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US4822598A
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Cosmetic agent on the basis of quaternary chitosan derivatives, novel quaternary chitosan derivatives as well as processes for making same
Assignee: Procter and Gamble Deutschland GmbH
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Filing: 1983-11-03
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Granted: 1989-04-18
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Expires: 2003-11-03
Abstract
Abstract PCT No. PCT/EP83/00287 Sec. 371 Date Jul. 20, 1984 Sec. 102(e) Date Jul. 20, 1984 PCT Filed Nov. 3, 1983 PCT Pub. No. WO84/02343 PCT Pub. Date Jun. 21, 1984.The invention relates to cosmetic agents for treating of hairs or the skin which is characterized by a content of novel quaternary chitosan derivatives of the formula HO[C6H11-mNO4(R1)m(R2)n(R3)q]p H (m=0-0.5; n=0-6; q=0.005-3.0; p=10-50,000; R1=acetyl; R2=-CH2CH(OH)-CH2-O-, -CH2-CH(CH2OH)-O- or -CH(CH2OH)-CH2-O-; R3= <IMAGE> with R4=C1- to C4-alkyl and X=Cl, Br, or CH3SO4. It relates in furtherance to the novel quaternary chitosan derivatives as well as processes for making the same. These chitosan derivatives have a good substantivity, among others, to hair keratin and show hair strengthening and hair conditioning characteristics.
Inventors
- 👤 Gunther Lang
- 👤 Harald Wendel
- 👤 Eugen Konrad
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 10:06
CPC Classifications
A; A61; A61Q; A61Q19/00; A61K; A61K8/00; A61K8/18; A61K8/72; A61K8/73; A61K8/736; A61Q5/00; A61Q5/02; A61Q5/06; A61Q5/065; C; C08; C08B; C08B37/00; C08B37/0006; C08B37/0024; C08B37/0027; C08B37/003; A61K2800/00; A61K2800/40; A61K2800/54; A61K2800/542; A61K2800/5426; A61Q5/04; A61Q5/10
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
149 words
A cosmetic composition for the treatment of hair or skin, characterized in that the active ingredient is a quaternary macromolecular polymer compound derived from chitosan having the formula HO[C.sub.6 H.sub.11-m NO.sub.4 (R.sup.1).sub.m (R.sup.2).sub.n (R.sup.3).sub.q ].sub.p H, wherein m denotes any given numerical value from 0 to 0.5, n denotes any given numerical value from 0 to 6, q is a given numerical value from 0.005 to 3.0, p denotes a whole number from 10 to 50,000, R' is an acetyl residue, R 2 represents a bivalent residue of the formula --CH 2 CH(OH)--CH 2 --O--, ##STR7## and R 3 is a bivalent residue of the formula ##STR8## wherein R 4 =C 1 to C 4 alkyl and X=Cl, Br, I or CH 3 SO 4 , in a cosmetic carrier selected from the group consisting of water, an alcohol, an aqueous-alcoholic solution, a cream, a gel and an emulsion.
Claim 2
Dependent Claim
149 words
A cosmetic composition for the treatment of hair or skin, characterized in that the active ingredient is a quaternary macromolecular polymer compound derived from chitosan having the formula HO[C.sub.6 H.sub.11-m NO.sub.4 (R.sup.1).sub.m (R.sup.2).sub.n (R.sup.3).sub.q ].sub.p H, wherein m denotes any given numerical value from 0 to 0.5, n denotes any given numerical value from 0 to 6, q is a given numerical value from 0.005 to 3.0, p denotes a whole number from 10 to 50,000, R' is an acetyl residue, R 2 represents a bivalent residue of the formula --CH 2 CH(OH)--CH 2 --O--, ##STR7## and R 3 is a bivalent residue of the formula ##STR8## wherein R 4 =C 1 to C 4 alkyl and X=Cl, Br, I or CH 3 SO 4 , in a cosmetic carrier selected from the group consisting of water, an alcohol, an aqueous-alcoholic solution, a cream, a gel and an emulsion.
Claim 3
Dependent Claim
21 words
Composition in accordance with claim 1, characterized in that n in formula I denotes a numerical value of 1.0 to 2.1.
Claim 4
Dependent Claim
22 words
Composition in accordance with claim 1, characterized in that q in the formula I denotes a numerical value of 0.05 to 0.6.
Claim 5
Dependent Claim
27 words
Composition in accordance with claim 1, characterized in that it contains the polymer compound of formula I in an amount of from 0.05 to 10.0% by weight.
