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US4818815A Expired / Lapsed US ⏱️ 0.0 years remaining

Cationic 1,2,3-thiadiazole-azo-aniline or tetrahydroquinoline compounds

Assignee: Novartis Corp
•
Filing: 1986-07-17
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Granted: 1989-04-04
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Expires: 2006-07-17
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Abstract

Abstract The invention relates to novel 1,2,3-thiadiazole-axo compounds of formula ##STR1## wherein R is unsubstituted or substituted alkyl or alkenyl, R 1 is hydrogen or unsubstituted or substituted alkyl or alkenyl, R 2 is hydrogen or unsubstituted or substituted alkyl, alkenyl, cycloalkyl or phenyl, or R 1 and R 2 , together with the nitrogen atom to which they are attached, are a 5- or 6-membered heterocyclic ring which may contain one or two additional hetero atoms as ring members and/or may be substituted, or R 1 together with R 3 ortho to the amino group form a partially hydrogenated, unsubstituted or substituted 5-or 6-membered heterocyclic ring which may contain an additional N or O atom as ring member, R 3 and R 4 are each independently of the other hydrogen, alkyl, alkoxy, alkanoylamino or halogen, R 5 is hydrogen or together with R 4 in ortho-position forms the member which completes a fused benzene ring, R 7 is hydrogen, optionally substituted phenyl or alkyl, and X⊖ is an anion. These compounds are suitable for dyeing or printing acrylic, acid-modified polyamide and acid-modified polyester fibres in blue shades.

Inventors

  • 👤 Peter Moser

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 15:20
CPC Classifications
C; C09; C09B; C09B31/00; D; D06; D06P; D06P1/00; D06P1/41; C09B44/00; C09B44/10; C09B44/107

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 90 words
A 1,2,3-thiadiazole-azo compound of the formula ##STR36## wherein X.sup.⊖ is an anion R is C 1 -C 4 alkyl, each of R 1 and R 2 independently of the other is C 1 -C 4 alkyl, or R 1 together with R 3 in ortho-position to the amino group and with the benzene ring form a tetrahydroquinoline ring which is unsubstituted or substituted by 1 to 4 methyl groups, R 3 is hydrogen or together with R 1 is the tetrahydroquinoline radical as defined above, and R 4 is hydrogen.
Claim 2
Dependent Claim 90 words
A 1,2,3-thiadiazole-azo compound of the formula ##STR36## wherein X.sup.⊖ is an anion R is C 1 -C 4 alkyl, each of R 1 and R 2 independently of the other is C 1 -C 4 alkyl, or R 1 together with R 3 in ortho-position to the amino group and with the benzene ring form a tetrahydroquinoline ring which is unsubstituted or substituted by 1 to 4 methyl groups, R 3 is hydrogen or together with R 1 is the tetrahydroquinoline radical as defined above, and R 4 is hydrogen.
Claim 3
Dependent Claim 50 words
A 1,2,3-thiadiazole-azo compound according to claim 1, wherein X.sup.⊖ is an anion selected from halide, boron tetrafluoride, thiocyanide, sulfate, alkylsulfate, aminosulfate, chlorate, perchlorate, carbonate, bicarbonate, phosphate, phophoromolybdate, phosphorotungstate, phosphorotungstomolybdate, benzenesulfonate, chlorobenzenesulfonate, naphthalenesulfonate, toluenesulfonate, oxalate, maleate, formate, acetate, propionate, lactate, succinate, chloroacetate, tartrate, methanesulfonate and benzoate or is a complex anion.
Claim 4
Dependent Claim 29 words
A 1,2,3-thiadiazole-azo compound according to claim 2, wherein X.sup.⊖ is an anion selected from halide, methyl sulfate, ethyl sulfate, phosphate, sulfate, carbonate, benzenesulfonate, toluenesulfonate, 4-chlorobenzenesulfonate, acetate, formate or tetrachlorozinc.

References Cited (Backward Citations)

CA556218A Cited
US3148935A Cited
GB858181A Cited
US3280100A Cited
GB972956A Cited
US3793305A Cited
DE2142565A1 Cited
US4468349A Cited
JPS61107251A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-04-03 1992-10-03 1993-04-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-04-03 1996-10-03 1997-04-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-04-03 2000-10-03 2001-04-04 $7700.00 Window Closed / Lapsed

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