Polyolefin compositions for water pipes and for wire and cable coatings

Claim 2

An improved polyolefin composition having improved resistance to deterioration in the presence of chlorinated and nonchlorinated water and having improved resistance to temperatures in the range of about 0° C. to about 100° C. consisting of a blend of: (a) about 93 to about 99.5 percent by weight of an isotactic poly-1-butene polymer; (b) about 0.05 to about 0.50 percent by weight of a hindered amine UV stabilizer; (c) about 0.05 to about 1.1 by weight of a hindered phenolic thermal stabilizer having a molecular weight above 530 and selected from the group consisting of 1,3,5-trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxy-benzyl)benzene, octadecyl 3,5-di-tert-butyl-4-hydroxyhydrocinnamate, tetrakis[methylene(3,5-di-tert-butyl-4-hydroxy-hydro-cinnamate)]methane, 1,3,5-tris(4-tert-butyl-3-hydroxy-2,6-dimethylbenzyl)-1,3,5-triazine-2,4,6-(1H,3H,5H)-trione, bis-[3,3-bis(4'hydroxy-3'tert-butylphenyl)-butanoic acid]-glycolester, tris(3,5-di-t-butyl-4-hydroxybenzyl)isocyanurate and mixtures thereof; (d) about zero to about 0.5 percent by weight of a nucleating agent; (e) about zero to about 4 percent by weight of a pigment; (f) about zero to about 3.0 percent by weight of a filler; (g) from about 0.1 to about 3.0 percent by weight of a chelating agent selected from the group comprising: 2,2'-oxamidobis-ethyl 3-(3,5-di-t-butyl-4-hydroxy-phenyl)propionate, N'N'-bis[3-(3,5-di-tert-butyl-4-hydroxy-phenyl)]propionyl hydrazine, calcium bis(mono-ethyl (3,5-di-tert-butyl-4-hydroxy-benzyl)phosphonate, and tris(2-t-butyl-4-(2-methyl-4-hydroxy-5-t-butylphenylthio)-5-methyl)phenylphosphite.

Claim 3

The composition of claim 1 wherein said nucleating agent is high density polyethylene.

Claim 4

The composition of claim 1 wherein said pigment is selected from the group consisting of carbon black, iron oxide yellow, phthalocyanine blue and titanium dioxide.

Claim 5

The composition of claim 1 wherein said filler comprises a magnesium silicate coated with a metal stearate.

Claim 6

The composition of claim 1 wherein said filler is zinc stearate coated talc.

Claim 7

The composition of claim 1 wherein the relative amounts of each component are: (a) about 95.5 to about 99.5 percent by weight of said isotactic poly-1-butene polymer; (b) about 0.10 to about 0.40 percent by weight of said hindered amine UV stabilizer; (c) about 0.10 to about 0.90 by weight of said hindered phenolic thermal stabilizer having a molecular weight above 530 and selected from the group consisting of 1,2,5-trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxy-benzyl)benzene, octadecyl 3,5-di-tert-butyl-4-hydroxyhydrocinnamate, tetrakis[methylene(3,5-di-tert-butyl-4-hydroxy-hydro-cinnamate)]methane, 1,3,5-tris(4-tert-butyl-3-hydroxy-2,6-dimethylbenzyl)-1,3,5-triazine-2,4,6-(1H,3H,5H)-trione, bis-[3,3-bis(4'hydroxy-3'tert.butyl-phenyl)-butanoic acid]-glycolester, tris(3,5-di-t-butyl-4-hydroxybenzyl)isocyanurate, and mixtures thereof; (d) about 0.05 to about 0.4 percent by weight of said nucleating agent; (e) about zero to about 3 percent by weight of said pigment; (f) about zero to about 2 percent by weight of said filler; and (g) from about 0.1 to about 2.0 percent by weight of a chelating agent selected from the group comprising:

Claim 8

2'-oxamidobis-ethyl 3-(3,5-di-t-butyl-4-hydroxy-phenyl)propionate, N'N'-bis[3-(3,5-di-tert-butyl-4-hydroxy-phenyl)]propionyl hydrazine, calcium bis(mono-ethyl(3,5-di-tert-butyl-4-hydroxy-benzyl)phosphonate, and tris(2-t-butyl-4-(2-methyl-4-hydroxy-5-t-butylphenylthio)-5-methyl)phenylphosphite.

Claim 9

2'-oxamidobis-ethyl 3-(3,5-di-t-butyl-4-hydroxy-phenyl)propionate, N'N'-bis[3-(3,5-di-tert-butyl-4-hydroxy-phenyl)]propionyl hydrazine, calcium bis(mono-ethyl(3,5-di-tert-butyl-4-hydroxy-benzyl)phosphonate, and tris(2-t-butyl-4-(2-methyl-4-hydroxy-5-t-butylphenylthio)-5-methyl)phenylphosphite.

Claim 10

The composition of claim 1 wherein the relative amounts of each component are: (a) about 95.5 to about 99.5 percent by weight of said isotactic poly-1-butene polymer; (b) about 0.15 to about 0.3 percent by weight of said hindered amine UV stabilizer; (c) about 0.4 to about 0.75 by weight of said hindered phenolic thermal stabilizer having a molecular weight above 530 and selected from the group consisting of:

Claim 11

3,5-trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxy-benzyl)benzene, octadecyl 3,5-di-tert-butyl-4-hydroxyhydrocinnamate, tetrakis[methylene(3,5-di-tert-butyl-4-hydroxy-hydro-cinnamate)]methane, 1,3,5-tris(4-tert-butyl-3-hydroxy-2,6-dimethylbenzyl)-1,3,5-triazine-2,4,6-(1H,3H,5H)-trione, bis-[3,3-bis(4'hydroxy-3'tert-butyl-phenyl)-butanoic acid]-glycolester, tris(3,5-di-t-butyl-4-hydroxybenzyl)isocyanurate, and mixtures thereof; (d) about 0.1 to about 0.2 percent by weight of said nucleating agent; (e) about 0.2 to about 2 percent by weight of said pigment; (f) about 0.5 to about 1.5 percent by weight of said filler; and (g) about 0.1 to about 0.2 percent by weight of said chelating agent.

