Process for preparation of polyurethane condoms

Claim 2

Condoms consisting of a cross-linked thermoset polyurethane having a uniform wall thickness within the range of between about 2.2 and 2.8 mils obtained from a single dipping bath according to the process characterized by the steps of (a) setting up a single dipping bath, said bath comprising (1) a solvent solution of a polyurethane polymer or prepolymer; (2) said polymer or prepolymer being the reaction product of a polyisocyanate and at least one long chain polyol; (3) said polyol being amorphous and non-crystalline at room temperature and having an average molecular weight within the range of between about 500 and 6000; (4) said polyol having an average hydroxy number of within the range of between about 225 and 22.4; and (5) said polyisocyanate having an NCO/OH ratio of within the range of between about 0.95/1 and 1.1/1; (b) dipping molds on which condoms are to be formed in said single dipping bath for a period of time within the range of between about 30 and 60 seconds for depositing a polyurethane film in the form of a condom on each of said molds; (c) withdrawing said molds from said single dipping bath at the rate of within the range of between about 16 and 90 centimeters per minute; (d) curing said deposited film in the form of a condom on each of said molds by exposure to elevated temperatures for a time sufficient to effect said cure; (e) cooling the said cured film on said molds; (f) forming an integral cuff at the base of the said film on each of said molds; and (g) removing said deposited film in the form of a condom with an integral cuff from each of said molds.

Claim 3

Polyurethane condoms obtained by the process of claim 1, and further characterized by (a) said curing step being carried out for a period of time within the range of between about 20 and 40 minutes.

Claim 4

Polyurethane condoms obtained by the process of claim 1, further characterized by (a) said curing step being carried out at an elevated temperature within the range of between about 130 and 175 degrees Centigrade.

Claim 5

Polyurethane condoms obtained by the process of claim 1, further characterized by (a) said setting up step being carried out by providing said bath with a Brookfield viscosity within the range of between about 120 and 470 centipoise.

Claim 6

Polyurethane condoms obtained by the process of claim 1, further characterized by (a) prior to said dipping step selecting molds on which said condoms are to be formed; (b) applying in a first applying step a textured surface to said molds from said selecting step; and (c) applying in a second applying step a release agent to said textured surfaces.

Claim 7

Polyurethane condoms obtained by the process of claim 1, further characterized by (a) said second applying step being carried out with polytetrafluoroethylene powder.

Claim 8

Polyurethane condoms obtained by the process of claim 1, further characterized by (a) said cooling step being carried out to a temperature within the range of between about 50 and 60 degrees Centigrade.

Claim 9

Condoms comprised of a cross-linked thermoset polyurethane having a uniform wall thickness within the range of between about 2.2 and 2.8 mils obtained from a single dipping bath according to the process characterized by the steps of (a) setting up a single dipping bath, said bath comprising (1) a solvent solution of a polyurethane polymer or prepolymer; (2) said polymer or prepolymer being the reaction product of a polyisocyanate and at least one long chain polyol; (3) said polyol being amorphous and non-crystalline at room temperature and having an average molecular weight within the range of between about 500 and 6000; (4) said polyol having an average hydroxy number of within the range of between about 225 and 22.4; and (5) said polyisocyanate having an NCO/OH ratio of within the range of between about 0.95/1 and 1.1/1; (b) dipping molds on which condoms are to be formed in said single dipping bath for a period of time within the range of between about 30 and 60 seconds for depositing a polyurethane film in the form of a condom on each of said molds; (c) withdrawing said molds from said single dipping bath at the rate of within the range of between about 16 and 90 centimeters per minute; (d) curing said deposited film in the form of a condom on each of said molds by exposure to elevated temperatures for a time sufficient to effect said cure; (e) cooling the said cured film on said molds; (f) forming an integral cuff at the base of the said film on each of said molds; (g) applying a lubricant to said deposited film in the form of condoms; (h) said lubricant being a member selected from the group consisting of starch, a silicone compound or a water soluble gel lubricant; and (i) removing said deposited film in the form of a condom with an integral cuff from each of said molds.

Claim 10

Condoms comprised of a cross-linked thermoset polyurethane having a uniform wall thickness within the range of between about 2.2 and 2.8 mils obtained from a single dipping bath according to the process characterized by the steps of (a) setting up a single dipping bath, said bath comprising (1) a solvent solution of a polyurethane polymer or prepolymer; (2) said polymer or prepolymer being the reaction product of a polyisocyanate and at least one long chain polyol; (3) said polyol being amorphous and non-crystalline at room temperature and having an average molecular weight within the range of between about 500 and 6000; (4) said polyol having an average hydroxy number of within the range of between about 225 and 22.4; and (5) said polyisocyanate having an NCO/OH ratio of within the range of between about 0.95/1 and 1.1/1; (b) dipping molds on which condoms are to be formed in said single dipping bath for a period of time within the range of between about 30 and 60 seconds for depositing a polyurethane film in the form of a condom on each of said molds; (c) withdrawing said molds from said single dipping bath at the rate of within the range of between about 16 and 90 centimeters per minute; (d) curing said deposited film in the form of a condom on each of said molds by exposure to elevated temperatures for a time sufficient to effect said cure; (e) cooling the said cured film on said molds; (f) forming an integral cuff at the base of the said film on each of said molds; (g) applying a lubricant to said deposited film in the form of condoms; (h) said lubricant being a member selected from the group consisting of starch, a silicone compound or a water soluble gel lubricant; and (i) removing said deposited film in the form of a condom with an integral cuff from each of said molds.