Integrated fuel cell and fuel conversion apparatus

Claim 1

A fuel cell system comprising: (a) a fuel cell including a fuel electrode, an oxygen electrode, and an electrolyte disposed therebetween; (b) a pair of reaction vessels, each being adapted to alternately make a hydrogen containing gas and to be regenerated, each of said reaction vessels having an upstream end and a downstream end, each vessel having disposed therein, in sequence from its upstream to downstream end, a first volume of inert packing material containing no reform catalyst, a second volume of material including a first region comprising a regenerable sulfur absorber of oxides of zinc, oxides of iron, zinc ferrite, oxides of chromium, oxides, of copper, oxides of vanadium, oxides of tungsten or mixtures thereof and a second region downstream of said first region comprising reform catalyst material, and a third volume of material; (c) means for alternately directing a hydrocarbon feedstock and steam first into said first volume of one of said vessels and then into said first volume of the other of said vessels; (d) means for directing the hydrogen containing gas produced in the one of said vessels receiving said feedstock and steam into said fuel electrode of said fuel cell and for directing the exhaust from said fuel electrode and steam into said third volume of material in the other of said vessels; (e) means for directing an oxygen containing gas into said vessels including an inlet means upstream of said second region of reform catalyst; and (f) each of said vessels including combustion products outlet means at its upstream end for exhausting combustion products therefrom during regeneration of each vessel.