Claim 12

3,5-trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxy-benzyl)benzene, octadecyl 3,5-di-tert-butyl-4-hydroxyhydrocinnamate, tetrakis[methylene(3,5-di-tert-butyl-4-hydroxy-hydro-cinnamate)]methane, 1,3,5-tris(4-tert-butyl-3-hydroxy-2,6-dimethylbenzyl)-1,3,5-triazine-2,4,6-(1H,3H,5H)-trione, bis-[3,3-bis(4'hydroxy-3'tert-butyl-phenyl)-butanoic acid]-glycolester, tris(3,5-di-t-butyl-4-hydroxybenzyl)isocyanurate, and mixtures thereof; (d) about 0.1 to about 0.2 percent by weight of said nucleating agent; (e) about 0.2 to about 2 percent by weight of said pigment; (f) about 0.5 to about 1.5 percent by weight of said filler; and (g) about 0.1 to about 0.2 percent by weight of said chelating agent.

Claim 13

A composition for use in a cool water carrying system consisting of a polymeric blend of: (a) about 93 to about 99.5 percent by weight of an isotactic alpha olefin polymer having 2-6 carbon atoms; (b) about 0.05 to about 0.5 percent by weight of N,N'-bis(2,2,6,6-tetramethyl-4-piperidinyl)-1,6-hexane diamine polymer with 2,4,6-trichloro-1,3,5-triazine and 2,4,4-trimethyl-1,2-pentanamine; (c) about 0.05 to about 1.1 percent by weight of a hindered phenolic thermal stabilizer having a molcular weight above 530 and selected from the group consisting of: 1,3,5-trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxy-benzyl)benzene, octadecyl 3,5-di-tert-butyl-4-hydroxyhydrocinnamate, tetrakis[methylene(3,5-di-tert-butyl-4-hydroxy-hydro-cinnamate)]methane, 1,3,5-tris(4-tert-butyl-3-hydroxy-2,6-dimethylbenzyl)-1,3,5-triazine-2,4,6-(1H,3H,5H)-trione, bis-[3,3-bis(4'hydroxy-3'tert-butyl-phenyl)-butanoic acid]-glycolester, tris(3,5-di-t-butyl-4-hydroxybenzyl)isocyanurate and mixtures thereof; (d) from about zero to about 0.5 percent by weight of a nucleating agent; (e) about zero to about 4 percent by weight of a pigment; (f) about zero to about 3 percent by weight of a filler; and (g) about 0.1 to about 3 percent by weight of a chelating agent selected from the group comprising: 2,2'-oxamidobis-ethyl 3-(3,5-di-t-butyl-4-hydroxy-phenyl)propionate, N'N'-bis[3-(3,5-di-tert-butyl-4-hydroxy-phenyl)]propionyl hydrazine, calcium bis(mono-ethyl(3,5-di-tert-butyl-4-hydroxy-benzyl)phosphonate, and tris(2-t-butyl-4-(2-methyl-4-hydroxy-5-t-butylphenylthio)-5-methyl)phenylphosphite.

Claim 14

A composition for use in a cool water carrying system consisting of a polymeric blend of: (a) about 93 to about 99.5 percent by weight of an isotactic alpha olefin polymer having 2-6 carbon atoms; (b) about 0.05 to about 0.5 percent by weight of N,N'-bis(2,2,6,6-tetramethyl-4-piperidinyl)-1,6-hexane diamine polymer with 2,4,6-trichloro-1,3,5-triazine and 2,4,4-trimethyl-1,2-pentanamine; (c) about 0.05 to about 1.1 percent by weight of a hindered phenolic thermal stabilizer having a molcular weight above 530 and selected from the group consisting of: 1,3,5-trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxy-benzyl)benzene, octadecyl 3,5-di-tert-butyl-4-hydroxyhydrocinnamate, tetrakis[methylene(3,5-di-tert-butyl-4-hydroxy-hydro-cinnamate)]methane, 1,3,5-tris(4-tert-butyl-3-hydroxy-2,6-dimethylbenzyl)-1,3,5-triazine-2,4,6-(1H,3H,5H)-trione, bis-[3,3-bis(4'hydroxy-3'tert-butyl-phenyl)-butanoic acid]-glycolester, tris(3,5-di-t-butyl-4-hydroxybenzyl)isocyanurate and mixtures thereof; (d) from about zero to about 0.5 percent by weight of a nucleating agent; (e) about zero to about 4 percent by weight of a pigment; (f) about zero to about 3 percent by weight of a filler; and (g) about 0.1 to about 3 percent by weight of a chelating agent selected from the group comprising: 2,2'-oxamidobis-ethyl 3-(3,5-di-t-butyl-4-hydroxy-phenyl)propionate, N'N'-bis[3-(3,5-di-tert-butyl-4-hydroxy-phenyl)]propionyl hydrazine, calcium bis(mono-ethyl(3,5-di-tert-butyl-4-hydroxy-benzyl)phosphonate, and tris(2-t-butyl-4-(2-methyl-4-hydroxy-5-t-butylphenylthio)-5-methyl)phenylphosphite.

