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US4809771A Expired / Lapsed US ⏱️ 0.0 years remaining

Lih thermal storage capsule/heat exchanger

Assignee: SUBJECT TO LICENSE
•
Filing: 1987-04-24
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Granted: 1989-03-07
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Expires: 2007-04-24
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Abstract

Abstract A thermal storage apparatus for use with space-based burst power supplies. Lithium hydride is encapsulated within spherical hollow capsules. Each capsule is made of a three layer hollow shell. The inner layer of each shell is molybdemum, the middle layer silicon carbide, and the outer layer molybedum. The lithium hydride occupies only about sixty percent of the interior volume of each capsule at ambient temperatures to allow for thermal expansion. The outer diameter of each capsule is 3 cm. The thickness of the layers is 0.1 mm for the inner and outer layer, and 0.3-0.5 mm for the middle layer. The capsules are arranged in a packed array for use in heat storage. A heat transfer working fluid, such as lithium, sodium or potassium, transfers heat to and from the packed array.

Inventors

  • 👤 Elliot B. Kennel
  • 👤 Edward T. Mahefkey
  • 👤 Jerry E. Beam

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 20:40
CPC Classifications
C; C09; C09K; C09K5/00; C09K5/02; C09K5/06; F; F28; F28D; F28D20/00; F28D20/02; F28D20/023; Y; Y02; Y02E; Y02E60/00; Y02E60/14

