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US4820743A
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Polymer/polyol composition, processes for making the same and polyurethane therefrom
Assignee: Sanyo Chemical Industries Ltd
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Filing: 1987-12-09
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Granted: 1989-04-11
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Expires: 2007-12-09
Abstract
Abstract Polymer/polyol compositions, obtained by polymerizing one or more ethylenically unsaturated monomers in situ in a blend of a polyether polyol and a polyamine, are of suitably high reactivity. The polymer/polyol compositions provide, by reaction with a polyisocyanate, polyurethanes having improved moldability and physical properties along with self-mold-release characteristics, and are particularly suitable for producing polyurethane by RIM process.
Inventors
- 👤 Isao Ishikawa
- 👤 Tsuyoshi Tomosada
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 14:32
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/65; C08G18/6552; C08G18/6558; C08G18/657; C08G18/40; C08G18/63; C08G2120/00; C08G2125/00
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
147 words
A polymer/polyol composition, which is convertible by reaction with a polyisocyanate to a polyurethane, wherein the polymer of said composition is formed by polymerizing one or more ethylenically unsaturated monomers in situ in a blend of at least one polyol and at least one polyamine; said polyol comprising a polyol having a hydroxyl number of 15-100, selected from the group consisting of polyether polyols, polyester polyols, urethane-modified polyols, polyols containing polymerizable unsaturated bonds in the molecule, and polymer/polyols previously prepared in situ in any of these polyols; said polyamine being selected from the group consisting of aromatic polyamines, aliphatic polyamines, alicyclic polyamines, heterocyclic polyamines, araliphatic polyamines, polyamide polyamines, polyether polyamines and dicyandiamide; the amount of said polyamine being 0.5-60 parts by weight per 100 parts by weight of said polyol; and said polymer being present in an amount of 1-70% based on the weight of said composition.
Claim 2
Dependent Claim
147 words
A polymer/polyol composition, which is convertible by reaction with a polyisocyanate to a polyurethane, wherein the polymer of said composition is formed by polymerizing one or more ethylenically unsaturated monomers in situ in a blend of at least one polyol and at least one polyamine; said polyol comprising a polyol having a hydroxyl number of 15-100, selected from the group consisting of polyether polyols, polyester polyols, urethane-modified polyols, polyols containing polymerizable unsaturated bonds in the molecule, and polymer/polyols previously prepared in situ in any of these polyols; said polyamine being selected from the group consisting of aromatic polyamines, aliphatic polyamines, alicyclic polyamines, heterocyclic polyamines, araliphatic polyamines, polyamide polyamines, polyether polyamines and dicyandiamide; the amount of said polyamine being 0.5-60 parts by weight per 100 parts by weight of said polyol; and said polymer being present in an amount of 1-70% based on the weight of said composition.
Claim 3
Dependent Claim
110 words
The composition of claim 1, wherein said polyamine comprises at least one polyamine selected from aromatic polyamines represented by the following general formula (1), (2), (3) or (4): ##STR4## wherein R represents H, an alkyl group, an electron attractive group, or combination of two or more of them; n is an integer of 1-3; X represents direct link, or a divalent group, selected from the group consisting of C 1 -C 10 alkylene, --O--, --CO--, --CO--, --SO 2 --, thio, polythio, seleno, polyseleno, telluro and polytelluro groups; m is 0 or positive integer; and Y represents a trivalent aliphatic hydrocarbon groups; wherein plural R may be the same or different.
Claim 4
Dependent Claim
51 words
The composition of claim 1, wherein said polyamine is at least one compound selected from the group consisting of those having one or more alkyl substituents on the aromatic nucleus, those free from any substituents on the aromatic nucleus, and those having one or more electron-attractive substituents on the aromatic nucleus.
Claim 5
Dependent Claim
78 words
The composition of claim 1, wherein said polyamine is selected from the group consisting of: (1) at least one aromatic polyamine having one or more alkyl substituents on the aromatic nucleus; (2) at least one aromatic polyamine free from any substituents on the aromatic nucleus; (3) a combination of (1) and (2); and (4) a combination of (1), (2) or (3) with at least one aromatic polyamine having one or more electron attractive substituents on the aromatic nucleus.
Claim 6
Dependent Claim
44 words
The composition of claim 1, wherein said polyamine comprises an aromatic diamine having at least one alkyl substituent in the ortho-position to one amino group and two alkyl substituents each containing 1 to 3 carbon atoms in the ortho-positions to the other amino groups.
Claim 7
Dependent Claim
29 words
The composition of claim 5, wherein said diamine is at least one compound selected from the group consisting of 3,5-diethyl-2,4-tolylenediamine, 3,5-diethyl-2,6-tolylenediamine, 1,3-diethyl-2,4-diaminobenzene, 2,4-diamino-mesitylene, 1,3,5-triethyl-2,6-diamino-benzene, 2,4-diaminotoluene, 2,6-diaminotoluene, 3,3',5,5'-tetraethyl-4,4'-di-aminodiphenylemethane, and 3,3',5,5'-tetraisopropyl-4,4'-diaminodiphenylmethane.
