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US4816507A
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1,2,2,6,6-pentamethyl-4-piperidylaminotriazine derivatives and their use as stabilizers
Assignee: BASF Corp
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Filing: 1987-08-14
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Granted: 1989-03-28
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Expires: 2007-08-14
Abstract
Abstract Compounds of the formula (I) ##STR1## wherein R 1 and R 5 are independently hydrogen, C 1 -C 12 -alkyl, C 5 -C 7 -cycloalkyl or a group of the formula (II), ##STR2## R 2 , R 3 and R 4 are independently C 2 -C 12 -alkylene, R is a group of the formula (III) ##STR3## wherein R 6 is C 2 -C 8 -dialkylamino, C 1 -C 4 -alkoxy, a 5-membered to 7-membered heterocyclic group containing a nitrogen atom which is attached to the triazine residue or a group of the formula (IV), ##STR4## R 7 and R 8 are independently C 1 -C 12 -alkyl, C 5 -C 7 -cycloalkyl, benzyl or a group of the formula (II), subject to the proviso that both, R 1 and R 5 are different from hydrogen, if R is a group ##STR5## are useful as light stabilizers, heat stabilizers and/or oxidation stabilizers for organic materials, in particular synthetic polymers.
Inventors
- 👤 Erfinders G. Cantatore
- 👤 Francois Gugumus
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 23:40
CPC Classifications
C; C07; C07D; C07D401/00; C07D401/14; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3467; C08K5/3477; C08K5/3492; C08K5/34926
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
133 words
A compound of the formula (I) ##STR21## wherein R 1 and R 5 are independently hydrogen, C 1 -C 12 -alkyl, C 5 -C 7 -cycloalkyl or a group of the formula (II), ##STR22## R 2 , R 3 and R 4 are independently C 2 -C 12 -alkylene, R is a group of the formula (III) ##STR23## wherein R 6 is C 2 -C 8 -dialkylamino, C 1 -C 4 -alkoxy, pyrrolidinyl, piperidino (other than morpholino or thiomorpholino) or a group of the formula (IV), ##STR24## R 7 and R 8 are independently C 1 -C 12 -alkyl, C 5 -C 7 -cycloalkyl, benzyl or a group of the formula (II), subject to the proviso that both, R 1 and R 5 are different from hydrogen, if R is a group ##STR25##
Claim 2
Dependent Claim
133 words
A compound of the formula (I) ##STR21## wherein R 1 and R 5 are independently hydrogen, C 1 -C 12 -alkyl, C 5 -C 7 -cycloalkyl or a group of the formula (II), ##STR22## R 2 , R 3 and R 4 are independently C 2 -C 12 -alkylene, R is a group of the formula (III) ##STR23## wherein R 6 is C 2 -C 8 -dialkylamino, C 1 -C 4 -alkoxy, pyrrolidinyl, piperidino (other than morpholino or thiomorpholino) or a group of the formula (IV), ##STR24## R 7 and R 8 are independently C 1 -C 12 -alkyl, C 5 -C 7 -cycloalkyl, benzyl or a group of the formula (II), subject to the proviso that both, R 1 and R 5 are different from hydrogen, if R is a group ##STR25##
Claim 3
Dependent Claim
22 words
The compound according to claim 1, wherein R 6 is C 2 -C 8 -dialkylamino, or a group of the formula (IV).
Claim 4
Dependent Claim
36 words
The compound according to claim 1, wherein R 6 is a group of the formula (IV) and R 7 and R 8 are independently C 1 -C 12 -alkyl or a group of the formula (II).
Claim 5
Dependent Claim
31 words
The compound according to claim 1, wherein R 1 and R 5 are independently C 1 -C 12 -alkyl, C 5 -C 7 -cycloalkyl or a group of the formula (II).
Claim 6
Dependent Claim
26 words
The compound according to claim 1, wherein R 1 and R 5 are independently C 1 -C 6 -alkyl or a group of the formula (II).
Claim 7
Dependent Claim
56 words
The compound according to claim 1, wherein R 1 and R 5 are methyl, R 2 , R 3 and R 4 are independently ethylene or trimethylene, R 6 is a group of the formula (IV) and R 7 and R 8 are independently C 1 -C 4 -alkyl or a group of the formula (II).
Claim 8
Dependent Claim
48 words
The compound according to claim 1, wherein R 1 and R 5 are methyl, R 2 and R 4 are trimethylene, R 3 is ethylene, R 6 is a group of the formula (IV), R 7 and R 8 which are identical are C 1 -C 12 -alkyl.
Claim 9
Dependent Claim
19 words
The compound according to claim 1, wherein R 7 and R 8 are independently C 1 -C 6 -alkyl.
Claim 10
Dependent Claim
18 words
The compound according to claim 1, wherein R 7 and R 8 are independently methyl, ethyl or butyl.
Claim 11
Dependent Claim
14 words
The compound according to claim 1, wherein R 7 and R 8 are n-butyl.
Claim 12
Dependent Claim
83 words
A compound mixture comprising 70% to 99% by weight of a compound of formula I according to claim 1, wherein R 1 and R 5 are methyl, and 0 to 30% by weight of a compound of the formula (Ib) ##STR26## and 0 to 30% by weight of a compound of the formula (Ic) ##STR27## wherein R, R 2 , R 3 and R 4 are as defined in claim 1 "wherein at least one of formula Ib or Ic must be present".
Claim 13
Dependent Claim
30 words
A composition stabilized against light, oxidation or heat induced degradation which comprises (a) a polymer, and (b) an effective stabilizing amount of at least one compound according to claim 1.
Claim 14
Dependent Claim
32 words
A method for stabilizing a polymer against light, oxidation or heat induced degradation which comprises incorporating in said polymer an effective stabilizing amount of at least one compound according to claim 1.
Claim 15
Dependent Claim
14 words
A composition according to claim 12, wherein the polymeric polymer is polyethylene or polypropylene.
Claim 16
Dependent Claim
12 words
A composition according to claim 12, which additionally contains a phenolic antioxidant.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1992-03-27 | 1992-09-26 | 1993-03-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-03-27 | 1996-09-26 | 1997-03-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-03-27 | 2000-09-26 | 2001-03-28 | $7700.00 | Window Closed / Lapsed |