Claim 15

The composition of claim 8 wherein the relative amounts of each component are: (a) about 95.5 to about 99.5 percent by weight of said isotactic alpha olefin polymer having 2-6 carbon atoms; (b) about 0.10 to about 0.40 percent by weight of said N,N'-bis(2,2,6,6-tetramethyl-4-piperidinyl)-1,6-hexane diamine polymer with 2,4,6-trichloro-1,3,5-triazine and 2,4,5-trimethyl-1,2-pentanamine; (c) about 0.10 to about 0.90 by weight of said hindered phenolic thermal stabilizer having a molecular weight above 530 and selected from the group consisting of: 1,2,5-trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxy-benzyl)benzene, octadecyl 3,5-di-tert-butyl-4-hydroxyhydrocinnamate, tetrakis[methylene(3,5-di-tert-butyl-4-hydroxy-hydro-cinnamate)]methane, 1,3,5-tris(4-tert-butyl-3-hydroxy-2,6-dimethylbenzyl)-1,3,5-triazine-2,4,6-(1H,3H,5H)-trione, bis-[3,3-bis(4'hydroxy-3'tert-butyl-phenyl)-butanoic acid]-glycolester, tris(3,5-di-t-butyl-4-hydroxybenzyl)isocyanurate and mixtures thereof; (d) about 0.05 to about 0.4 percent by weight of said nucleating agent; (e) about zero to about 3 percent by weight of said pigment; (f) about zero to about 2 percent by weight of said filler; and (g) about 0.1 to about 2 percent by weight of said chelating agent.

Claim 16

The composition of claim 8 wherein the relative amounts of each component are: (a) about 95.5 to about 99.5 percent by weight of said isotactic alpha olefin polymer having 2-6 carbon atoms; (b) about 0.15 to about 0.3 percent by weight of N,N'-bis(2,2,6,6-tetramethyl-4-piperidinyl)-1,6-hexane diamine polymer with 2,4,6-trichloro-1,3,5-triazine and 2,4,4-trimethyl-1,2-pentanamine; (c) about 0.4 to about 0.75 by weight of said hindered phenolic thermal stabilizer having a molecular weight above 530 and selected from the group consisting of: 1,3,5-trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxy-benzyl)benzene, octadecyl 3,5-di-tert-butyl-4-hydroxyhydrocinnamate, tetrakis[methylene(3,5-di-tert-butyl-4-hydroxy-hydro-cinnamate)[methane, 1,3,5-tris(4-tert-butyl-3-hydroxy-2,6-diemethylbenzyl)-1,3,5-triazine-2,4,6-(1H,3H,5H)-trione, bis-[3,3-bis(4'hydroxy-3'tert,butyl-phenyl)-butanoic acid]-glycolester, tris(3,5-di-t-butyl-4-hydroxybenzyl)isocyanurate and mixtures thereof; (d) about 0.1 to about 0.2 percent by weight of said nucleating agent; (e) about 0.2 to about 2 percent by weight of said pigment; (f) about 0.5 to 1.5 percent by weight of said filler; and (g) about 0.1 to about 0.2 percent by weight of said chelating agent.

Claim 17

A composition for a chlorinated cool water supplying pipe consisting of essentially of a blend of: (a) about 93 to about 99.5 percent by weight of an isotactic butene-1 homopolymer; (b) about 0.05 to about 0.5 percent by weight of N,N'-bis(2,2,6,6-tetramethyl-4-piperidinyl)-1,6-hexane diamine polymer with 2,4,6-trichloro-1,3,5-triazine and 2,4,4-trimethyl-1,2-pentanamine; (c) about 0.05 to about 1.1 percent by weight of at least one hindered phenolic thermal stabilizer having a molecular weight above 530; (d) about 0.0 to about 0.5 percent by weight of a polyethylene nucleating agent; (e) about zero to about 4 percent by weight of a pigment; (f) about zero to about 3 percent by weight of a filler; and (g) about 0.1 to about 3.0 percent by weight of a chelating agent selected from the group comprising: 2,2'-oxamidobis-ethyl 3-(3,5-di-t-butyl-4-hydroxy-phenyl)propionate, N'N'-bis[3-(3,5-di-tert-butyl-4-hydroxy-phenyl)[propionyl hydrazine, calcium bis(mono-ethyl(3,5-di-tert-butyl-4-hydroxy-benzyl)phosphonate, and tris(2-t-butyl-4-(2-methyl-4-hydroxy-5-t-butylphenylthio)-5-methyl)phenylphosphite.

Claim 18

A composition for a chlorinated cool water supplying pipe consisting of essentially of a blend of: (a) about 93 to about 99.5 percent by weight of an isotactic butene-1 homopolymer; (b) about 0.05 to about 0.5 percent by weight of N,N'-bis(2,2,6,6-tetramethyl-4-piperidinyl)-1,6-hexane diamine polymer with 2,4,6-trichloro-1,3,5-triazine and 2,4,4-trimethyl-1,2-pentanamine; (c) about 0.05 to about 1.1 percent by weight of at least one hindered phenolic thermal stabilizer having a molecular weight above 530; (d) about 0.0 to about 0.5 percent by weight of a polyethylene nucleating agent; (e) about zero to about 4 percent by weight of a pigment; (f) about zero to about 3 percent by weight of a filler; and (g) about 0.1 to about 3.0 percent by weight of a chelating agent selected from the group comprising: 2,2'-oxamidobis-ethyl 3-(3,5-di-t-butyl-4-hydroxy-phenyl)propionate, N'N'-bis[3-(3,5-di-tert-butyl-4-hydroxy-phenyl)[propionyl hydrazine, calcium bis(mono-ethyl(3,5-di-tert-butyl-4-hydroxy-benzyl)phosphonate, and tris(2-t-butyl-4-(2-methyl-4-hydroxy-5-t-butylphenylthio)-5-methyl)phenylphosphite.

