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US4828749A Expired / Lapsed US ⏱️ 0.0 years remaining

Multilayer detergent tablets for dishwashing machines

Assignee: Henkel AG and Co KGaA
•
Filing: 1986-11-17
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Granted: 1989-05-09
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Expires: 2006-11-17
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Abstract

Abstract A multilayer detergent tablet for dishwashing machines based on alkali metal metasilicates, pentaalkali metal triphosphates, active chlorine compound, and surfactant. The tablet comprises a first cold water-soluble layer of alkali metal metasilicate nonahydrate, pentaalkali metal triphosphate, and a low-foaming nonionic surfactant; and a second layer which dissolves rapidly at increasing water temperatures comprising alkali metal metasilicate, pentaalkali metal triphosphate, and an active chlorine compound.

Inventors

  • 👤 Hans Kruse
  • 👤 Jochen Jacobs
  • 👤 Theodor Altenschoepfer
  • 👤 Peter Jeschke

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 13:33
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/395; C11D3/3955; C11D17/00; C11D17/0047; C11D17/0065; C11D17/0073; C11D17/0078; C11D3/02; C11D3/04; C11D3/08

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 178 words
A multilayer detergent tablet for dishwashing machines based on alkaline components selected from the group consisting of alkali metal metasilicates and pentaalkali metal triphosphates; an active chlorine compound; and surfactant; said tablet comprising a first cold water-soluble layer of alkali metal metasilicate nonahydrate and pentaalakli metal triphosphate containing from about 7 to about 22.4% by weight water of crystallization in a weight ratio of from 0.35:1 to 1:1, based on anhydrous compounds, and from about 1 to about 5% by weight of a low-foaming nonionic surfactant; and a second layer which dissolves rapidly at increasing water temperaures comprising from about 88 to about 98% by weight of anhydrous alkali metal metasilicate and pentaalkali metal triphosphate in a weight ratio of from about 2:1 to 1:2, based on anhydrous compounds, and from about 0.5 to about 5% by weight of an active chlorine compound, said first layer having a specific gravity of from about 1.2 to about 1.4 g/cm 3 , and said second layer having a specific gravity of from about 1.4 to about 1.7 g/cm 3 .
Claim 2
Dependent Claim 178 words
A multilayer detergent tablet for dishwashing machines based on alkaline components selected from the group consisting of alkali metal metasilicates and pentaalkali metal triphosphates; an active chlorine compound; and surfactant; said tablet comprising a first cold water-soluble layer of alkali metal metasilicate nonahydrate and pentaalakli metal triphosphate containing from about 7 to about 22.4% by weight water of crystallization in a weight ratio of from 0.35:1 to 1:1, based on anhydrous compounds, and from about 1 to about 5% by weight of a low-foaming nonionic surfactant; and a second layer which dissolves rapidly at increasing water temperaures comprising from about 88 to about 98% by weight of anhydrous alkali metal metasilicate and pentaalkali metal triphosphate in a weight ratio of from about 2:1 to 1:2, based on anhydrous compounds, and from about 0.5 to about 5% by weight of an active chlorine compound, said first layer having a specific gravity of from about 1.2 to about 1.4 g/cm 3 , and said second layer having a specific gravity of from about 1.4 to about 1.7 g/cm 3 .
Claim 3
Dependent Claim 49 words
A mulilayer detergent tablet in accordance with claim 1 wherein said tablet contains as tabletting aids, from about 0.5 to about 2.5% by weight of calcium hydrogen phosphate dihydrate and from about 1 to about 5% by weight of anhydrous sodium acetate, based on the weight of said tablet.
Claim 4
Dependent Claim 15 words
A multilayer detergent tablet in accordance with claim 1 wherein said first layer is colored.
Claim 5
Dependent Claim 17 words
A multilayer detergent tablet in accordance with claim 1 wherein said alkali metal metasilicate nonahydrate is colored.
Claim 6
Dependent Claim 28 words
