Patent US4822836A successfully refreshed from Google Patents.
US4822836A
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Polyphenylene ether/polyamide blends having improved melt flow characteristics
Assignee: General Electric Co
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Filing: 1987-09-18
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Granted: 1989-04-18
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Expires: 2007-09-18
Abstract
Abstract Novel compatibilized polyphenylene ether-polyamide compositions are provided by this invention, comprising polyphenylene ether resin, polyamide resin, a compatibilizing agent, and a melt flow-improving compound. The compatibilizing agent may be selected from a wide variety of materials, such as saturated aliphatic polycarboxylic acids or derivatives thereof; various silane compounds; and functionalized polyphenylene ethers. A specific example of a compatibilizer is citric acid. Specific examples of melt flow-improving compounds are stearic acid, oleic acid, and linolenic acid.
Inventors
- 👤 Ronald J. Wroczynski
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 08:23
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/04; C08K5/09; C08L; C08L71/00; C08L71/08; C08L71/10; C08L71/12; C08L77/00; C08L75/00; C08L81/00
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
235 words
A compatibilized polyphenylene ether-polyamide composition having improved melt flow characteristics, comprising: (a) a polyphenylene ether resin, (b) a polyamide resin, (c) a compatibilizer compound for a) and b), and (d) a melt flow improving amount of a compound selected from the group consisting of straight chain fatty acids and organic carboxylic acids of the formula R-CO(T') wherein R is a monovalent alkyl or aralkyl radical having about 4 to 32 carbon atoms and R' is --OH or halogen, and acid anhydride derivatives thereof, wherein the compatibilizer is selected from the group consisting of: (A) a saturated aliphatic polycarboxylic acid or derivative thereof; (B) a silane compound comprising at least one silicon atom bonded to a carbon atom via an oxygen bridge and at least one ethylene carbon-to-carbon double bond or a carbon-to-carbon triple bond and/or an amine or mercapto functional group which is not bonded directly to the silicon atom; (C) a functionalized polyphenylene ether; (D) an oxidized polyolefin wax, optionally in combination with an organic phosphite; (E) a copolymer comprising units of a vinyl aromatic compound and an alpha-beta unsaturated dicarboxylic acid or dicarboxylic acid anhydride, or a copolymer with units of a vinyl aromatic compound of an imide compound of an alpha-beta unsaturated dicarboxylic acid; and (F) the reaction product of (a) a 1,2-substituted olefinic compound with a carboxyl group or acid anhydride group, (b) a polyphenylene ether, and (c) a radical initiator.
Claim 2
Dependent Claim
235 words
A compatibilized polyphenylene ether-polyamide composition having improved melt flow characteristics, comprising: (a) a polyphenylene ether resin, (b) a polyamide resin, (c) a compatibilizer compound for a) and b), and (d) a melt flow improving amount of a compound selected from the group consisting of straight chain fatty acids and organic carboxylic acids of the formula R-CO(T') wherein R is a monovalent alkyl or aralkyl radical having about 4 to 32 carbon atoms and R' is --OH or halogen, and acid anhydride derivatives thereof, wherein the compatibilizer is selected from the group consisting of: (A) a saturated aliphatic polycarboxylic acid or derivative thereof; (B) a silane compound comprising at least one silicon atom bonded to a carbon atom via an oxygen bridge and at least one ethylene carbon-to-carbon double bond or a carbon-to-carbon triple bond and/or an amine or mercapto functional group which is not bonded directly to the silicon atom; (C) a functionalized polyphenylene ether; (D) an oxidized polyolefin wax, optionally in combination with an organic phosphite; (E) a copolymer comprising units of a vinyl aromatic compound and an alpha-beta unsaturated dicarboxylic acid or dicarboxylic acid anhydride, or a copolymer with units of a vinyl aromatic compound of an imide compound of an alpha-beta unsaturated dicarboxylic acid; and (F) the reaction product of (a) a 1,2-substituted olefinic compound with a carboxyl group or acid anhydride group, (b) a polyphenylene ether, and (c) a radical initiator.
Claim 3
Dependent Claim
44 words
A composition as in claim 1 wherein compound (d) is selected from the group consisting of stearic acid, lauric acid, myristic acid, palmitic acid, oleic acid, linoleic acid, linolenic acid, behinic acid, arachidic acid, menhadenic acid, erucic acid and mixtures and acid anhydrides, thereof.
Claim 4
Dependent Claim
35 words
A composition as in claim 1 wherein compound (d) is present in an amount of about 0.01 to 10 parts by weight based upon the weight of 100 parts of said polyphenylene ether-polyamide base resin.
Claim 5
Dependent Claim
32 words
A composition as in claim 1 wherein compound (d) is present in an amount up to about 0.1 to 3 parts by weight per 100 parts of said polyphenylene ether-polyamide base resin.
Claim 6
Dependent Claim
25 words
A composition as in claim 1 wherein said polyphenylene ether resin is a polymer derived principally from 2,6 dimethyl phenylene units and/or 2,3,6-trimethyl phenylene units.
Claim 7
Dependent Claim
13 words
A composition as in claim 1 wherein said polyphenylene ether is poly(2,6-dimethyl-1,4-phenylene ether).
Claim 8
Dependent Claim
34 words
A composition as in claim 1 wherein said polyamide resin is selected from the group consisting of polyamide 6, polyamide 6,6 polyamide 11, polyamide 12, polyamide 6,3, polyamide 4,6, polyamide 6,10 and polyamide 6,12.
Claim 9
Dependent Claim
27 words
A composition as in claim 7 wherein the polyamide resin contains an excess of amine functional groups in relation to said resins concentration of acid functional groups.
Claim 10
Dependent Claim
53 words
A composition as in claim 1 wherein said polyphenylene ether resin is present in an amount of 5 to 80 parts by weight and said polyamide resin is present in a corresponding amount of 95 to 20 parts by weight based upon the weight of 100 parts of (a) and (b) taken together.
Claim 11
Dependent Claim
12 words
A composition as in claim 2 wherein compound (d) is stearic acid.
Claim 12
Dependent Claim
34 words
A composition as in claim 1, further comprising up to about 20 parts by weight of a elastomeric impact strength improving agent, based upon 100 parts by weight of the polyphenylene ether-polyamide base resin.
Claim 13
Dependent Claim
33 words
A composition as in claim 1 wherein said compatibilizer compound is present in an amount of 0.01 to 10 parts by weight based upon 100 parts of components (a) and (b) taken together.
Claim 14
Dependent Claim
13 words
A composition as in claim 12 wherein the compatibilizer compound is citric acid.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1992-04-17 | 1992-10-17 | 1993-04-18 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-04-17 | 1996-10-17 | 1997-04-18 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-04-17 | 2000-10-17 | 2001-04-18 | $7700.00 | Window Closed / Lapsed |