Claim 19

The composition of claim 11 wherein the relative amounts of each component are: (a) about 95.5 to about 99.5 percent by weight of said isotactic 1-butene homopolymer; (b) about 0.1 to about 0.4 percent by weight of N,N'-bis(2,2,6,6-tetramethyl-4-piperidinyl)-1,6-hexane diamine polymer with 2,4,6-trichloro-1,3,5-triazine and 2,4,4-trimethyl-1,2-pentanamine; (c) about 0.10 to about 0.90 by weight of said hindered phenolic thermal stabilizer having a molecular weight above 530 and selected from the group consisting of:

Claim 20

3,5-trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxy-benzyl)benzene, octadecyl 3,5-di-tert-butyl-4-hydroxyhydrocinnamate, tetrakis[methylene(3,5-di-tert-butyl-4-hydroxy-hydro-cinnamate)]methane, 1,3,5-tris(4-tert-butyl-3-hydroxy-2,6-dimethylbenzyl)-1,3,5-triazine-2,4,6-(1H,3H,5H)-trione, bis-[3,3-bis(4'hydroxy-3'tert-butyl-phenyl)-butanoic acid]-glycolester, tris(3,5-di-t-butyl-4-hydroxybenzyl)isocyanurate and mixtures thereof; (d) about 0.05 to about 0.4 percent by weight of said nucleating agent; (e) about zero to about 3 percent by weight of said pigment; (f) about zero to about 2 percent by weight of said filler; and (g) about 0.1 to about 2 percent by weight of said chelating agent.

Claim 21

3,5-trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxy-benzyl)benzene, octadecyl 3,5-di-tert-butyl-4-hydroxyhydrocinnamate, tetrakis[methylene(3,5-di-tert-butyl-4-hydroxy-hydro-cinnamate)]methane, 1,3,5-tris(4-tert-butyl-3-hydroxy-2,6-dimethylbenzyl)-1,3,5-triazine-2,4,6-(1H,3H,5H)-trione, bis-[3,3-bis(4'hydroxy-3'tert-butyl-phenyl)-butanoic acid]-glycolester, tris(3,5-di-t-butyl-4-hydroxybenzyl)isocyanurate and mixtures thereof; (d) about 0.05 to about 0.4 percent by weight of said nucleating agent; (e) about zero to about 3 percent by weight of said pigment; (f) about zero to about 2 percent by weight of said filler; and (g) about 0.1 to about 2 percent by weight of said chelating agent.

Claim 22

The composition of claim 11 wherein the relative amounts of each component are: (a) about 95.5 to about 99.5 percent by weight of said isotactic butene-1 homopolymer; (b) about 0.15 to about 0.3 percent by weight of N,N'-bis(2,2,6,6-tetramethyl-4-piperidinyl)-1,6-hexane diamine polymer with 2,4,6-trichloro-1,3,5-triazine and 2,4,4-trimethyl-1,2-pentanamine; (c) about 0.4 to about 0.75 by weight of said hindered phenolic thermal stabilizer having a molecular weight above 530 and selected from the group consisting of: 1,3,5-trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxy-benzyl)benzene, octadecyl 3,5,-di-tert-butyl-4-hydroxyhydrocinnamate, tetrakis[methylene(3,5-di-tert-butyl-4-hydroxy-hydro-cinnamate)]methane, 1,3,5-tris(4-tert-butyl-3-hydroxy-2,6-dimethylbenzyl)-1,3,5-triazine-2,4,6-(1H,3H,5H)-trione, bis-[3,3-bis(4'hydroxy-3'tert-butyl-phenyl)-butanoic acid]-glycolester, tris(3,5-di-t-butyl-4-hydroxybenzyl)isocyanurate and mixtures thereof; (d) about 0.1 to about 0.3 percent by weight of said nucleating agent; (e) about 0.2 to about 2 percent by weight of said pigment; (f) about 0.5 to about 1.5 percent by weight of said filler; and (g) about 0.1 to about 0.2 percent by weight of said chelating agent.

Claim 23

A composition for a chlorinated cool water supplying pipe consisting essentially of a blend of: (a) about 93 to about 99.5 percent by weight of an isotactic butene-1 copolymer; (b) about 0.05 to about 0.5 percent by weight of N,N'-bis(2,2,6,6-tetramethyl-4-piperidinyl)-1,6-hexane diamine polymer with 2,4,6-trichloro-1,3,5-triazine and 2,4,4-trimethyl-1,2-pentanamine; (c) about 0.05 to about 1.1 percent by weight of a hindered phenolic thermal stabilizer having a molecular weight above 530; (d) about zero to about 0.5 percent by weight of a polyethylene nucleating agent; (e) about zero to about 4 percent by weight of phthalocyanine blue pigment; (f) about zero to about 3 percent by weight of a filler; and (g) about 0.1 to about 3.0 percent by weight of a chelating agent selected from the group comprising: 2,2'-oxamidobis-ethyl 3-(3,5-di-t-butyl-4-hydroxy-phenyl)propionate, N'N'-bis[3-(3,5-di-tert-butyl-4-hydroxy-phenyl)]propanyl hydrazine, calcium bis(mono-ethyl(3,5-di-tert-butyl-4-hydroxy-benzyl)phosphonate, and tris(2-t-butyl-4-(2-methyl-4-hydroxy-5-t-butylphenylthio)-5-methyl)phenylphosphite.

