Patent EP0164270A2 successfully refreshed from Google Patents.
Patent US4816074A successfully refreshed from Google Patents.
US4816074A
Expired / Lapsed
US
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Kaolinite aggregation using sodium silicate
Assignee: ECC America Inc
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Filing: 1988-01-28
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Granted: 1989-03-28
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Expires: 2008-01-28
Abstract
Abstract A process is described in which a structured aggregated kaolin pigment is prepared by mixing substantially dry kaolin in particulate form with an aqueous alkali metal silicate to deposit on the surface of the kaolin particles a substantially molecular level of said silicate without formation of silica gel, drying the treated kaolin without calcination and exposing it to an acidic gas. The product is useful as a pigment in the coating or filling of paper.
Inventors
- 👤 Rasik H. Raythatha
- 👤 E. Wayne Andrews
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 04:41
CPC Classifications
D; D21; D21H; D21H19/00; D21H19/36; D21H19/38; D21H19/40; C; C09; C09C; C09C1/00; C09C1/40; C09C1/42; C01; C01P; C01P2004/00; C01P2004/50; C01P2004/51; C01P2004/52; C01P2004/60; C01P2004/61; C01P2004/62; C01P2004/80; C01P2006/00; C01P2006/14; C01P2006/19; C01P2006/21; C01P2006/60; C01P2006/80; C01P2006/82; C01P2006/90; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31971; Y10T428/31993
Claims Analysis
Total Claims: 29
Claim 1
Independent Claim
68 words
A process for producing a structured aggregated kaolin pigment useful for improving optical properties when incorporated in paper which comprises the steps of mixing a substantially dry kaolin in particulate form with an aqueous alkali metal silicate to deposit on the surface of the kaolin particles a molecular level of silicate without formation of a silica gel, drying the treated kaolin and exposing it to an acidic gas.
Claim 2
Dependent Claim
68 words
A process for producing a structured aggregated kaolin pigment useful for improving optical properties when incorporated in paper which comprises the steps of mixing a substantially dry kaolin in particulate form with an aqueous alkali metal silicate to deposit on the surface of the kaolin particles a molecular level of silicate without formation of a silica gel, drying the treated kaolin and exposing it to an acidic gas.
Claim 3
Dependent Claim
28 words
The process as set forth in claim 1 in which the pH of the aqueous alkali metal silicate is in the range of about 11 to about 14.
Claim 4
Dependent Claim
33 words
The process as set forth in claim 2 in which the pH of the final product, measured as a 20% slurry in water, is in the range of about 2 to about 6.5.
Claim 5
Dependent Claim
36 words
The process as set forth in claim 1 in which the amount of silicate used is in the range of about 0.25 weight % to about 5.0 weight % based on the weight of dry clay.
Claim 6
Dependent Claim
35 words
The process as set forth in claim 1 in which about 0.62 weight % to about 12.5 weight % of a 40% active aqueous sodium silicate is used based on the weight of dry clay.
Claim 7
Dependent Claim
15 words
The process as set forth in claim 1 in which the acidic gas is HCl.
Claim 8
Dependent Claim
22 words
The process as set forth in claim 1 in which the acidic gas is moist HCl gas carried by an inert gas.
Claim 9
Dependent Claim
16 words
The process as set forth in claim 1 in which the acidic gas is anhydrous HCl.
Claim 10
Dependent Claim
19 words
The process as set forth in claim 1 in which residual HCl gas is neutralized with anhydrous gaseous ammonia.
Claim 11
Dependent Claim
19 words
The process as set forth in claim 1 in which the drying step is carried out below calcining temperature.
Claim 12
Dependent Claim
22 words
The process as set forth in claim 10 in which the drying step is carried out at temperatures not above 300° C.
Claim 13
Dependent Claim
27 words
The process as set forth in claim 1 in which the feed kaolin has a particle size distribution of at least 94% less than 2 micrometers E.S.D.
Claim 14
Dependent Claim
35 words
The process as set forth in claim 1 in which the feed clay is mixed with an aggregation enhancing agent selected from the group consistingof alkaline earth metal carbonates, chlorides or hydroxides, or lithium carbonate.
Claim 15
Dependent Claim
17 words
The process as set forth in claim 13 in which the aggregation enhancing agent is calcium carbonate.
Claim 16
Dependent Claim
29 words
The process as set forth in claim 13 in which the aggregation enhancing agent is calcium chloride and is added prior to the spray drying of the feed clay.
Claim 17
Dependent Claim
28 words
The process as set forth in claim 13 in which the aggregation enhancing agent is calcium chloride and is blended in after spray drying of the feed clay.
Claim 18
Dependent Claim
27 words
The process as set forth in claim 13 in which the aggregation enhancing agent is calcium hydroxide and is added after spray drying of the feed clay.
Claim 19
Dependent Claim
40 words
The process as set forth in claim 13 in which the aggregation enhancing agent is present in quantities to provide from about 5 to 120 millimoles of the enhancing agent metal ion species per 100 parts by weight of kaolin.
Claim 20
Dependent Claim
78 words
A process of coating paper which comprises employing as a coating pigment in a coating composition a structured aggregated kaolin prepared by mixing a substantially dry kaolin having a particle size distribution of at least 94% less than 2 micrometers E.S.D. with an aqueous alkali metal silicate to deposit on the surface of the kaolin particles a molecular layer of silicate without formation of a silica gel, drying the treated kaolin and exposing it to an acidic gas.
Claim 21
Dependent Claim
78 words
A process of coating paper which comprises employing as a coating pigment in a coating composition a structured aggregated kaolin prepared by mixing a substantially dry kaolin having a particle size distribution of at least 94% less than 2 micrometers E.S.D. with an aqueous alkali metal silicate to deposit on the surface of the kaolin particles a molecular layer of silicate without formation of a silica gel, drying the treated kaolin and exposing it to an acidic gas.
Claim 22
Dependent Claim
15 words
The method as set forth in claim 19 in which the acidic gas is HCl.
Claim 23
Dependent Claim
35 words
The method as set forth in claim 19 in which the treated kaolin pigment is used in an amount of about 5% to about 60% by weight of total pigment employed in the coating composition.
Claim 24
Dependent Claim
31 words
The process as set forth in claim 1 in which the aqueous alkali metal silicate has a ratio of SiO 2 /Na 2 O in the range of 1.25 to 3.8.
Claim 25
Dependent Claim
15 words
The process as set forth in claim 22 in which said ratio is about 1.25.
Claim 26
Dependent Claim
28 words
The process as set forth in claim 1 in which the moisture of the feed clay to the acidic gas treating step does not exceed 7 weight %.
Claim 27
Dependent Claim
18 words
The process as set forth in claim 1 in which the feed clay is prepared by air classification.
Claim 28
Dependent Claim
56 words
A process for producing a structured aggregated kaolin pigment useful for improving optical properties when incorporated in paper which comprises the steps of mixing an aqueous suspension of a particulate kaolin clay with an aqueous alkali metal silicate without formation of a silica gel, spray drying, and exposing the particulate kaolin clay to an acidic gas.
Claim 29
Dependent Claim
56 words
A process for producing a structured aggregated kaolin pigment useful for improving optical properties when incorporated in paper which comprises the steps of mixing an aqueous suspension of a particulate kaolin clay with an aqueous alkali metal silicate without formation of a silica gel, spray drying, and exposing the particulate kaolin clay to an acidic gas.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1992-03-27 | 1992-09-26 | 1993-03-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-03-27 | 1996-09-26 | 1997-03-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-03-27 | 2000-09-26 | 2001-03-28 | $7700.00 | Window Closed / Lapsed |