US4455286A
Expired / Lapsed
US
⏱️ 0.0 years remaining
High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures
Assignee: United States Department of Energy
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Filing: 1982-07-07
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Granted: 1984-06-19
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Expires: 2002-07-07
Abstract
Abstract A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.
Inventors
- 👤 John E. Young
- 👤 Vinod M. Jalan
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 14:10
CPC Classifications
H; H01; H01M; H01M8/00; H01M8/06; H01M8/0662; B; B01; B01D; B01D53/00; B01D53/02; Y; Y02; Y02E; Y02E60/00; Y02E60/30; Y02E60/50
Claims Analysis
Total Claims: 4
Claim 1
Independent Claim
142 words
A method of removing hydrogen sulfide from a gaseous mixture at a temperature of 500°-700° C. comprising: providing a sorbent mixture including about 60-70% ZnO and 30-40% by weight highly dispersed CuO; reducing the CuO to elemental copper by contact with hydrogen gas at a temperature of 230°-650° C.; passing the gaseous mixture at a temperature of 500°-700° C. into contact with the reduced sorbent mixture to form sulfides of copper in the sorbent as it is spent; regenerating the spent sorbent in an oxidizing atmosphere to remove substantially all of its sulfur content and form a regenerated sorbent mixture including a major proportion of ZnO and a minor proportion of CuO; reducing the regenerated CuO to elemental copper and passing additional gaseous mixture into contact with the reduced and regenerated sorbent mixture for removing H 2 S from the gaseous mixture.
Claim 2
Independent Claim
142 words
A method of removing hydrogen sulfide from a gaseous mixture at a temperature of 500°-700° C. comprising: providing a sorbent mixture including about 60-70% ZnO and 30-40% by weight highly dispersed CuO; reducing the CuO to elemental copper by contact with hydrogen gas at a temperature of 230°-650° C.; passing the gaseous mixture at a temperature of 500°-700° C. into contact with the reduced sorbent mixture to form sulfides of copper in the sorbent as it is spent; regenerating the spent sorbent in an oxidizing atmosphere to remove substantially all of its sulfur content and form a regenerated sorbent mixture including a major proportion of ZnO and a minor proportion of CuO; reducing the regenerated CuO to elemental copper and passing additional gaseous mixture into contact with the reduced and regenerated sorbent mixture for removing H 2 S from the gaseous mixture.
Claim 3
Dependent Claim
33 words
The method of claim 1 wherein the gaseous mixture contacts the sorbent in a continuous flow at a space velocity of about 700-2500 hr -1 in respect to the volume of the sorbent.
Claim 4
Dependent Claim
66 words
The method of claim 1 wherein a substantially continuous flow of gaseous mixture passes in contact with the sorbent while monitoring the H 2 S concentration in the said mixture leaving contact with the sorbent and wherein sorbent substantially free of sulfides of copper is provided for contacting said continuous flow of gaseous mixture when said concentration of H 2 S exceeds a predetermined breakthrough level.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-06-19 | 1987-12-19 | 1988-06-19 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-06-19 | 1991-12-19 | 1992-06-19 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-06-19 | 1995-12-19 | 1996-06-19 | $7700.00 | Window Closed / Lapsed |