Claim 24

A composition for a chlorinated cool water supplying pipe consisting essentially of a blend of: (a) about 93 to about 99.5 percent by weight of an isotactic butene-1 copolymer; (b) about 0.05 to about 0.5 percent by weight of N,N'-bis(2,2,6,6-tetramethyl-4-piperidinyl)-1,6-hexane diamine polymer with 2,4,6-trichloro-1,3,5-triazine and 2,4,4-trimethyl-1,2-pentanamine; (c) about 0.05 to about 1.1 percent by weight of a hindered phenolic thermal stabilizer having a molecular weight above 530; (d) about zero to about 0.5 percent by weight of a polyethylene nucleating agent; (e) about zero to about 4 percent by weight of phthalocyanine blue pigment; (f) about zero to about 3 percent by weight of a filler; and (g) about 0.1 to about 3.0 percent by weight of a chelating agent selected from the group comprising: 2,2'-oxamidobis-ethyl 3-(3,5-di-t-butyl-4-hydroxy-phenyl)propionate, N'N'-bis[3-(3,5-di-tert-butyl-4-hydroxy-phenyl)]propanyl hydrazine, calcium bis(mono-ethyl(3,5-di-tert-butyl-4-hydroxy-benzyl)phosphonate, and tris(2-t-butyl-4-(2-methyl-4-hydroxy-5-t-butylphenylthio)-5-methyl)phenylphosphite.

Claim 25

Pipes for carrying cool potable water which contain a polymeric compositions consisting essentially of an intimate blend of: (a) about 95.5 to about 99.5 percent by weight of an isotactic butene-1 homopolymer; (b) about 0.1 to about 0.4 percent by weight of N,N'-bis(2,2,6,6-tetramethyl-4-piperidinyl)-1,6-hexane diamine, polymer with 2,4,6-trichloro-1,3,5-triazine and 2,4,4-trimethyl-1,2-pentanamine; (c) about 0.1 to about 0.9 percent by weight of 1,3,5-trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxy-benzyl)-benzene and octadecyl 3, 5-di-tert-butyl-4-hydroxyhydrocinnamate; (d) about 0.05 to about 0.4 percent by weight of a nucleating agent; (e) about zero to about 3 percent by weight of a phthalocyanine blue pigment; (f) about zero to about 2 percent by weight of a filler; and (g) from about 0.1 to about 3.0 percent by weight of a chelating agent selected from the group comprising:

Claim 26

Pipes for carrying cool potable water which contain a polymeric compositions consisting essentially of an intimate blend of: (a) about 95.5 to about 99.5 percent by weight of an isotactic butene-1 homopolymer; (b) about 0.1 to about 0.4 percent by weight of N,N'-bis(2,2,6,6-tetramethyl-4-piperidinyl)-1,6-hexane diamine, polymer with 2,4,6-trichloro-1,3,5-triazine and 2,4,4-trimethyl-1,2-pentanamine; (c) about 0.1 to about 0.9 percent by weight of 1,3,5-trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxy-benzyl)-benzene and octadecyl 3, 5-di-tert-butyl-4-hydroxyhydrocinnamate; (d) about 0.05 to about 0.4 percent by weight of a nucleating agent; (e) about zero to about 3 percent by weight of a phthalocyanine blue pigment; (f) about zero to about 2 percent by weight of a filler; and (g) from about 0.1 to about 3.0 percent by weight of a chelating agent selected from the group comprising:

Claim 27

2'-oxamidobis-ethyl 3-(3,5-di-t-butyl-4-hydroxy-phenyl)propionate, N'N'-bis[3-(3,5-di-tert-butyl-4-hydroxy-phenyl)]propionyl hydrazine, calcium bis(mono-ethyl(3,5-di-tert-butyl-4-hydroxy-benzyl)phosphonate, and tris(2-t-butyl-4-(2-methyl-4-hydroxy-5-t-butylphenylthio)-5-methyl)phenylphosphite.

Claim 28

2'-oxamidobis-ethyl 3-(3,5-di-t-butyl-4-hydroxy-phenyl)propionate, N'N'-bis[3-(3,5-di-tert-butyl-4-hydroxy-phenyl)]propionyl hydrazine, calcium bis(mono-ethyl(3,5-di-tert-butyl-4-hydroxy-benzyl)phosphonate, and tris(2-t-butyl-4-(2-methyl-4-hydroxy-5-t-butylphenylthio)-5-methyl)phenylphosphite.

Claim 29

Pipes for carrying cool potable water which contain a polymeric composition consisting essentially of an intimate blend of: (a) about 99.5 to about 99.5 percent by weight of an isotactic butene-1 copolymer; (b) about 0.10 to about 0.4 perfent by weight of said N,N'-bis(2,2,6,6-tetramethyl-4-piperidinyl)-1,6-hexane diamine polymer with 2,4,6-trichloro-1,3,5-triazine and 2,4,4-trimethyl-1,2-pentanamine; (c) about 0.10 to about 0.90 percent by weight of a hindered phenolic thermal stabilizer having a molecular weight above 530 and selected from the group consisting of: 1,3,5-trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxy-benzyl)benzene, octadecyl 3,5-di-tert-butyl-4-hydroxyhydrocinnamate, tetrakis[methylene(3,5-di-tert-butyl-4-hydroxy-hydro-cinnamate)]methane, 1,3,5-tris(4-tert-butyl-3-hydroxy-2,6-dimethylbenzyl)-1,3,5-triazine-2,4,6-(1H,3H,5H)-trione, bis-[3,3-bis(4'hydroxy-3'tert-butyl-phenyl)-butanoic acid]-glycolester, tris(3,5-di-t-butyl-4-hydroxybenzyl)isocyanurate and mixtures thereof; (d) about 0.5 to about 0.4 percent by weight of a nucleating agent; (e) about zero to about 3 percent by weight of a phthalocyanine blue pigment; (f) about zero to about 2 percent by weight of a filler; and (g) about 0.1 to about 3.0 percent by weight of a chelating agent selecting from the group comprising: 2,2'-oxamidobis-ethyl 3-(3,5-di-t-butyl-4-hydroxy-phenyl)propionate, N'N'-bis[3-(3,5-di-tert-butyl-4-hydroxy-phenyl)]propionyl hydrazine, calcium bis(mono-ethyl(3,5-di-tert-butyl-4-hydroxy-benzyl)phosphonate, and tris(2-t-butyl-4-(2-methyl-4-hydroxy-5-t-butylphenylthio)-5-methyl)phenylphosphite.

