Enhancing the reaction rate in high temperature, high space velocity catalytic conversion of methane to higher molecular weight hydrocarbons

Claim 2

In a continuous catalytic process for the production of higher molecular weight hydrocarbons from methane in which a reaction gas containing methane and less than 1 volume percent other hydrocarbons is contacted in a reaction zone with a higher molecular weight hydrocarbon synthesis catalyst under C 2 + hydrocarbon synthesis conditions, the improvement comprising adding a C 2 to C 4 hydrocarbon to the reaction gas such that said C 2 to C 4 hydrocarbon comprises 1 to 5 volume percent of the reaction gas, said reaction conditions including a temperature greater than 1000° C. and a gas hourly space velocity of greater than 3200 hr -1 .

Claim 3

The process of claim 1 wherein said reaction zone contains a stationary or fluidized bed of a catalyst containing a carbide, nitride, boride or oxide of a Group I-A, II-A, III-A, IV-B or actinide series metal.

Claim 4

The process of claim 2 wherein said temperature is in the range of 1020° to 1150° C., said space velocity is in the range of 6000 to 36,000 hr -1 and at least 20 mole percent of said methane is converted to higher molecular weight hydrocarbons.

Claim 5

The process of claim 3 wherein said catalyst contains a Group I-A metal selected from lithium, potassium or cesium.

Claim 6

The process of claim 3 wherein said catalyst contains a Group II-A metal selected from beryllium, magnesium, calcium, strontium, barium or radium.

Claim 7

The process of claim 3 wherein said catalyst contains a Group III-A metal selected from aluminum, scandium, yttrium, lanthanum and actinium.

Claim 8

The process of claim 3, wherein said catalyst contain a Group IV-B metal selected from titanium, zirconium, and hafnium.

Claim 9

The process of claim 1 wherein said catalyst contains thorium or uranium.

Claim 10

The process of claim 1 wherein said catalyst contains a boron compound.

Claim 11

The process of claim 1 wherein said catalyst contains a silicon compound.

Claim 12

The process of claim 3 wherein said higher molecular weight hydrocarbon stream is rich in ethylene or aromatics or both.

Claim 13

In a continuous catalytic process for the production of higher molecular weight hydrocarbons from methane in which a reaction gas containing methane and less than 0.2 volume percent other hydrocarbons is contacted in a reaction zone with a higher molecular weight hydrocarbon synthesis catalyst under C 2 + hydrocarbon synthesis conditions, the improvement comprising adding a C 2 to C 4 hydrocarbon to the reaction gas such that said C 2 and C 4 hydrocarbon comprises 1 to 5 volume percent of the reaction gas, said conditions including a temperature in the range of 1050° to 1125° C., a space velocity is in the range of 9000 to 18,000 hr -1 and wherein at least 40 mole percent of said methane is converted to higher molecular weight hydrocarbons.

Claim 14

In a continuous catalytic process for the production of higher molecular weight hydrocarbons from methane in which a reaction gas containing methane and less than 0.2 volume percent other hydrocarbons is contacted in a reaction zone with a higher molecular weight hydrocarbon synthesis catalyst under C 2 + hydrocarbon synthesis conditions, the improvement comprising adding a C 2 to C 4 hydrocarbon to the reaction gas such that said C 2 and C 4 hydrocarbon comprises 1 to 5 volume percent of the reaction gas, said conditions including a temperature in the range of 1050° to 1125° C., a space velocity is in the range of 9000 to 18,000 hr -1 and wherein at least 40 mole percent of said methane is converted to higher molecular weight hydrocarbons.

Claim 15

The process of claim 12 wherein said catalyst contains a Group I-A metal selected from lithium, potassium or cesium.

Claim 16

The process of claim 12 wherein said catalyst contains a Group II-A metal selected from beryllium, magnesium, calcium, strontium, barium or radium.

Claim 17

The process of claim 12 wherein said catalyst contains a Group III-A metal selected from aluminum, scandium, yttrium, lanthanum and actinium.

Claim 18

The process of claim 12 wherein said catalyst contains a Group IV-B metal selected from titanium, zirconium, and hafnium.

Claim 19

The process of claim 12 wherein said catalyst contains thorium or uranium.

Claim 20

The process of claim 12 wherein said catalyst contains boron compound.

Claim 21

The process of claim 12 wherein said catalyst contains a silicon compound.

Claim 22

The process of claim 12 wherein said higher molecular weight hydrocarbon stream is rich in ethylene or aromatics or both.

Claim 23

In a continuous catalytic process for the production of higher molecular weight hydrocarbons from methane in which a reaction gas consisting essentially of methane and less than 0.2 volume percent other hydrocarbons is contacted in a reaction zone with a higher molecular weight hydrocarbon synthesis catalyst under C 2 + hydrocarbon synthesis conditions, the improvement comprising adding a C 2 to C 4 hydrocarbon to the reaction gas such that said C 2 and C 4 hydrocarbon to the reaction gas such that said C 2 to C 4 hydrocarbon comprises 2 to 4 volume percent of the reaction gas, whereby the reaction rate is increased by a factor of 1.4 to 4.0, said conditions including a temperature in the range of 1050° to 1125° C., a space velocity is in the range of 9000 to 18,000 hr -1 , said catalyst contains a carbide, nitride, boride, or oxide of a Group I-A, II-A, III-A, IV-B or actinide series metal and wherein at least 40 mole percent of said methane is converted to higher molecular weight hydrocarbons.

Claim 24

In a continuous catalytic process for the production of higher molecular weight hydrocarbons from methane in which a reaction gas consisting essentially of methane and less than 0.2 volume percent other hydrocarbons is contacted in a reaction zone with a higher molecular weight hydrocarbon synthesis catalyst under C 2 + hydrocarbon synthesis conditions, the improvement comprising adding a C 2 to C 4 hydrocarbon to the reaction gas such that said C 2 and C 4 hydrocarbon to the reaction gas such that said C 2 to C 4 hydrocarbon comprises 2 to 4 volume percent of the reaction gas, whereby the reaction rate is increased by a factor of 1.4 to 4.0, said conditions including a temperature in the range of 1050° to 1125° C., a space velocity is in the range of 9000 to 18,000 hr -1 , said catalyst contains a carbide, nitride, boride, or oxide of a Group I-A, II-A, III-A, IV-B or actinide series metal and wherein at least 40 mole percent of said methane is converted to higher molecular weight hydrocarbons.