Claim 6
Dependent Claim
22 words
Composition in accordance with claim 1, further comprising cationic, nonionic, amphoteric or anionic tenside surfactant and provided in form of a shampoo.
Claim 7
Dependent Claim
17 words
Composition in accordance with claim 5, characterized in that the anionic tenside is an alkyl ether sulfate.
Claim 8
Dependent Claim
32 words
Composition in accordance with claim 6, characterized in that the tenside is contained therein in a concentration between 3 and 25% by weight and has a pH value between 4 and 7.
Claim 9
Dependent Claim
42 words
Composition in accordance with claim 1, characterized in that it contains as a cosmetic base an alcoholic or aqueous-alcoholic solution which is admixed with a pressurized propellant gas, is filled into a pressure container and is present as an aerosol hair spray.
Claim 10
Dependent Claim
49 words
Composition in accordance with claim 1, characterized in that the cosmetic base is water, alcoholic or aqueous-alcoholic solution, a cream, a gel or an emulsion, wherein the chitosan derivative of the formula I is contained in a concentration between 0.1 and 10% by weight, composition being for skin treatment.
Claim 11
Dependent Claim
93 words
Composition in accordance with claim 1, characterized in that it contains an additional film forming cosmetic polymer which is selected from the group consisting of shellac, alginates, gelatines, pectines, cellulose derivatives, polyvinylpyrrolidone, polyvinyl acetate, polymerisates of acrylic acid, polymerisates of methacrylic acid, basic polymerisates of esters of acrylic acid with amino alcohols, basic polymerizates of methacrylic acid with amino alcohols, salts of basic polymerisates of acrylic acid, salts of basic polymerisates of methacrylic acid, quaternisation products of basic polymerisates of acrylic acid, quaternisation products of basis polymerisates of methacrylic acid, polyacrylonitrile, and polyvinylpyrrolidone-vinylacetate.
Claim 12
Dependent Claim
39 words
Composition in accordance with claim 1, characterized in that the cosmetic base is water, alcoholic or aqueous-alcoholic solution or an emulsion further comprising additional hair dye and is present in the form of a dyeing strengthener or tinting strengthener.
Claim 13
Dependent Claim
106 words
Quaternary macromolecular polymer compound derived from chitosan of the general formula I HO[C.sub.6 H.sub.11-m NO.sub.4 (R.sup.1).sub.m (R.sup.2).sub.n (R.sup.3).sub.q ].sub.p H, wherein m denotes any given numerical value from 0 to 0.5, n denotes any given numerical value from 0 to 6, q is a given numerical value from 0.0005 to 3.0, p denotes a whole number from 10 to 50,000, R 1 is an acetyl residue, R 2 represents a bivalent residue --CH 2 CH(OH)--CH 2 --O--, ##STR9## and R 3 is a bivalent residue ##STR10## with R 4 =C 1 - to C 4 -alkyl and X=Cl, Br, I or CH 3 SO 4 .
Claim 14
Dependent Claim
106 words
Quaternary macromolecular polymer compound derived from chitosan of the general formula I HO[C.sub.6 H.sub.11-m NO.sub.4 (R.sup.1).sub.m (R.sup.2).sub.n (R.sup.3).sub.q ].sub.p H, wherein m denotes any given numerical value from 0 to 0.5, n denotes any given numerical value from 0 to 6, q is a given numerical value from 0.0005 to 3.0, p denotes a whole number from 10 to 50,000, R 1 is an acetyl residue, R 2 represents a bivalent residue --CH 2 CH(OH)--CH 2 --O--, ##STR9## and R 3 is a bivalent residue ##STR10## with R 4 =C 1 - to C 4 -alkyl and X=Cl, Br, I or CH 3 SO 4 .
Claim 15
Dependent Claim
43 words
Compound in accordance with claim 12, characterized in that in formula I, n denotes a numerical value of 1.0 to 2.1, q represents a numerical value of 0.05 to 1.1 and the limit viscosity n has a value of 27 to 733 ml/g.
Claim 16
Dependent Claim
15 words
Compound in accordance with claim 12, characterized in that in formula I n=0 and q=1.4.
Claim 17
Dependent Claim
18 words
Compound in accordance with claim 12, characterized in that in formula I R 4 =CH 3 and X=Cl.
References Cited (Backward Citations)
No citation records indexed.
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