Claim 8
Dependent Claim
16 words
The composition of claim 5, wherein said diamine is 3,5-diethyl-2,4-tolylenediamine, 3,5-diethyl-2,6-tolylenediamine, or a mixture of them.
Claim 9
Dependent Claim
18 words
The composition of claim 1, wherein said polyol having a hydroxyl number of 15-100 is a polyether polyol.
Claim 10
Dependent Claim
18 words
The composition of claim 8, wherein said polyether polyol contains at least 5% by weight of polyoxyethylene units.
Claim 11
Dependent Claim
29 words
The composition of claim 1, wherein said monomer is at least one ethylenically unsaturated compound selected from the group consisting of nitriles, hydrocarbon monomers, carboxylic acids and derivatives thereof.
Claim 12
Dependent Claim
123 words
A process for producing a polymer/polyol composition, convertible by reaction with a polyisocyanate to a polyurethane, which comprises polymerizing one or more ethylenically unsaturated monomers in situ in a blend of at least one polyol and at least one polyamine; said polyol comprising a polyol having a hydroxyl number of 15-100; said polyamine being selected from the group consisting of aromatic polyamines, aliphatic polyamines, alicyclic polyamines, heterocyclic polyamines, araliphatic polyamines, polyamide polyamines, polyether polyamines and dicyandiamide; said polyamine being used in an amount of 0.5-60 parts by weight per 100 parts by weight of said polyol; and said monomers being used in an amount of 1-50 parts by weight per 100 parts by weight of the total of said polyol and said polyamine.
Claim 13
Dependent Claim
123 words
A process for producing a polymer/polyol composition, convertible by reaction with a polyisocyanate to a polyurethane, which comprises polymerizing one or more ethylenically unsaturated monomers in situ in a blend of at least one polyol and at least one polyamine; said polyol comprising a polyol having a hydroxyl number of 15-100; said polyamine being selected from the group consisting of aromatic polyamines, aliphatic polyamines, alicyclic polyamines, heterocyclic polyamines, araliphatic polyamines, polyamide polyamines, polyether polyamines and dicyandiamide; said polyamine being used in an amount of 0.5-60 parts by weight per 100 parts by weight of said polyol; and said monomers being used in an amount of 1-50 parts by weight per 100 parts by weight of the total of said polyol and said polyamine.
Claim 14
Dependent Claim
78 words
The process of claim 11, wherein said polyamine is selected from the group consisting of: (1) at least one aromatic polyamine having one or more alkyl substituents on the aromatic nucleus; (2) at least one aromatic polyamine free from any substituents on the aromatic nucleus; (3) a combination of (1) and (2); and (4) a combination of (1), (2) or (3) with at least one aromatic polyamine having one or more electron attractive substituents on the aromatic nucleus.
Claim 15
Dependent Claim
26 words
A process for producing a cellular or noncellular polyurethane, which comprises reacting a mixture comprising the polymer/polyol composition claimed in claim 1 and an organic polyisocyanate.
Claim 16
Dependent Claim
26 words
A process for producing a cellular or noncellular polyurethane, which comprises reacting a mixture comprising the polymer/polyol composition claimed in claim 4 and an organic polyisocyanate.
Claim 17
Dependent Claim
105 words
The process of claim 13, wherein said polyisocyanate is reacted with an active hydrogen atom-containing component comprising, based on the weight of said component, (i) at least 20% of said polymer/polyol composition; (ii) 0-70% of at least one other high molecular weight polyol, having equivalent weight of 200-4,000, selected from the group consisting of polyether polyols, polyester polyols and modified polyols; and (iii) 0-70% of at least one low molecular weight compound containing at least two active hydrogen atom-containing groups, said compound having equivalent weight of at least 30 and less than 200, selected from the group consisting of low molecular weight polyols and amines.
Claim 18
Dependent Claim
10 words
A polyurethane foam produced by the process of claim 13.
Claim 19
Dependent Claim
20 words
A polyurethane, having an overall density of at least 0.6 g/cm 3 , produced by the process of claim 13.
Claim 20
Dependent Claim
15 words
The process of claim 16, wherein polyurethane molded article is formed by reaction injection molding.
Claim 21
Dependent Claim
19 words
The process of claim 18, wherein polyurethane molded article is formed without applying each time an external mold-release agent.
Claim 22
Dependent Claim
10 words
A microcelular polyurethane produced by the process of claim 18.
References Cited (Backward Citations)
US4683272A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1992-04-10 | 1992-10-10 | 1993-04-11 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-04-10 | 1996-10-10 | 1997-04-11 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-04-10 | 2000-10-10 | 2001-04-11 | $7700.00 | Window Closed / Lapsed |