Surface modified cemented carbides

Claim 2

A cemented carbide body having a peripheral surface formed by sintering a blended powder mixture comprising at least 70 weight percent tungsten carbide in hexagonal form and a sufficient amount of additional carbides for improving crater resistance, said additional carbides having a B-1 structure and selected from the group consisting of the carbides of titanium, tantalum, columbium, molybdenum, vanadium, chromium, zirconium and hafnium and being less than 15 percent by weight additional carbides, a cobalt metallic binder, and aluminum nitride in an amount sufficient to enhance the surface toughness of the cemented carbide body by promoting binder enrichment and depletion of aluminum nitride and said additional carbides near a peripheral surface, said binder enrichment comprising an increased cobalt metallic binder content near said peripheral surface of at least 1.2 times the average concentration of cobalt metallic binder in said substrate, said depletion of aluminum nitride and said additional carbides near a peripheral surface comprising substantially entirely depleting said aluminum nitride and said additional carbides near said peripheral surface while said average concentration of aluminum nitride and said additional carbides is retained in a remaining portion of said substrate.

Claim 3

A cemented carbide body according to claim 1 wherein said binder is selected from the group consisting of cobalt, nickel, iron and alloys thereof.

Claim 4

A cemented carbide body according to claim 2 wherein said body includes less than twenty percent by weight additional carbides selected from the group consisting of titanium, hafnium, tantalum and niobium.

Claim 5

A cemented carbide body according to claim 3 wherein said binder is cobalt.

Claim 6

A cemented carbide body according to claim 1 wherein said aluminum nitride is present in an amount from an effective amount enhancing surface toughness to an amount less than about 20 percent by volume.

Claim 7

A coated cemented carbide body comprising a substrate having a peripheral surface directly adjacent the exterior coating wherein said substrate is formed by sintering a blended powder mixture comprising at least 70 weight percent tungsten carbide in hexagonal form and a sufficient amount of additional carbides for improving crater resistance, said additional carbides having a B-1 structure and selected from the group consisting of the carbides of titanium, tantalum, columbium, molybdenum, vanadium, chromium, zirconium and hafnium and being less than 15 percent by weight additional carbides, a cobalt metallic binder, and aluminum nitride in an amount sufficient to enhance the surface toughness of the cemented carbide body by promoting binder enrichment and depletion of aluminum nitride and said additional carbides near a peripheral surface, said binder enrichment comprising an increased cobalt metallic binder content near said peripheral surface of at least 1.2 times the average concentration of cobalt metallic binder in said substrate, said depletion of aluminum nitride and said additional carbides near a peripheral surface comprising substantially entirely depleting said aluminum nitride and said additional carbides near said peripheral surface while said average concentration of aluminum nitride and said additional carbides is retained in a remaining portion of said substrate, and a hard refractory metal exterior coating directly adjacent said peripheral surface.

Claim 8

A coated cemented carbide body comprising a substrate having a peripheral surface directly adjacent the exterior coating wherein said substrate is formed by sintering a blended powder mixture comprising at least 70 weight percent tungsten carbide in hexagonal form and a sufficient amount of additional carbides for improving crater resistance, said additional carbides having a B-1 structure and selected from the group consisting of the carbides of titanium, tantalum, columbium, molybdenum, vanadium, chromium, zirconium and hafnium and being less than 15 percent by weight additional carbides, a cobalt metallic binder, and aluminum nitride in an amount sufficient to enhance the surface toughness of the cemented carbide body by promoting binder enrichment and depletion of aluminum nitride and said additional carbides near a peripheral surface, said binder enrichment comprising an increased cobalt metallic binder content near said peripheral surface of at least 1.2 times the average concentration of cobalt metallic binder in said substrate, said depletion of aluminum nitride and said additional carbides near a peripheral surface comprising substantially entirely depleting said aluminum nitride and said additional carbides near said peripheral surface while said average concentration of aluminum nitride and said additional carbides is retained in a remaining portion of said substrate, and a hard refractory metal exterior coating directly adjacent said peripheral surface.