Patent US4826554A successfully refreshed from Google Patents.
US4826554A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Method for making an improved solid polymer electrolyte electrode using a binder
Assignee: Dow Chemical Co
•
Filing: 1985-12-09
•
Granted: 1989-05-02
•
Expires: 2005-12-09
Abstract
Abstract The invention is a method for forming a solid polymer electrolyte structure comprising: (a.) forming a mixture of a binder and a plurality of catalytically active, electrically conductive particles; (b.) forming the mixture into a particle containing film; (c.) contacting the film with a fluorocarbon membrane in its thermoplastic form; (d.) contacting the particle-containing film with an electrically conductive, hydraulically permeable matrix, thereby forming a laminate having a membrane on one side, a matrix on another side and a plurality of catalytically active particles therebetween; and (e.) applying sufficient pressure to the laminate to embed at least a portion of the matrix into the membrane.
Inventors
- 👤 John M. McIntyre
- 👤 Jeffrey D. Birdwell
- 👤 Bruce R. Smith
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 22:32
CPC Classifications
H; H01; H01M; H01M8/00; H01M8/10; H01M8/1004; C; C25; C25B; C25B9/00; C25B9/17; C25B9/19; C25B9/23; H01M8/1016; H01M8/1018; H01M8/102; H01M8/1023; H01M8/1039; Y; Y02; Y02E; Y02E60/00; Y02E60/30; Y02E60/50; Y02P; Y02P70/00; Y02P70/50; Y10; Y10T; Y10T156/00; Y10T156/10; Y10T156/1089; Y10T156/109
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
213 words
A method for forming a solid polymer electrolyte structure consisting essentially of: (a.) forming a mixture of a polytetrafluoroethylene or a fluorocarbon ion exchange active polymer in its thermoplastic form and a plurality of catalytically active, electrically conductive particles having an average particle size diameter of from about 10 to about 30 microns and having a surface area of from about 800 to about 1800 square meters per gram; (b.) forming the mixture into a particle containing film; (c.) contacting the film with a fluorocarbon membrane in its thermoplastic form; (d.) contacting the particle-containing film with an electrically conductive, hydraulically permeable matrix, thereby forming a laminate having a membrane on one side, a matrix on another side and a plurality of catalytically active particles there between, wherein the matrix is selected from the group consisting of carbon cloth, carbon paper, carbon felt, metallic screen, metallic felt and a porous metallic sheet and wherein the matrix has a resistivity of from about 600,000 to about 1375 microohm-centimeters; and (e.) applying sufficient pressure to the laminate to bond at least a portion of the matrix to the membrane thereby forming a membrane having catalytically active particles present on the membrane at a level of less than about 25 milligrams per square centimeter of membrane area.
Claim 2
Independent Claim
213 words
A method for forming a solid polymer electrolyte structure consisting essentially of: (a.) forming a mixture of a polytetrafluoroethylene or a fluorocarbon ion exchange active polymer in its thermoplastic form and a plurality of catalytically active, electrically conductive particles having an average particle size diameter of from about 10 to about 30 microns and having a surface area of from about 800 to about 1800 square meters per gram; (b.) forming the mixture into a particle containing film; (c.) contacting the film with a fluorocarbon membrane in its thermoplastic form; (d.) contacting the particle-containing film with an electrically conductive, hydraulically permeable matrix, thereby forming a laminate having a membrane on one side, a matrix on another side and a plurality of catalytically active particles there between, wherein the matrix is selected from the group consisting of carbon cloth, carbon paper, carbon felt, metallic screen, metallic felt and a porous metallic sheet and wherein the matrix has a resistivity of from about 600,000 to about 1375 microohm-centimeters; and (e.) applying sufficient pressure to the laminate to bond at least a portion of the matrix to the membrane thereby forming a membrane having catalytically active particles present on the membrane at a level of less than about 25 milligrams per square centimeter of membrane area.
Claim 3
Dependent Claim
16 words
The method of claim 1 wherein the particles are applied to both sides of the membrane.
Claim 4
Dependent Claim
11 words
The method of claim 1 wherein the matrix is carbon paper.
Claim 5
Dependent Claim
15 words
The method of claim 1 wherein the matrix has a resistivity of about 1500 microohm-centimeters.
Claim 6
Dependent Claim
53 words
The method of claim 1 wherein the catalytically active particles are selected from the group consisting of platinum group metals, platinum group metal oxides, ruthenium, iridium, rhodium, platinum, palladium, either alone or in combination with an oxide of a film-forming metal, and cobalt oxide either alone or in combination with other metal oxides.
