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US4808686A Expired / Lapsed US ⏱️ 0.0 years remaining

Silicone-polyimides, and method for making

Assignee: General Electric Co
•
Filing: 1987-06-18
•
Granted: 1989-02-28
•
Expires: 2007-06-18
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Abstract

Abstract Silicone-polyimides having improved flexibility can be obtained, by sequentially intercondensing organic diamine, aminoorgano terminated polydiorganosiloxane and aromatic bisanhydride. A decrease in flexural modulus and an increase in elongation percent is effected while flame retardance remains substantially unchanged.

Inventors

  • 👤 James A. Cella
  • 👤 Patrick E. Gallagher
  • 👤 Gary K. Shank

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 10:34
CPC Classifications
H; H01; H01B; H01B3/00; H01B3/18; H01B3/30; H01B3/46; C; C08; C08G; C08G73/00; C08G73/06; C08G73/10; C08G73/1057; C08G73/106; C08G77/00; C08G77/42; C08G77/452; C08G77/455; H01B3/303; H01B3/306

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 53 words
Flame retardant extrudable silicone polyimide having improved flexibility and useful as a wire-coating insulator comprising by weight from about 40 to 90% of arylimide units chemically combined with from 10 to about 60% of polydiorganosiloxane having an elongation of at least 100% and a flexural modulus (psi) of from about 28,500 to 150,000.
Claim 2
Dependent Claim 53 words
Flame retardant extrudable silicone polyimide having improved flexibility and useful as a wire-coating insulator comprising by weight from about 40 to 90% of arylimide units chemically combined with from 10 to about 60% of polydiorganosiloxane having an elongation of at least 100% and a flexural modulus (psi) of from about 28,500 to 150,000.
Claim 3
Dependent Claim 48 words
A flame retardant extrudable silicone polyimide in accordance with claim 1, which is the condensation product of reaction of a mixture comprising aryl diamine, aromatic bisanhydride and a silicone polyimide oligomer having terminal anhydride groups and a degree of polymerization of from about 1.5 to 50 repeat units.
Claim 4
Dependent Claim 47 words
A flame retardant extrudable silicone polyimide in accordance with claim 1, which is the condensation product of reaction of a mixture comprising silicone diamine, aromatic bisanhydride and aryl polyimide oligomer having terminal anhydride groups and a degree of polymerization of from about 1.5 to 50 repeat units.
Claim 5
Dependent Claim 20 words
A silicone-polyimide in accordance with claim 1, which is the condensation production of reaction of at least two oligomeric imides.
Claim 6
Dependent Claim 17 words
A flame retardant extrudable silicone polyimide in accordance with claim 2, where the aryl diamine is metaphenylenediamine.
Claim 7
Dependent Claim 18 words
A flame retardant extrudable silicone polyimide in accordance with claim 3, where the silicone diamine is an aminopropylpolydimethylsiloxane.
Claim 8
Dependent Claim 21 words
A flame retardant extrudable silicone polyimide in accordance with claim 2, where the aromatic bisanhydride is a mixture of aromatic bisanhydrides.
Claim 9
Dependent Claim 20 words
A flame retardant extrudable silicone polyimide in accordance with claim 2, where the aromatic bisanhydride is an aromatic bis(ether anhydride).
Claim 10
Dependent Claim 18 words
A flame retardant extrudable silicone polyimide in accordance with claim 2, where the aromatic bisanhydride is 2,2-bis[4-(3,4-dicarboxyphenoxy)phenyl]propane dianhydride.
Claim 11
Dependent Claim 21 words
A flame retardant extrudable silicone polyimide in accordance with claim 3, where the aromatic bisanhydride is a mixture of aromatic bisanhydrides.
Claim 12
Dependent Claim 20 words
A flame retardant extrudable silicone polyimide in accordance with claim 3, where the aromatic bisanhydride is an aromatic bis(ether anhydride).
Claim 13
Dependent Claim 18 words
A flame retardant extrudable silicone polyimide in accordance with claim 3, where the aromatic bisanhydride is 2,2-bis[4-(3,4-dicarboxyphenoxy)phenyl]propane dianhydride.
Claim 14
Dependent Claim 8 words
A silicone-polyimide foam in accordance with claim 1.
Claim 15
Dependent Claim 8 words
A silicone-polyimide film in accordance with claim 1.
Claim 16
Dependent Claim 8 words
A silicone-polyimide fiber in accordance with claim 1.

References Cited (Backward Citations)

US4480009A Cited
US4504632A Cited
US4690997A Cited
US4586997A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-02-28 1992-08-29 1993-02-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-02-28 1996-08-29 1997-02-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-02-28 2000-08-29 2001-02-28 $7700.00 Window Closed / Lapsed

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