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US4816356A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for producing a solid state battery

Assignee: Individual
•
Filing: 1987-11-09
•
Granted: 1989-03-28
•
Expires: 2007-11-09
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Abstract

Abstract A process for producing a solid state battery successively comprising, superimposed between two metallic contact elements, a layer or thin film of an alkali metal which provides a source of ions, a layer or thin film of ion-superconducting solid electrolyte glass of high ionic conductivity and a layer or thin film of a layered intercalation compound capable of inserting ions issued from the alkali metal film. The lamellae of the thin film or layer of layered compound are oriented substantially perpendicularly parallel to the surface of the solid electrolyte. The process includes forming the layer or thin film of layered intercalation compound by forming a periodic irregularity in only the surface atoms of a substantially smooth substrate surface, and molecular beam depositing the layer or thin film of layered intercalation compound on the substrate surface containing the periodic irregularity of surface atoms. The periodic irregularity of surface atoms conditions the nucleation starting of the layered growth.

Inventors

  • 👤 Minko Balkanski

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 05:15
CPC Classifications
H; H01; H01M; H01M10/00; H01M10/05; H01M10/056; H01M10/0561; H01M10/0562; H01M4/00; H01M4/02; H01M4/36; H01M4/58; H01M4/581; H01M6/00; H01M6/14; H01M6/18; H01M6/188; Y; Y02; Y02E; Y02E60/00; Y02E60/10; Y02P; Y02P70/00; Y02P70/50; Y10; Y10T; Y10T29/00; Y10T29/49; Y10T29/49002; Y10T29/49108; Y10T29/49115