Claim 7
Dependent Claim
31 words
The method of claim 1 wherein the catalytically active particles are present of the membrane at a level of from about 0.4 to about 1.0 milligrams per square centimeter of membrane.
Claim 8
Dependent Claim
20 words
The method of claim 1 wherein the fluorocarbon polymer has an equivalent weight of from about 500 to about 2000.
Claim 9
Dependent Claim
15 words
The method of claim 1 wherein the plurality of electrically conductive particles constitute an anode.
Claim 10
Dependent Claim
15 words
The method of claim 1 wherein the plurality of electrically conductive particles constitute an cathode.
Claim 11
Dependent Claim
39 words
The method of claim 1 wherein a plurality of electrically conductive particles form an anode on one side of the membrane sheet and a plurality of electrically conductive particles form a cathode on the opposite side of the membrane.
Claim 12
Dependent Claim
28 words
The method of claim 1 wherein one electrode is composed of a plurality of electricaly conductive particles and the other electrode is composed of a porous metal plate.
Claim 13
Independent Claim
205 words
A method for forming a solid polymer electrolyte structure consisting essentially of: (a.) forming a mixture of a polytetrafluoroethylene or a fluorocarbon ion exchange active polymer in its thermoplastic form and a plurality of catalytically active, electrically conductive particles having an average particle size diameter of from about 10 to about 30 microns and having a surface area of from about 800 to about 1800 square memters per gram; (b.) forming the mixture into a particle containing film; (c.) contacting the film with a fluorocarbon membrane in its thermoplastic form; (d.) contacting the particle-containing film with an electrically conductive, hydraulically permeable matrix, thereby forming a laminate having a membrane on one side, a matrix on another side and a plurality of catalytically active particles there between, wherein the matrix is carbon cloth and wherein the matrix has a resistivity of from about 600,000 to about 1375 microohm-centimeters and a thickness of from about 0.002 to about 0.025 inches; and (e.) applying sufficient pressure to the laminate to bond at least a portion of the matrix to the membrane thereby forming a membrane having catalytically active particles present on the membrane at a level of less than about 25 milligrams per square centimeter of membrane area.
Claim 14
Independent Claim
205 words
A method for forming a solid polymer electrolyte structure consisting essentially of: (a.) forming a mixture of a polytetrafluoroethylene or a fluorocarbon ion exchange active polymer in its thermoplastic form and a plurality of catalytically active, electrically conductive particles having an average particle size diameter of from about 10 to about 30 microns and having a surface area of from about 800 to about 1800 square memters per gram; (b.) forming the mixture into a particle containing film; (c.) contacting the film with a fluorocarbon membrane in its thermoplastic form; (d.) contacting the particle-containing film with an electrically conductive, hydraulically permeable matrix, thereby forming a laminate having a membrane on one side, a matrix on another side and a plurality of catalytically active particles there between, wherein the matrix is carbon cloth and wherein the matrix has a resistivity of from about 600,000 to about 1375 microohm-centimeters and a thickness of from about 0.002 to about 0.025 inches; and (e.) applying sufficient pressure to the laminate to bond at least a portion of the matrix to the membrane thereby forming a membrane having catalytically active particles present on the membrane at a level of less than about 25 milligrams per square centimeter of membrane area.
References Cited (Backward Citations)
US3134697A
Cited
US4107005A
Cited
US4210501A
Cited
US4191618A
Cited
US4224121A
Cited
US4276146A
Cited
US4465570A
Cited
US4287032A
Cited
US4468311A
Cited
US4319969A
Cited
US4293396A
Cited
US4364815A
Cited
US4315805A
Cited
US4666574A
Cited
US4457822A
Cited
EP0031660B1
Cited
GB2069006A
Cited
US4272353A
Cited
US4311568A
Cited
US4299674A
Cited
US4394229A
Cited
US4360417A
Cited
US4299675A
Cited
US4389297A
Cited
US4341605A
Cited
US4486276A
Cited
EP0066369A1
Cited
US4349428A
Cited
US4421579A
Cited
US4469579A
Cited
US4349418A
Cited
EP0081251A1
Cited
US4545886A
Cited
US4437951A
Cited
US4568941A
Cited
GB2117797A
Cited
US4414092A
Cited
US4610762A
Cited
US4650551A
Cited
US4650711A
Cited
US4654104A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1992-05-01 | 1992-10-31 | 1993-05-02 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-05-01 | 1996-10-31 | 1997-05-02 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-05-01 | 2000-10-31 | 2001-05-02 | $7700.00 | Window Closed / Lapsed |