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US4824764A Expired / Lapsed US ⏱️ 0.0 years remaining

Silver halide photographic material

Assignee: Fujifilm Holdings Corp
•
Filing: 1987-05-20
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Granted: 1989-04-25
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Expires: 2007-05-20
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Abstract

Abstract A silver halide photographic material comprising a support having at least one light-sensitive silver halide emulsion layer on the support, wherein at least one of the emulsion layer and other constituent layers contains at least one compound represented by formula (I) and at least one compound represented by formula (II): ##STR1## wherein R 0 is an organic group having 7 to 30 carbon atoms, A is a substituted or unsubstituted phenylene group, or a substituted or unsubstituted naphthylene group, and X is NH or 0, ##STR2## wherein R 1 is an aliphatic, aromatic or heterocyclic group; R 2 is a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aralkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryl group, a substituted or unsubstituted aryloxy group, or a substituted or unsubstituted amino group; G is a carbonyl group, a sulfonyl group, a sulfoxy group, a phosphoryl group, or an N-substituted or unsubstituted iminomethylene group (NH═C<); R 10 and R 100 are both hydrogen atoms, or one or R 10 and R 100 is a hydrogen atom and the other is a substituted or unsubstituted alkylsulfonyl group, a substituted or unsubstituted arylsulfonyl group, or an acyl group; and G, R 2 , R 100 and the nitrogen atom to which G, R 2 and R 100 are linked may form a partial structure of hydrazone (--N═C<), provided that the compound represented by formula (II) is not the same with the compound represented by formula (I), and the total number of carbon atoms of R 1 and R 2 is 14 to 60.

Inventors

  • 👤 Yoshio Inagaki
  • 👤 Nobuaki Inoue

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 23:39
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/005; G03C1/06; G03C1/30; G03C1/061; Y; Y10; Y10S; Y10S430/00; Y10S430/15

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 316 words
A silver halide photographic material comprising a support having at least one light-sensitive silver halide emulsion layer on the support, wherein at least one of the emulsion layer and other constituent layers contains at least one compound represented by formula (I) and at least one compound represented by formula (II): ##STR14## wherein R 0 is an organic group having 7 to 30 carbon atoms, A is a substituted or unsubstituted phenylene group, or a substituted or unsubstituted naphthylene group, and X is NH or 0, ##STR15## wherein R 1 is an aliphatic, aromatic or heterocyclic group; R 2 is a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aralkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryl group, a substituted or unsubstituted aryloxy group, or a substituted or unsubstituted amino group; G is a carbonyl group, a sulfoxy group, a phosphoryl group, or an N-substituted or unsubstituted iminomethylene group (NH═C<); R 10 and R 100 are both hydrogen, atoms, or one of R 10 and R 100 is a hydrogen atom and the other is a substituted or unsubstituted alkylsulfonyl group, a substituted or unsubstituted arylsulfonyl group, or an acyl group; and G, R 2 , R 100 and the nitrogen atom to which G, R 2 and R 100 are linked may form a partial structure of hydrazone (--N═C<), provided that the compound represented by formula (II) is not the same with the compound represented by formula (I), and the total number of carbon atoms of R 1 and R 2 is 14 to 60 wherein said compound represented by formula (I) and said compound represented by formula (II) are present in an amount sufficient to increase contrast and to prevent decreased sensitivity and gradiation following storage, and reduction in sensitivity and gamma value resulting from processing in a low activity developer of said halide photographic material.
Claim 2
Dependent Claim 316 words
A silver halide photographic material comprising a support having at least one light-sensitive silver halide emulsion layer on the support, wherein at least one of the emulsion layer and other constituent layers contains at least one compound represented by formula (I) and at least one compound represented by formula (II): ##STR14## wherein R 0 is an organic group having 7 to 30 carbon atoms, A is a substituted or unsubstituted phenylene group, or a substituted or unsubstituted naphthylene group, and X is NH or 0, ##STR15## wherein R 1 is an aliphatic, aromatic or heterocyclic group; R 2 is a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aralkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryl group, a substituted or unsubstituted aryloxy group, or a substituted or unsubstituted amino group; G is a carbonyl group, a sulfoxy group, a phosphoryl group, or an N-substituted or unsubstituted iminomethylene group (NH═C<); R 10 and R 100 are both hydrogen, atoms, or one of R 10 and R 100 is a hydrogen atom and the other is a substituted or unsubstituted alkylsulfonyl group, a substituted or unsubstituted arylsulfonyl group, or an acyl group; and G, R 2 , R 100 and the nitrogen atom to which G, R 2 and R 100 are linked may form a partial structure of hydrazone (--N═C<), provided that the compound represented by formula (II) is not the same with the compound represented by formula (I), and the total number of carbon atoms of R 1 and R 2 is 14 to 60 wherein said compound represented by formula (I) and said compound represented by formula (II) are present in an amount sufficient to increase contrast and to prevent decreased sensitivity and gradiation following storage, and reduction in sensitivity and gamma value resulting from processing in a low activity developer of said halide photographic material.
Claim 3
Dependent Claim 112 words
A silver halide photographic material as claimed in claim 1, wherein the compound represented by formula (II) is a compound represented by formula (III): ##STR16## wherein Y is a substituted or unsubstituted phenylene group; L is --CONH--, --SO 2 NH--, --O--, --S--, or ##STR17## (wherein R 5 is hydrogen atom or a substituted or unsubstituted alkyl group); n is 0 or 1; R 3 is an organic group having 7 or more carbon atoms; and R 4 is a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted phenyl group, a substituted or unsubstituted aralkyl group, a substituted or unsubstituted alkoxy group, or a substituted or unsubstituted phenoxy group.
Claim 4
Dependent Claim 64 words
A silver halide photographic material as claimed in claim 1, wherein an amount of the compound represented by formula (I) is 1×10 -6 to 1×10 -2 mol per mol of silver of the silver halide photographic material, and an amount of the compound represented by formula (II) is 1×10 -5 to 1×10 -1 mol per mol of silver of the silver halide photographic material.
Claim 5
Dependent Claim 37 words
A silver halide photographic material as claimed in claim 2, wherein an amount of the compound represented by formula (III) is 1×10 -5 to 1×10 -1 mol per mol of silver of the silver halide photographic material.
Claim 6
Dependent Claim 32 words
A silver halide photographic material as claimed in claim 1, wherein a molar ratio of the compound represented by formula (I) to the compound represented by formula (II) is 1/20 to 10/1.
Claim 7
Dependent Claim 24 words
A silver halide photographic material as in claim 2, wherein when R 5 is a hydrogen atom, R 4 is not a hydrogen atom.

References Cited (Backward Citations)

US4224401A Cited
US4323643A Cited
US4269929A Cited
US4681836A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-04-24 1992-10-24 1993-04-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-04-24 1996-10-24 1997-04-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-04-24 2000-10-24 2001-04-25 $7700.00 Window Closed / Lapsed

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