Claim 30

Pipes for carrying cool potable water which contain a polymeric composition consisting essentially of an intimate blend of: (a) about 99.5 to about 99.5 percent by weight of an isotactic butene-1 copolymer; (b) about 0.10 to about 0.4 perfent by weight of said N,N'-bis(2,2,6,6-tetramethyl-4-piperidinyl)-1,6-hexane diamine polymer with 2,4,6-trichloro-1,3,5-triazine and 2,4,4-trimethyl-1,2-pentanamine; (c) about 0.10 to about 0.90 percent by weight of a hindered phenolic thermal stabilizer having a molecular weight above 530 and selected from the group consisting of: 1,3,5-trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxy-benzyl)benzene, octadecyl 3,5-di-tert-butyl-4-hydroxyhydrocinnamate, tetrakis[methylene(3,5-di-tert-butyl-4-hydroxy-hydro-cinnamate)]methane, 1,3,5-tris(4-tert-butyl-3-hydroxy-2,6-dimethylbenzyl)-1,3,5-triazine-2,4,6-(1H,3H,5H)-trione, bis-[3,3-bis(4'hydroxy-3'tert-butyl-phenyl)-butanoic acid]-glycolester, tris(3,5-di-t-butyl-4-hydroxybenzyl)isocyanurate and mixtures thereof; (d) about 0.5 to about 0.4 percent by weight of a nucleating agent; (e) about zero to about 3 percent by weight of a phthalocyanine blue pigment; (f) about zero to about 2 percent by weight of a filler; and (g) about 0.1 to about 3.0 percent by weight of a chelating agent selecting from the group comprising: 2,2'-oxamidobis-ethyl 3-(3,5-di-t-butyl-4-hydroxy-phenyl)propionate, N'N'-bis[3-(3,5-di-tert-butyl-4-hydroxy-phenyl)]propionyl hydrazine, calcium bis(mono-ethyl(3,5-di-tert-butyl-4-hydroxy-benzyl)phosphonate, and tris(2-t-butyl-4-(2-methyl-4-hydroxy-5-t-butylphenylthio)-5-methyl)phenylphosphite.

Claim 31

An improved polyolefin composition having improved resistance to deterioration in the presence of cool chlorinated water, said composition consisting essentially of a blend of: (a) about 95.5 to about 99.5 percent by weight of an isotactic butene-1 homopolymer; (b) about 0.15 to about 0.3 percent by weight of N,N'-bis(2,2,6,6-tetramethyl-4-piperidinyl)-1,6-hexane diamine polymer with 2,4,6-trichloro-1,3,5-triazine and 2,4,5-trimethyl-1,2-pentanamine; (c) about 0.40 to about 0.75 percent by weight of a mixture of octadecyl 3,5-di-tert-butyl-4-hydroxyhydrocinnamate and 1,3,5-trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxy-benzyl)-benzene; (d) about 0.1 to about 0.2 percent by weight of high density polyethylene; (e) about 0.2 to about 2.0 percent by weight of a member of the group consisting of phthalocyanine blue pigment, and mixture of carbon black, titanium dioxide; and (f) about 0.5 to about 1.5 percent by weight of a magnesium silicate coated with a metal stearate; and (g) about 0.1 to about 3.0 percent by weight of a chelating agent selected from the group comprising:

Claim 32

An improved polyolefin composition having improved resistance to deterioration in the presence of cool chlorinated water, said composition consisting essentially of a blend of: (a) about 95.5 to about 99.5 percent by weight of an isotactic butene-1 homopolymer; (b) about 0.15 to about 0.3 percent by weight of N,N'-bis(2,2,6,6-tetramethyl-4-piperidinyl)-1,6-hexane diamine polymer with 2,4,6-trichloro-1,3,5-triazine and 2,4,5-trimethyl-1,2-pentanamine; (c) about 0.40 to about 0.75 percent by weight of a mixture of octadecyl 3,5-di-tert-butyl-4-hydroxyhydrocinnamate and 1,3,5-trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxy-benzyl)-benzene; (d) about 0.1 to about 0.2 percent by weight of high density polyethylene; (e) about 0.2 to about 2.0 percent by weight of a member of the group consisting of phthalocyanine blue pigment, and mixture of carbon black, titanium dioxide; and (f) about 0.5 to about 1.5 percent by weight of a magnesium silicate coated with a metal stearate; and (g) about 0.1 to about 3.0 percent by weight of a chelating agent selected from the group comprising:

Claim 33

2'-oxamidobis-ethyl 3-(3,5-di-t-butyl-4-hydroxy-phenyl)propionate, N'N'-bis[3-(3,5-di-tert-butyl-4-hydroxy-phenyl)]propionyl hydrazine, calcium bis(mono-ethyl (3,5-di-tert-butyl-4-hydroxy-benzyl)phosphonate, and tris(2-t-butyl-4-(2-methyl-4-hydroxy-5-t-butylphenylthio)-5-methyl)phenylphosphite.

Claim 34

2'-oxamidobis-ethyl 3-(3,5-di-t-butyl-4-hydroxy-phenyl)propionate, N'N'-bis[3-(3,5-di-tert-butyl-4-hydroxy-phenyl)]propionyl hydrazine, calcium bis(mono-ethyl (3,5-di-tert-butyl-4-hydroxy-benzyl)phosphonate, and tris(2-t-butyl-4-(2-methyl-4-hydroxy-5-t-butylphenylthio)-5-methyl)phenylphosphite.

