US4814397A
Expired / Lapsed
US
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Stabilized polyacetal compositions
Assignee: EIDP Inc
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Filing: 1987-02-27
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Granted: 1989-03-21
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Expires: 2007-02-27
Abstract
Abstract Incorporation of 0.1-10 weight percent of certain polymers and/or oligomers containing both hydroxy groups and at least one other functional group that is a stronger Lewis base than the hydroxy groups into polyacetal molding compositions results in improved thermal stability of such compositions.
Inventors
- 👤 Ernest R. Novak
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 12:10
CPC Classifications
C; C08; C08L; C08L59/00; C08L33/00; C08L33/04; C08L33/14; C08L77/00
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
150 words
A thermoplastic polyacetal composition consisting essentially of (a) 0.1-10 weight percent of at least one compound selected from the group consisting of polymers and oligomers containing both hydroxy groups and at least one other functional group that is a stronger Lewis base than the hydroxy groups, and (b) 90-99.9 weight percent of at least one polyacetal polymer, provided that the above-stated percentages are based on the total amounts of components (a) and (b) only, provided further that the atoms in the backbone of the polymer or oligomer to which the hydroxy groups are attached, directly or indirectly, are separated by not more than twenty chain atoms; provided further that the quantity of the at least one other functional group is up to 50 equivalent percent of the number of equivalents of hydroxy groups in the component (a); and provided further that the component (a) is substantially free of acidic materials.
Claim 2
Dependent Claim
150 words
A thermoplastic polyacetal composition consisting essentially of (a) 0.1-10 weight percent of at least one compound selected from the group consisting of polymers and oligomers containing both hydroxy groups and at least one other functional group that is a stronger Lewis base than the hydroxy groups, and (b) 90-99.9 weight percent of at least one polyacetal polymer, provided that the above-stated percentages are based on the total amounts of components (a) and (b) only, provided further that the atoms in the backbone of the polymer or oligomer to which the hydroxy groups are attached, directly or indirectly, are separated by not more than twenty chain atoms; provided further that the quantity of the at least one other functional group is up to 50 equivalent percent of the number of equivalents of hydroxy groups in the component (a); and provided further that the component (a) is substantially free of acidic materials.
Claim 3
Dependent Claim
23 words
The composition of claim 1 wherein the polyacetal is homopolymer and the component (a) is substantially free of acidic materials and basic materials.
Claim 4
Dependent Claim
22 words
The composition of claim 1 wherein the component (a) is substantially free of acid salts and non-volatile ash of a basic character.
Claim 5
Dependent Claim
18 words
The composition of claims 1, 2 or 3 wherein component (a) comprises 0.2-4.0 weight percent of the composition.
Claim 6
Dependent Claim
18 words
The composition of claims 1, 2 or 3 wherein component (a) comprises 0.6-2.5 weight percent of the composition.
Claim 7
Dependent Claim
30 words
The composition of claims 1, 2 or 3 wherein the ratio of hydroxy groups to carbon atoms in the backbone of the polymer or oligomer is in the range 1:1-1:20.
Claim 8
Dependent Claim
27 words
The composition of claim 3 wherein the ratio of hydroxy groups to carbon atoms in the backbone of the polymer or oligomer is in the range 1:2-1:20.
Claim 9
Dependent Claim
31 words
The composition of claims 1, 2 or 3 wherein the ratio of hydroxy groups to carbon atoms in the backbone of the polymer or oligomer is in the range of 1:2-1:10.
Claim 10
Dependent Claim
30 words
The composition of claims 1, 2 or 3 wherein the ratio of hydroxy groups to carbon atoms in the backbone of the polymer or oligomer is in the range 1:2-1:5
Claim 11
Dependent Claim
34 words
The composition of claims 1, 2 or 3 wherein the quantity of the at least one other functional group is 1-25 equivalent percent of the number of equivalents of hydroxy groups in component (a).
Claim 12
Dependent Claim
34 words
The composition of claims 1, 2 or 3 where the quantity of the at least one other functional group is 2-10 equivalent percent of the number of equivalents of hydroxy groups in component (a).
Claim 13
Dependent Claim
32 words
The composition of claims 1, 2 or 3 wherein component (a) is a copolymer of hydroxypropyl methacrylate and a comonomer selected from the group consisting of acrylamide, methacrylamide, dimethylaminoethyl methacrylate, and vinyl-2-pyrrolidone.
Claim 14
Dependent Claim
15 words
The composition of claims 1, 2 or 3 wherein component (a) is hydroxypropyl methacrylate/acrylamide copolymer.
Claim 15
Dependent Claim
14 words
The composition of claims 1 or 3 wherein the polyacetal polymer is a homopolymer.
Claim 16
Dependent Claim
18 words
The composition of claim 14 wherein the component (a) contains not more than 40 ppm of acidic materials.
Claim 17
Dependent Claim
26 words
The composition of claim 2 wherein component (a) contains not more than 40 ppm of basic materials and not more than 40 ppm of acidic materials.
Claim 18
Dependent Claim
19 words
The composition of claims 1, 2 or 3 wherein the polyacetal has a number average molecular weight of 10,000-100,000.
Claim 19
Dependent Claim
24 words
The composition of claims 1, 2 or 3 further comprising at least one of co-stabilizers, antitioxidants, pigments, colorants, reinforcing agents, toughening agents and fillers.
Claim 20
Dependent Claim
13 words
The composition of claims 1, 2 or 3 further comprising a nylon co-stabilizer.
Claim 21
Dependent Claim
12 words
Shaped articles made from the composition of claims 1, 2 or 3.
Claim 22
Independent Claim
47 words
A method of preparing the composition or claims 1, 2 or 3 comprising mixing the hydroxy containing compound with the polyacetal polymer at a temperature above the melting points of the components or the composition and below the temperature at which degradation of the components will occur.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1992-03-20 | 1992-09-19 | 1993-03-21 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-03-20 | 1996-09-19 | 1997-03-21 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-03-20 | 2000-09-19 | 2001-03-21 | $7700.00 | Window Closed / Lapsed |