A multilayer detergent tablet in accordance with claim 1 wherein said alkali metal metasilicate present in said second layer is a mixture of anhydrous metasilicate and metasilicate nonahydrate.
Claim 7
Dependent Claim 21 words
A multilayer detergent tablet in accordance with claim 1 wherein said pentaalkali metal triphosphate present in said second layer is anhydrous.
Claim 8
Dependent Claim 26 words
A multilayer detergent tablet in accordance with claim 1 wherein said tablet has a specific gravity of from about 1.35 to about 1.55 g/cm 3 .
Claim 9
Dependent Claim 184 words
A dishwashing process comprising adding to a dishwashing machine a multilayer detergent tablet based on alkaline components selected from the group consisting of alkali metal metasilicates and pentaalkali metal triphosphates; an active chlorine compound; and surfactant; said tablet comprising a first cold water-soluble layer of alkali metal metasilicate nonahydrate and pentraalkali metal triphosphate containing from about 7 to about 22.4% by weight water of crystallization in a weight ratio of from 0.35:1 to 1:1, based on anhydrous compounds, and from about 1 to about 5% by weight of a low-foaming nonionic surfactant; and a second layer which dissolves rapidly at increasing water temperatures comprising from about 88 to about 98% by weight of anhydrous alkali metal metasilicate and pentaalkali metal triphosphate in a weight ratio of from about 2:1 to 1:2, based on anhydrous compounds, and from about 0.5 to about 5% by weight of an active chlorine compound, said first layer having a specific gravity of from about 1.2 to about 1.4 g/cm 3 , and said second layer having a specific gravity of from about 1.4 to about 1.7 g/cm 3 .
Claim 10
Dependent Claim 184 words
A dishwashing process comprising adding to a dishwashing machine a multilayer detergent tablet based on alkaline components selected from the group consisting of alkali metal metasilicates and pentaalkali metal triphosphates; an active chlorine compound; and surfactant; said tablet comprising a first cold water-soluble layer of alkali metal metasilicate nonahydrate and pentraalkali metal triphosphate containing from about 7 to about 22.4% by weight water of crystallization in a weight ratio of from 0.35:1 to 1:1, based on anhydrous compounds, and from about 1 to about 5% by weight of a low-foaming nonionic surfactant; and a second layer which dissolves rapidly at increasing water temperatures comprising from about 88 to about 98% by weight of anhydrous alkali metal metasilicate and pentaalkali metal triphosphate in a weight ratio of from about 2:1 to 1:2, based on anhydrous compounds, and from about 0.5 to about 5% by weight of an active chlorine compound, said first layer having a specific gravity of from about 1.2 to about 1.4 g/cm 3 , and said second layer having a specific gravity of from about 1.4 to about 1.7 g/cm 3 .
Claim 11
Dependent Claim 47 words
A process in accordance with claim 8 wherein said tablet contains as tabletting aids, from about 0.5 to about 2.5% by weight of calcium hydrogen phosphate dihydrate and from about 1 to about 5% by weight of anhydrous sodium acetate, based on the weight of said tablet.
Claim 12
Dependent Claim 13 words
A process in accordance with claim 8 wherein said first layer is colored.
Claim 13
Dependent Claim 26 words
A process in accordance with claim 8 wherein said alkali metal metasilicate present in said second layer is a mixture of anhydrous metasilicate and metasilicate nonahydrate.
Claim 14
Dependent Claim 19 words
A process in accordance with claim 8 wherein said pentaalkali metal triphosphate present in said second layer is anhydrous.

References Cited (Backward Citations)

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US3154494A Cited
CH430925A Cited
US3390092A Cited
US4219436A Cited
US4518516A Cited
DE3315950A1 Cited
EP0126963A1 Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-05-08 1992-11-07 1993-05-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-05-08 1996-11-07 1997-05-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-05-08 2000-11-07 2001-05-09 $7700.00 Window Closed / Lapsed

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