasilicate, pentaalkali metal triphosphate, and an active chlorine compound.
Inventors
- 👤 Hans Kruse
- 👤 Jochen Jacobs
- 👤 Theodor Altenschoepfer
- 👤 Peter Jeschke
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 13:33
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/395; C11D3/3955; C11D17/00; C11D17/0047; C11D17/0065; C11D17/0073; C11D17/0078; C11D3/02; C11D3/04; C11D3/08
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
178 words
A multilayer detergent tablet for dishwashing machines based on alkaline components selected from the group consisting of alkali metal metasilicates and pentaalkali metal triphosphates; an active chlorine compound; and surfactant; said tablet comprising a first cold water-soluble layer of alkali metal metasilicate nonahydrate and pentaalakli metal triphosphate containing from about 7 to about 22.4% by weight water of crystallization in a weight ratio of from 0.35:1 to 1:1, based on anhydrous compounds, and from about 1 to about 5% by weight of a low-foaming nonionic surfactant; and a second layer which dissolves rapidly at increasing water temperaures comprising from about 88 to about 98% by weight of anhydrous alkali metal metasilicate and pentaalkali metal triphosphate in a weight ratio of from about 2:1 to 1:2, based on anhydrous compounds, and from about 0.5 to about 5% by weight of an active chlorine compound, said first layer having a specific gravity of from about 1.2 to about 1.4 g/cm 3 , and said second layer having a specific gravity of from about 1.4 to about 1.7 g/cm 3 .
Claim 2
Dependent Claim
178 words
A multilayer detergent tablet for dishwashing machines based on alkaline components selected from the group consisting of alkali metal metasilicates and pentaalkali metal triphosphates; an active chlorine compound; and surfactant; said tablet comprising a first cold water-soluble layer of alkali metal metasilicate nonahydrate and pentaalakli metal triphosphate containing from about 7 to about 22.4% by weight water of crystallization in a weight ratio of from 0.35:1 to 1:1, based on anhydrous compounds, and from about 1 to about 5% by weight of a low-foaming nonionic surfactant; and a second layer which dissolves rapidly at increasing water temperaures comprising from about 88 to about 98% by weight of anhydrous alkali metal metasilicate and pentaalkali metal triphosphate in a weight ratio of from about 2:1 to 1:2, based on anhydrous compounds, and from about 0.5 to about 5% by weight of an active chlorine compound, said first layer having a specific gravity of from about 1.2 to about 1.4 g/cm 3 , and said second layer having a specific gravity of from about 1.4 to about 1.7 g/cm 3 .
Claim 3
Dependent Claim
49 words
A mulilayer detergent tablet in accordance with claim 1 wherein said tablet contains as tabletting aids, from about 0.5 to about 2.5% by weight of calcium hydrogen phosphate dihydrate and from about 1 to about 5% by weight of anhydrous sodium acetate, based on the weight of said tablet.
Claim 4
Dependent Claim
15 words
A multilayer detergent tablet in accordance with claim 1 wherein said first layer is colored.
Claim 5
Dependent Claim
17 words
A multilayer detergent tablet in accordance with claim 1 wherein said alkali metal metasilicate nonahydrate is colored.
Claim 6
Dependent Claim
28 words
A multilayer detergent tablet in accordance with claim 1 wherein said alkali metal metasilicate present in said second layer is a mixture of anhydrous metasilicate and metasilicate nonahydrate.
Claim 7
Dependent Claim
21 words
A multilayer detergent tablet in accordance with claim 1 wherein said pentaalkali metal triphosphate present in said second layer is anhydrous.
Claim 8
Dependent Claim
26 words
A multilayer detergent tablet in accordance with claim 1 wherein said tablet has a specific gravity of from about 1.35 to about 1.55 g/cm 3 .
Claim 9
Dependent Claim
184 words
A dishwashing process comprising adding to a dishwashing machine a multilayer detergent tablet based on alkaline components selected from the group consisting of alkali metal metasilicates and pentaalkali metal triphosphates; an active chlorine compound; and surfactant; said tablet comprising a first cold water-soluble layer of alkali metal metasilicate nonahydrate and pentraalkali metal triphosphate containing from about 7 to about 22.4% by weight water of crystallization in a weight ratio of from 0.35:1 to 1:1, based on anhydrous compounds, and from about 1 to about 5% by weight of a low-foaming nonionic surfactant; and a second layer which dissolves rapidly at increasing water temperatures comprising from about 88 to about 98% by weight of anhydrous alkali metal metasilicate and pentaalkali metal triphosphate in a weight ratio of from about 2:1 to 1:2, based on anhydrous compounds, and from about 0.5 to about 5% by weight of an active chlorine compound, said first layer having a specific gravity of from about 1.2 to about 1.4 g/cm 3 , and said second layer having a specific gravity of from about 1.4 to about 1.7 g/cm 3 .
Claim 10
Dependent Claim
184 words
A dishwashing process comprising adding to a dishwashing machine a multilayer detergent tablet based on alkaline components selected from the group consisting of alkali metal metasilicates and pentaalkali metal triphosphates; an active chlorine compound; and surfactant; said tablet comprising a first cold water-soluble layer of alkali metal metasilicate nonahydrate and pentraalkali metal triphosphate containing from about 7 to about 22.4% by weight water of crystallization in a weight ratio of from 0.35:1 to 1:1, based on anhydrous compounds, and from about 1 to about 5% by weight of a low-foaming nonionic surfactant; and a second layer which dissolves rapidly at increasing water temperatures comprising from about 88 to about 98% by weight of anhydrous alkali metal metasilicate and pentaalkali metal triphosphate in a weight ratio of from about 2:1 to 1:2, based on anhydrous compounds, and from about 0.5 to about 5% by weight of an active chlorine compound, said first layer having a specific gravity of from about 1.2 to about 1.4 g/cm 3 , and said second layer having a specific gravity of from about 1.4 to about 1.7 g/cm 3 .
Claim 11
Dependent Claim
47 words
A process in accordance with claim 8 wherein said tablet contains as tabletting aids, from about 0.5 to about 2.5% by weight of calcium hydrogen phosphate dihydrate and from about 1 to about 5% by weight of anhydrous sodium acetate, based on the weight of said tablet.
Claim 12
Dependent Claim
13 words
A process in accordance with claim 8 wherein said first layer is colored.
Claim 13
Dependent Claim
26 words
A process in accordance with claim 8 wherein said alkali metal metasilicate present in said second layer is a mixture of anhydrous metasilicate and metasilicate nonahydrate.
Claim 14
Dependent Claim
19 words
A process in accordance with claim 8 wherein said pentaalkali metal triphosphate present in said second layer is anhydrous.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1992-05-08 | 1992-11-07 | 1993-05-09 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-05-08 | 1996-11-07 | 1997-05-09 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-05-08 | 2000-11-07 | 2001-05-09 | $7700.00 | Window Closed / Lapsed |