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US4820751A
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Rubber composition for tires
Assignee: Bridgestone Corp
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Filing: 1988-04-25
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Granted: 1989-04-11
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Expires: 2008-04-25
Abstract
Abstract A rubber composition for tires having improved heat build-up and high temperature reinforcibility comprises specified amounts of particular surface-treated carbon black, silica and particular silane coupling agent based on 100 parts by weight of rubber ingredient.
Inventors
- 👤 Michitaka Takeshita
- 👤 Uchu Mukai
- 👤 Toshio Sugawara
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 08:22
CPC Classifications
C; C08; C08K; C08K3/00; C08K3/02; C08K3/04; B; B60; B60C; B60C1/00; B60C1/0016; C08K5/00; C08K5/54
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
254 words
A rubber composition for tires, comprising a rubber ingredient selected from the group consisting of natural rubber, diene series synthetic rubber and a blend thereof, and 30˜150 parts by weight of a reinforcible carbon black having a specific surface area (N 2 SA) of 70˜250 m 2 /g as measured by nitrogen adsorption process, a dibutyl phthalate absorption (DBP absorption) of 80˜150 ml/100 g, a concentration of total acidic group introduced into the surface of carbon black of 0.25˜2.0 μeq/m 2 , a ratio of weak acidic group in the total acidic group of at least 65% and a pH value of 3˜5.5, 0˜40 parts by weight of silica based on 100 parts by weight of said rubber ingredient, and 4.65×10 -5 m·s˜4.65×10 -3 m·s (m is parts by weight of carbon black added and s is a value of N 2 SA of carbon black) of at least one silane coupling agent selected from compounds having the following general formulae (1) and (2): Y.sub.3 --Si--C.sub.n H.sub.2n S.sub.m C.sub.n H.sub.2n Si--Y.sub.3 or Y.sub.3 --SiC.sub.n H.sub.2n X (1) wherein X is a nitroso group, a mercapto group, an amino group, an epoxy group, a vinyl group, a chlorine atom or an imido group, Y is an alkyl group or an alkoxyl group having a carbon number of 1˜4 or a chlorine atom, and each of n and m is an integer of 1˜6; and Y.sub.3 SiC.sub.n H.sub.2n S.sub.m S' (2) wherein X' is ##STR6## and Y, m and n are the same as described above.
Claim 2
Dependent Claim
254 words
A rubber composition for tires, comprising a rubber ingredient selected from the group consisting of natural rubber, diene series synthetic rubber and a blend thereof, and 30˜150 parts by weight of a reinforcible carbon black having a specific surface area (N 2 SA) of 70˜250 m 2 /g as measured by nitrogen adsorption process, a dibutyl phthalate absorption (DBP absorption) of 80˜150 ml/100 g, a concentration of total acidic group introduced into the surface of carbon black of 0.25˜2.0 μeq/m 2 , a ratio of weak acidic group in the total acidic group of at least 65% and a pH value of 3˜5.5, 0˜40 parts by weight of silica based on 100 parts by weight of said rubber ingredient, and 4.65×10 -5 m·s˜4.65×10 -3 m·s (m is parts by weight of carbon black added and s is a value of N 2 SA of carbon black) of at least one silane coupling agent selected from compounds having the following general formulae (1) and (2): Y.sub.3 --Si--C.sub.n H.sub.2n S.sub.m C.sub.n H.sub.2n Si--Y.sub.3 or Y.sub.3 --SiC.sub.n H.sub.2n X (1) wherein X is a nitroso group, a mercapto group, an amino group, an epoxy group, a vinyl group, a chlorine atom or an imido group, Y is an alkyl group or an alkoxyl group having a carbon number of 1˜4 or a chlorine atom, and each of n and m is an integer of 1˜6; and Y.sub.3 SiC.sub.n H.sub.2n S.sub.m S' (2) wherein X' is ##STR6## and Y, m and n are the same as described above.
Claim 3
Dependent Claim
25 words
The rubber composition according to claim 1, wherein an amount of said silane coupling agent is within a range of 1.16×10 -4 m·s˜1.16×10 -3 m·s.
Claim 4
Dependent Claim
23 words
The rubber composition according to claim 1, wherein an amount of said carbon black is within a range of 40˜100 parts by weight.
Claim 5
Dependent Claim
32 words
The rubber composition according to claim 1, wherein said diene series rubber is selected from synthetic isoprene rubber, styrene-butadiene rubber, butadiene rubber, butyl rubber, ethylene-propylene-diene terpolymer rubber, chloroprene rubber and nitrile rubber.
Claim 6
Dependent Claim
19 words
The rubber composition according to claim 1, wherein said concentration of total acidic group is 0.3˜0.8 μeq/m 2 .
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1992-04-10 | 1992-10-10 | 1993-04-11 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-04-10 | 1996-10-10 | 1997-04-11 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-04-10 | 2000-10-10 | 2001-04-11 | $7700.00 | Window Closed / Lapsed |