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 200 words
A process for producing a solid state battery successively comprising, superimposed between two metallic contact elements, a layer or thin film of an alkali metal which provides a source of ions, a layer or thin film of ion-superconducting solid electrolyte glass of high ionic conductivity, and a layer or thin film of a layered intercalation compound capable of inserting ions issued from the layer or thin film of alkali metal, the lamellae of the thin film or layer of layered compound being oriented substantiallly perpendicularly to the surface of the solid electrolyte, said process including forming the layer or thin film of layered intercalation compound by the steps of (a) forming a periodic irregularity in only the surface atoms of a substantially smooth substrate surface, the substrate being selected from the group consisting of one of said metallic contact elements and said ion-superconducting solid electrolyte glass, and (b) molecular beam depositing the layer or thin film of layered intercalation compound on the substrate surface containing the periodic irregularity of surface atoms, the periodic irregularity of surface atoms conditioning the nucleation starting of the layered growth, whereby the lamellae of the layered compound correspond with the periodic irregularity of surface atoms.
Claim 2
Dependent Claim 200 words
A process for producing a solid state battery successively comprising, superimposed between two metallic contact elements, a layer or thin film of an alkali metal which provides a source of ions, a layer or thin film of ion-superconducting solid electrolyte glass of high ionic conductivity, and a layer or thin film of a layered intercalation compound capable of inserting ions issued from the layer or thin film of alkali metal, the lamellae of the thin film or layer of layered compound being oriented substantiallly perpendicularly to the surface of the solid electrolyte, said process including forming the layer or thin film of layered intercalation compound by the steps of (a) forming a periodic irregularity in only the surface atoms of a substantially smooth substrate surface, the substrate being selected from the group consisting of one of said metallic contact elements and said ion-superconducting solid electrolyte glass, and (b) molecular beam depositing the layer or thin film of layered intercalation compound on the substrate surface containing the periodic irregularity of surface atoms, the periodic irregularity of surface atoms conditioning the nucleation starting of the layered growth, whereby the lamellae of the layered compound correspond with the periodic irregularity of surface atoms.
Claim 3
Dependent Claim 43 words
A process for producing a solid state battery as defined by claim 1, wherein the periodic irregularity in the surface atoms comprises vicinal surfaces formed by cutting the substrate surface near a dense plane to provide a variation in the surface atom density.
Claim 4
Dependent Claim 30 words
A process for producing a solid state battery as defined by claim 1, wherein the periodic irregularity in the surface atoms is formed by chemically etching faces of surface crystallites.
Claim 5
Dependent Claim 32 words
A process for producing a solid state battery as defined by claim 2, wherein the periodic irregularity in only the surface atoms comprises a pattern of spaced, parallel lines of vicinal surfaces.
Claim 6
Dependent Claim 32 words
A process for producing a solid state battery as defined by claim 3, wherein the periodic irregularity in only the surface atoms comprises a pattern of spaced, parallel lines of etched crystallites.
Claim 7
Dependent Claim 24 words
A process for producing a solid state battery as defined by claim 1, wherein the molecular beam deposition is effected in an ultrahigh vacuum.
Claim 8
Dependent Claim 31 words
A process for producing a solid state battery as defined by claim 6, wherein the molecular beam deposition is effected in a vacuum of at least about 10 -11 mm Hg.
Claim 9
Dependent Claim 53 words
A process for producing a solid state battery as defined by claim 1, wherein the thin film or layer of layered compounds is formed on one of the metallic contact elements, and, on the layer thus obtained, the layer of ion-superconducting solid electrolyte glass and the layer of alkali metal are formed, respectively.
Claim 10
Dependent Claim 56 words
A process for producing a solid state battery as defined by claim 1, wherein the thin film or layer of layered compound is formed on the layer of ion-superconducting solid electrolyte glass, which is previously formed on the layer of alkali metal, after deposit of said alkali metal layer on one of the metallic contact elements.
Claim 11
Dependent Claim 106 words
A process for producing a solid state battery as defined by claim 1, wherein the layer or thin film of layered intercalation compound is formed of a substance selected from the group consisting of InSe, In 2 Se 3 , MPX 3 where M is a metal selected from the group Fe, Ni and Co, P is phosphorus and X is a metalloid selected from the group O, S, Se and Te, and MX 2 where M is a metal selected from the group Ti, Zr, Hf, Nb, Ta, Mo and W and X is a metalloid selected from the group O, S, Se and Te.
Claim 12
Dependent Claim 25 words
A process for producing a solid state battery as defined by claim 10, wherein the layer or thin film of layered intercalation compound comprises InSe.
Claim 13
Dependent Claim 30 words
A process for producing a solid state battery as defined by claim 1, wherein the layer or thin film of ion-superconducting solid electrolyte glass is formed of a lithio-borate glass.
Claim 14
Dependent Claim 38 words
A process for producing a solid state battery as defined by claim 12, wherein the layer of thin film of ion-superconducting solid electrolyte glass is formed of a lithio-borate glass comprising B 2 S 3 --Li 2 S--LiI.
Claim 15
Dependent Claim 95 words
A solid state battery successively comprising, superimposed between two metallic contact elements, a layer or thin film of an alkali metal which provides a source of ions, a layer or thin film of a ion-superconducting solid electrolyte glass of high ionic conductivity, and a layer or thin film of a layered intercalation compound capable of inserting ions issued from the alkali metal, the lamellae of the thin film or layer of layered compound being oriented substantially perpendicularly to the surface of the solid electrolyte, said layer of thin film of layered intercalation compound comprising InSe.
Claim 16
Dependent Claim 95 words
A solid state battery successively comprising, superimposed between two metallic contact elements, a layer or thin film of an alkali metal which provides a source of ions, a layer or thin film of a ion-superconducting solid electrolyte glass of high ionic conductivity, and a layer or thin film of a layered intercalation compound capable of inserting ions issued from the alkali metal, the lamellae of the thin film or layer of layered compound being oriented substantially perpendicularly to the surface of the solid electrolyte, said layer of thin film of layered intercalation compound comprising InSe.

References Cited (Backward Citations)

US4294898A Cited
US4299890A Cited
JPS5721073A Cited
EP0051947A1 Cited
JPS58126679A Cited
EP0103470A1 Cited
JPS59224065A Cited
FR2550015A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-03-27 1992-09-26 1993-03-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-03-27 1996-09-26 1997-03-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-03-27 2000-09-26 2001-03-28 $7700.00 Window Closed / Lapsed

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