Claims Analysis

Total Claims: 23
Claim 1
Independent Claim 57 words
A thermal storage apparatus for transferring and storing heat energy to and from a heat transfer working fluid, comprising a generally spherically shaped hollow shell containing a heat sink material, wherein the hollow shell comprises: (a) an inner shell layer of metal; (b) a middle shell layer of ceramic; and, (c) an outer shell layer of metal.
Claim 2
Dependent Claim 57 words
A thermal storage apparatus for transferring and storing heat energy to and from a heat transfer working fluid, comprising a generally spherically shaped hollow shell containing a heat sink material, wherein the hollow shell comprises: (a) an inner shell layer of metal; (b) a middle shell layer of ceramic; and, (c) an outer shell layer of metal.
Claim 3
Dependent Claim 66 words
A thermal storage apparatus for transferring and storing heat energy to and from a heat transfer working fluid, comprising a generally spherically shaped hollow shell containing lithium hydride, wherein the hollow shell has a layered construction that is compatible with lithium hydride and free lithium on its inner surface, is impermeable to hydrogen and is compatible with the heat transfer working fluid on its outer surface.
Claim 4
Dependent Claim 66 words
A thermal storage apparatus for transferring and storing heat energy to and from a heat transfer working fluid, comprising a generally spherically shaped hollow shell containing lithium hydride, wherein the hollow shell has a layered construction that is compatible with lithium hydride and free lithium on its inner surface, is impermeable to hydrogen and is compatible with the heat transfer working fluid on its outer surface.
Claim 5
Dependent Claim 71 words
The thermal storage apparatus according to claim 2, wherein the hollow shell comprises: (a) an inner shell layer of metal compatible with lithium hydride and free lithium; (b) a middle shell layer of ceramic impermeable to free hydrogen; (c) an outer shell layer of metal compatible with the heat transfer working fluid; and, (d) wherein the coefficients of thermal expansion of the inner, middle and outer shell layers are generally similar.
Claim 6
Dependent Claim 35 words
The thermal storage apparatus according to claim 2, wherein the hollow shell comprises: (a) an inner shell layer of metal; (b) a middle shell layer of ceramic; and, (c) an outer shell layer of metal.
Claim 7
Dependent Claim 37 words
The thermal storage apparatus according to claim 2, wherein the hollow shell comprises: (a) an inner shell layer of refractory metal; (b) a middle shell layer of ceramic; and, (c) an outer shell layer of refractory metal.
Claim 8
Dependent Claim 32 words
The thermal storage apparatus according to claim 2, wherein: (a) the inner shell layer comprises molybdenum; (b) the middle shell layer comprises silicon carbide; and, (c) the outer shell layer comprises molybdenum.
Claim 9
Dependent Claim 55 words
The thermal storage apparatus according to claim 6, wherein: (a) the outer diameter of the hollow shell is about 2 cm; (b) the inner shell layer is about 0.1 mm thick; (c) the middle shell layer is about 0.3 to about 0.5 mm thick; and, (d) the outer shell layer is about 0.1 mm thick.
Claim 10
Dependent Claim 28 words
The thermal storage apparatus according to claim 2, wherein the lithium hydride is at about 60% of its theoretical maximum density at ambient temperatures inside the hollow shell.
Claim 11
Dependent Claim 69 words
A thermal storage system for transferring and storing heat energy to and from a heat transfer working fluid, comprising a packed array of generally spherically shaped hollow shells containing lithium hydride, wherein each hollow shell has a layered construction that is compatible with lithium hydride and free lithium on its inner surface, is impermeable to hydrogen and is compatible with the heat transfer working fluid on its outer surface.
Claim 12
Dependent Claim 69 words
A thermal storage system for transferring and storing heat energy to and from a heat transfer working fluid, comprising a packed array of generally spherically shaped hollow shells containing lithium hydride, wherein each hollow shell has a layered construction that is compatible with lithium hydride and free lithium on its inner surface, is impermeable to hydrogen and is compatible with the heat transfer working fluid on its outer surface.
Claim 13
Dependent Claim 71 words
The thermal storage system according to claim 9, wherein each hollow shell comprises: (a) an inner shell layer of metal compatible with lithium hydride and free lithium; (b) a middle shell layer of ceramic impermeable to free hydrogen; (c) an outer shell layer of metal compatible with the heat transfer working fluid; and, (d) wherein the coefficients of thermal expansion of the inner, middle and outer shell layers are generally similar.
Claim 14
Dependent Claim 35 words
The thermal storage system according to claim 9, wherein each hollow shell comprises: (a) an inner shell layer of metal; (b) a middle shell layer of ceramic; and, (c) an outer shell layer of metal.
Claim 15
Dependent Claim 37 words
The thermal storage system according to claim 9, wherein each hollow shell comprises: (a) an inner shell layer of refractory metal; (b) a middle shell layer of ceramic; and, (c) an outer shell layer of refractory metal.
Claim 16
Dependent Claim 32 words
The thermal storage system according to claim 12, wherein: (a) the inner shell layer comprises molybdenum; (b) the middle shell layer comprises silicon carbide; and, (c) the outer shell layer comprises molybdenum.
Claim 17
Dependent Claim 55 words
The thermal storage system according to claim 13, wherein: (a) the outer diameter of each hollow shell is about 3 cm; (b) each inner shell layer is about 0.1 mm thick; (c) each middle shell layer is about 0.3 to about 0.5 mm thick; and, (d) each outer shell layer is about 0.1 mm thick.
Claim 18
Dependent Claim 28 words
The thermal storage system according to claim 9, wherein the lithium hydride is at about 60% of its theoretical maximum density at ambient temperatures inside each hollow shell.
Claim 19
Independent Claim 82 words
A method of storing thermal energy, comprising the steps of: (a) encapsulating lithium hydride inside a plurality of generally spherical hollow shells, each shell comprising: (i) an inner shell layer of metal; (ii) a middle shell layer of ceramic; and, (iii) an outer shell layer of metal; (b) arranging the hollow capsules into a packed array; (c) providing a source of heat; and, (c) flowing a heat transfer working fluid from the source of heat through the packed array of hollow shells.
Claim 20
Independent Claim 82 words
A method of storing thermal energy, comprising the steps of: (a) encapsulating lithium hydride inside a plurality of generally spherical hollow shells, each shell comprising: (i) an inner shell layer of metal; (ii) a middle shell layer of ceramic; and, (iii) an outer shell layer of metal; (b) arranging the hollow capsules into a packed array; (c) providing a source of heat; and, (c) flowing a heat transfer working fluid from the source of heat through the packed array of hollow shells.
Claim 21
Dependent Claim 40 words
The method of storing thermal energy according to claim 16, wherein: (a) the inner shell layer of metal is molybdenum; (b) the middle shell layer of ceramic is silicon carbide; and, (c) the outer shell layer of metal is molybdenum.
Claim 22
Dependent Claim 58 words
A thermal storage apparatus for transferring and storing heat energy to and from a heat transfer working fluid, comprising a generally spherically shaped hollow shell containing a heat sink material, wherein the hollow shell comprises: (a) an inner shell layer of molybdenum; (b) a middle shell layer of silicon carbide; and, (c) an outer shell layer of molybdenum.
Claim 23
Dependent Claim 58 words
A thermal storage apparatus for transferring and storing heat energy to and from a heat transfer working fluid, comprising a generally spherically shaped hollow shell containing a heat sink material, wherein the hollow shell comprises: (a) an inner shell layer of molybdenum; (b) a middle shell layer of silicon carbide; and, (c) an outer shell layer of molybdenum.

References Cited (Backward Citations)

JPS5243153A Cited
US4355627A Cited
SU920349A1 Cited
US4361182A Cited
US4459976A Cited
SU1083068A1 Cited
US4513053A Cited
US4657067A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-03-06 1992-09-05 1993-03-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-03-06 1996-09-05 1997-03-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-03-06 2000-09-05 2001-03-07 $7700.00 Window Closed / Lapsed

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