Claim 35

An improved polyolefin composition having resistance to deterioration in the presence of cool chlorinated water, said composition consisting essentially of a blend of: (a) about 95.5 to about 99.5 percent by weight of an isotactic butene-1 copolymer; (b) about 0.15 to about 0.3 percent by weight of N,N'-bis(2,2,6,6-tetramethyl-4-piperidinyl)-1,6-hexane diamine polymer with 2,4,6-trichloro-1,3,5-triazine and 2,4,4-trimethyl-1,2-pentanamine; (c) about 0.4 to about 0.75 percent by weight of a mixture of octadecyl 3,5-di-tert-butyl-4-hydroxyhydrocinnamate and 1,3,5-trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxy-benzyl)-benzene; (d) about 0.1 to about 0.2 percent by weight of high density polyethylene; (e) about 0.2 to about 2.0 percent by weight of a member of the group phthalocyanine blue, and a mixture of carbon black, titanium dioxide; and (f) about 0.5 to about 1.5 percent by weight of a magnesium silicate coated with a metal stearate; and (g) about 0.1 to about 3.0 percent by weight of a chelating agent selected from the group comprising:

Claim 36

An improved polyolefin composition having resistance to deterioration in the presence of cool chlorinated water, said composition consisting essentially of a blend of: (a) about 95.5 to about 99.5 percent by weight of an isotactic butene-1 copolymer; (b) about 0.15 to about 0.3 percent by weight of N,N'-bis(2,2,6,6-tetramethyl-4-piperidinyl)-1,6-hexane diamine polymer with 2,4,6-trichloro-1,3,5-triazine and 2,4,4-trimethyl-1,2-pentanamine; (c) about 0.4 to about 0.75 percent by weight of a mixture of octadecyl 3,5-di-tert-butyl-4-hydroxyhydrocinnamate and 1,3,5-trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxy-benzyl)-benzene; (d) about 0.1 to about 0.2 percent by weight of high density polyethylene; (e) about 0.2 to about 2.0 percent by weight of a member of the group phthalocyanine blue, and a mixture of carbon black, titanium dioxide; and (f) about 0.5 to about 1.5 percent by weight of a magnesium silicate coated with a metal stearate; and (g) about 0.1 to about 3.0 percent by weight of a chelating agent selected from the group comprising:

Claim 37

2'-oxamidobis-ethyl 3-(3,5-di-t-butyl-4-hydroxy-phenyl)propionate, N'N'-bis[3-(3,5-di-tert-butyl-4-hydroxy-phenyl)]propionyl hydrazine, calcium bis(mono-ethyl(3,5-di-tert-butyl-4-hydroxy-benzyl)phosphonate, and tris(2-t-butyl-4-(2-methyl-4-hydroxy-5-t-butylphenylthio)-5-methyl)phenylphosphite.

Claim 38

2'-oxamidobis-ethyl 3-(3,5-di-t-butyl-4-hydroxy-phenyl)propionate, N'N'-bis[3-(3,5-di-tert-butyl-4-hydroxy-phenyl)]propionyl hydrazine, calcium bis(mono-ethyl(3,5-di-tert-butyl-4-hydroxy-benzyl)phosphonate, and tris(2-t-butyl-4-(2-methyl-4-hydroxy-5-t-butylphenylthio)-5-methyl)phenylphosphite.

Claim 39

A wire and cable coating composition having improved resistance to deterioration in the presence of chlorinated and nonchlorinated water and having improved resistance to temperatures in the range of about 0° C. to about 100° C. consisting of a blend of: (a) about 93 to about 99.5 percent by weight of an isotactic poly-1-butene polymer; (b) about 0.05 to about 0.50 percent by weight of a hindered amine UV stabilizer; (c) about 0.05 to about 1.1 by weight of a hindered phenolic thermal stabilizer having a molecular weight above 530 and selected from the group consisting of 1,3,5-trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxy-benzyl)benzene, octadecyl 3,5-di-tert-butyl-4-hydroxyhydrocinnamate, tetrakis[methylene(3,5-di-tert-butyl-4-hydroxy-hydro-cinnamate)]-methane, 1,3,5-tris(4-tert-butyl-3-hydroxy-2,6-dimethylbenzyl)-1,3,5-triazine-2,4,6-(1H,3H,5H)-trione, bis-[3,3-bis(4'hydroxy-3'tert-butylphenyl)-butanoic acid]-glyolester, tris(3,5-di-t-butyl-4-hydroxybenzyl)isocyanurate and mixtures thereof; (d) about zero to about 0.5 percent by weight of a nucleating agent; (e) about zero to about 4 percent by weight of a pigment; (f) about zero to about 3.0 percent by weight of a filler; (g) about 0.1 to about 3.0 percent by weight of a chelating agent selected from the group comprising:

Claim 40

A wire and cable coating composition having improved resistance to deterioration in the presence of chlorinated and nonchlorinated water and having improved resistance to temperatures in the range of about 0° C. to about 100° C. consisting of a blend of: (a) about 93 to about 99.5 percent by weight of an isotactic poly-1-butene polymer; (b) about 0.05 to about 0.50 percent by weight of a hindered amine UV stabilizer; (c) about 0.05 to about 1.1 by weight of a hindered phenolic thermal stabilizer having a molecular weight above 530 and selected from the group consisting of 1,3,5-trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxy-benzyl)benzene, octadecyl 3,5-di-tert-butyl-4-hydroxyhydrocinnamate, tetrakis[methylene(3,5-di-tert-butyl-4-hydroxy-hydro-cinnamate)]-methane, 1,3,5-tris(4-tert-butyl-3-hydroxy-2,6-dimethylbenzyl)-1,3,5-triazine-2,4,6-(1H,3H,5H)-trione, bis-[3,3-bis(4'hydroxy-3'tert-butylphenyl)-butanoic acid]-glyolester, tris(3,5-di-t-butyl-4-hydroxybenzyl)isocyanurate and mixtures thereof; (d) about zero to about 0.5 percent by weight of a nucleating agent; (e) about zero to about 4 percent by weight of a pigment; (f) about zero to about 3.0 percent by weight of a filler; (g) about 0.1 to about 3.0 percent by weight of a chelating agent selected from the group comprising:

