Processes for purification of quaternary cationic surfactant materials and cosmetic compositions containing same

Claim 2

A process for purifying an impure quaternary cationic surfactant material intended for cosmetic use and rendering said quaternary cationic surfactant materials free flowing and substantially free of UV absorbing impurities having a maximum absorption in the range of from about 260 nm to about 280 nm comprising the following steps: (a) washing said impure quaternary cationic surfactant materials with an organic solvent selected from the group consisting of acetonitrile, acetone, diethyl ether, and mixtures thereof; (b) applying suction to remove the filtrate; and (c) drying the solid; wherein said impure quaternary cationic surfactant materials have the following general formula: ##STR6## wherein R 1 and R 2 are aliphatic groups containing from about 12 to about 22 carbon atoms, R 3 and R 4 are hydrogen or short chain alkyl groups containing from about 1 to about 4 carbon atoms and X is an ion selected from halogen, acetate, phosphate, nitrate and alkyl sulfate radicals.

Claim 3

A process according to claim 1 wherein the solvent is acetonitrile.

Claim 4

A process according to claim 2 wherein at least 0.5 mls/gm acetonitrile is used.

Claim 5

A process according to claim 2 wherein at least 5 mls/gm acetonitrile is used.

Claim 6

A process for purifying an impure quaternary cationic surfactant material intended for cosmetic use and rendering the material free flowing and substantially free of UV absorbing impurities with a maximum absorption at from about 270 nm to about 275 nm comprising the following steps: (a) washing the impure quaternary cationic surfactant material with at least 0.5 ml/gm acetonitrile for from about 60 to about 120 minutes; (b) applying suction for from about 30 to about 60 minutes to remove the filtrate; and (c) drying the solid, wherein said impure quaternary cationic surfactant materials have the following general formula: ##STR7## wherein R 1 and R 2 are aliphatic groups containing from about 12 to about 22 carbon atoms, R 3 and R 4 are hydrogen or short chain alkyl groups containing from about 1 to about 4 carbon atoms and X is an ion selected from halogen, acetate, phosphate, nitrate and alkyl sulfate radicals.

Claim 7

A process for purifying an impure quaternary cationic surfactant material intended for cosmetic use and rendering the material free flowing and substantially free of UV absorbing impurities with a maximum absorption at from about 270 nm to about 275 nm comprising the following steps: (a) washing the impure quaternary cationic surfactant material with at least 0.5 ml/gm acetonitrile for from about 60 to about 120 minutes; (b) applying suction for from about 30 to about 60 minutes to remove the filtrate; and (c) drying the solid, wherein said impure quaternary cationic surfactant materials have the following general formula: ##STR7## wherein R 1 and R 2 are aliphatic groups containing from about 12 to about 22 carbon atoms, R 3 and R 4 are hydrogen or short chain alkyl groups containing from about 1 to about 4 carbon atoms and X is an ion selected from halogen, acetate, phosphate, nitrate and alkyl sulfate radicals.

Claim 8

A shampoo composition comprising: (a) from about 0.5% to about 5% of a purified quaternary cationic surfactant material substantially free of, UV absorbing impurities with a maximum absorption at from about 270 nm to about 275 nm made by a process having the following steps: (i) washing the impure quaternary cationic surfactant material with at least 0.5 ml/gm acetonitrile for from about 60 to about 120 minutes; (ii) applying suction for from about 30 to about 60 minutes to remove the filtrate; and (iii) drying the solid, wherein said impure quaternary cationic surfactant materials have the following general formula: ##STR8## wherein R 1 and R 2 are aliphatic groups containing from about 12 to about 22 cabon atoms, R 3 and R 4 are hydrogen or short chain alkyl groups containing from about 1 to about 4 carbon atoms and X is an ion selected from halogen, acetate, phosphate, nitrate and alkyl sulfate radicals; (b) from about 0.5% to about 5% of a siloxane conditioning compound; (c) from about 5% to about 50% of a synthetic anionic surfactant; (d) from about 0.4% to about 3% of a suspending agent; and (e) water.

Claim 9

A shampoo composition comprising: (a) from about 0.5% to about 5% of a purified quaternary cationic surfactant material substantially free of, UV absorbing impurities with a maximum absorption at from about 270 nm to about 275 nm made by a process having the following steps: (i) washing the impure quaternary cationic surfactant material with at least 0.5 ml/gm acetonitrile for from about 60 to about 120 minutes; (ii) applying suction for from about 30 to about 60 minutes to remove the filtrate; and (iii) drying the solid, wherein said impure quaternary cationic surfactant materials have the following general formula: ##STR8## wherein R 1 and R 2 are aliphatic groups containing from about 12 to about 22 cabon atoms, R 3 and R 4 are hydrogen or short chain alkyl groups containing from about 1 to about 4 carbon atoms and X is an ion selected from halogen, acetate, phosphate, nitrate and alkyl sulfate radicals; (b) from about 0.5% to about 5% of a siloxane conditioning compound; (c) from about 5% to about 50% of a synthetic anionic surfactant; (d) from about 0.4% to about 3% of a suspending agent; and (e) water.

Claim 10

A shampoo composition according to claim 6 wherein the purified quaternary cationic surfactant material is selected from the group consisting of ditallow dimethyl ammonium chloride, distearyl dimethyl ammonium chloride, dicetyl dimethyl ammonium chloride, ditallow dimethyl ammonium phosphate, and di(hydrogenated tallow) dimethyl ammonium chloride.