Composite metal spring material, method of making, and spring members formed therefrom

Claim 1

A composite metal spring material comprising a layer of a copper metal selected from the group consisting of high conductivity copper and age and precipitation hardenable copper alloys metallurgically bonded to each side of a layer of austenitic stainless steel to form a symmetrical composite metal laminate, the laminate being selectively work-hardened for providing the laminate with selected resilience to form an electrically conductive spring material, characterized in that the material of the layer of copper metal comprises a material selected from the group consisting of high conductivity copper and age and precipitation hardenable copper alloys having nominal compositions by weight percent of 0.05 to 0.15 zirconium, 0.005 max. iron, 0.005 max. aluminum, 0.005 max. magnesium and the balance copper plus silver, the total of iron, aluminum and magnesium not exceeding 0.01 max., an alloy of 0.040 to 0.080 phosphorous, 0.080 to 0.130 magnesium, and the balance (at least 99.75 min.) copper plus silver with silver in the range from 0.27 to 0.100, an alloy of 0.025 to 0.040 phosphorous, 0.015 to 0.15 iron and the balance copper (plus silver), an alloy of 0.025 to 0.060 zirconium and the balance copper (plus silver), an alloy of 0.03 phosphorous, 0.007 iron, 0.005 zinc, and the balance copper (plus silver), and substantially pure copper having not more than 0.05 of other constituents therein, and in that the stainless steel layer of the spring material comprises a stainless steel alloy having a limited stabilizing dispersion therein selected from the group having nominal compositions by weight percent of 0.15 carbon max., 2.00 manganese max., 1.00 silicon max., 0.060 phosphorous max., 0.030 sulfur max., 17.5 to 17.8 chromium, 7.5 to 7.8 nickel and the balance iron, an alloy of 0.04 carbon man., 2.50 manganese max., 0.50 silicon max., 17.25 chromium, 4.5 nickel, 2.4 copper, and the balance iron, and an alloy of 0.09 carbon max., 1.00 manganese max., 1.00 silicon max., 0.040 phosphorous max., 0.030 sulfur max., 16.0 to 18.0 chromium, 6.50 to 7.75 nickel, 0.75 to 1.50 aluminum, and the balance iron, the stainless steel material being selectively strain hardened equal to about twenty-five to fifty percent of full work-hardening thereof and dispersion strengthened and in substantially fully solutionized condition except for said strain hardening and dispersion strengthening and being in selected thermally stress-relieved condition for providing the spring material with improved tensile strength of improved stability.