Claim 41

2'-oxamidobis-ethyl 3-(3,5-di-t-butyl-4-hydroxy-phenyl)propionate, N'N'-bis[3-(3,5-di-tert-butyl-4-hydroxy-phenyl)]propionyl hydrazine, calcium bis(mono-ethyl(3,5-di-tert-butyl-4-hydroxy-benzyl)phosphonate, and tris(2-t-butyl-4-(2-methyl-4-hydroxy-5-t-butylphenylthio)-5-methyl)phenylphosphite.

Claim 42

2'-oxamidobis-ethyl 3-(3,5-di-t-butyl-4-hydroxy-phenyl)propionate, N'N'-bis[3-(3,5-di-tert-butyl-4-hydroxy-phenyl)]propionyl hydrazine, calcium bis(mono-ethyl(3,5-di-tert-butyl-4-hydroxy-benzyl)phosphonate, and tris(2-t-butyl-4-(2-methyl-4-hydroxy-5-t-butylphenylthio)-5-methyl)phenylphosphite.

Claim 43

The composition of claim 19 wherein said nucleating agent is high density polyethylene.

Claim 44

The composition of claim 19 wherein said pigment is selected from the group consisting of carbon black, iron oxide yellow, phthalocyanine blue and titanium dioxide.

Claim 45

The composition of claim 19 wherein said filler comprises a magnesium silicate coated with a metal stearate.

Claim 46

The composition of claim 19 wherein said filler is zinc stearate coated talc.

Claim 47

The composition of claim 19 wherein the relative amounts of each component are: (a) about 95.5 to about 99.5 percent by weight of said isotactic poly-1-butene polymer; (b) about 0.10 to about 0.40 percent by weight of said hindered amine UV stabilizer; (c) about 0.10 to about 0.90 by weight of said hindered phenolic thermal stabilizer having a molecular weight above 530 and selected from the group consisting of 1,2,5-trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxy-benzyl)benzene, octadecyl 3,5-di-tert-butyl-4-hydroxyhydrocinnamate, tetrakis[methylene(3,5-di-tert-butyl-4-hydroxy-hydro-cinnamate)]methane, 1,3,5-tris(4-tert-butyl-3-hydroxy-2,6-dimethylbenzyl)-1,3,5-triazine-2,4,6-(1H,3H,5H)-trione, bis-[3,3-bis(4'hydroxy-3'tert-butylphenyl)-butanoic acid]-glycolester, tris(3,5-di-t-butyl-4-hydroxybenzyl)isocyanurate, and mixtures thereof; (d) about 0.05 to about 0.4 percent by weight of said nucleating agent; (e) about zero to about 3 percent by weight of said pigment; (f) about zero to about 2 percent by weight of said filler; and (g) about 0.1 to about 3.0 percent by weight of a chelating agent selected from the group comprising:

Claim 48

2'-oxamidobis-ethyl 3-(3,5-di-t-butyl-4-hydroxy-phenyl)propionate, N'N'-bis[3-(3,5-di-tert-butyl-4-hydroxy-phenyl)]propionyl hydrazine, calcium bis(mono-ethyl(3,5-di-tert-butyl-4-hydroxy-benzyl)phosphonate, and tris(2-t-butyl-4-(2-methyl-4-hydroxy-5-t-butylphenylthio)-5-methyl)phenylphosphite.

Claim 49

2'-oxamidobis-ethyl 3-(3,5-di-t-butyl-4-hydroxy-phenyl)propionate, N'N'-bis[3-(3,5-di-tert-butyl-4-hydroxy-phenyl)]propionyl hydrazine, calcium bis(mono-ethyl(3,5-di-tert-butyl-4-hydroxy-benzyl)phosphonate, and tris(2-t-butyl-4-(2-methyl-4-hydroxy-5-t-butylphenylthio)-5-methyl)phenylphosphite.

Claim 50

The composition of claim 19 wherein the relative amounts of each component are: (a) about 95.5 to about 99.5 percent by weight of said isotactic poly-1-butene polymer; (b) about 0.15 to about 0.3 percent by weight of said hindered amine UV stabilizer; (c) about 0.4 to about 0.75 by weight of said hindered phenolic thermal stabilizer having a molecular weight above 530 and selective from the group consisting of: 1,3,5-trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxy-benzyl)benzene, octadecyl 3,5-di-tert-butyl-4-hydroxyhydrocinnamate, tetrakis[methylene(3,5-di-tert-butyl-4-hydroxy-hydro-connamate)]methane, 1,3,5-tris(4-tert-butyl-3-hydroxy-2,6-dimethylbenzyl)-1,3,5-triazine-2,4,6-(1H,3H,5H)-trione, bis-[3,3-bis(4'hydroxy-3'tert-butyl-phenyl)-butanoic acid]-glycolester, tris(3,5-di-t-butyl-4-hydroxybenzyl)isocyanurate, and mixtures thereof; (d) about 0.1 to about 0.2 percent by weight of said nucleating agent; (e) about 0.2 to about 2 percent by weight of said pigment; (f) about 0.5 to about 1.5 percent by weight of said filler; and (g) about 0.1 to about 0.2 percent by weight of said chelating agent.