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US4803244A
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Process for the preparation of thermoplastic elastomers
Assignee: Union Carbide Corp
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Filing: 1987-11-16
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Granted: 1989-02-07
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Expires: 2007-11-16
Abstract
Abstract A process for the preparation of a thermoplastic elastomer comprising admixing, under reaction conditions, an unsaturated elastomer containing carbon-carbon double bonds; an essentially saturated thermoplastic homopolymer or copolymer; a multifunctional organosilicon compound containing an average of at least two Si-H groups per molecules; and a catalyst capable of hydrosilylating the carbon-carbon double bonds of the unsaturated elastomer.
Inventors
- 👤 Jeffrey D. Umpleby
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 21:15
CPC Classifications
C; C08; C08L; C08L23/00; C08L23/02; C08L23/16; C08F; C08F8/00; C08F8/42; C08J; C08J3/00; C08J3/005; C08K; C08K5/00; C08K5/54; C08L21/00; C08L23/18; C08L23/20; C08L23/22; C08J2321/00; C08L2207/00; C08L2207/04; C08L23/04; C08L23/10; C08L23/12; C08L83/00; C08L83/04; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31652; Y10T428/31663
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
56 words
A process for the preparation of a thermoplastic elastomer comprising admixing, under reaction conditions, an elastomer containing carbon-carbon double bonds; an essentially saturated thermoplastic homopolymer or copolymer; a multifunctional organosilicon compound containing an average of at least two Si--H groups per molecule; and a catalyst capable of hydrosilylating the carbon-carbon double bonds of the unsaturated elastomer.
Claim 2
Dependent Claim
56 words
A process for the preparation of a thermoplastic elastomer comprising admixing, under reaction conditions, an elastomer containing carbon-carbon double bonds; an essentially saturated thermoplastic homopolymer or copolymer; a multifunctional organosilicon compound containing an average of at least two Si--H groups per molecule; and a catalyst capable of hydrosilylating the carbon-carbon double bonds of the unsaturated elastomer.
Claim 3
Dependent Claim
20 words
The process defined in claim 1 wherein the elastomer contains at least one carbon-carbon double bond per 1000 carbon atoms.
Claim 4
Dependent Claim
18 words
The process defined in claim 1 wherein the elastomer has a molecular weight of at least about 100,000.
Claim 5
Dependent Claim
70 words
The process defined in claim 1 wherein the multifunctional organosilicon compound is a polysiloxane compound or mixture of polysiloxane compounds containing an average of at least two Si--H groups per molecule comprised essentially of 2 to about 100 siloxane units having the formulae: ##STR4## and 0 to about 5 siloxane units having the formulae: ##STR5## in any sequence or combination and having terminal groups which are hydroxy, alkoxy, or trimethylsiloxy.
Claim 6
Dependent Claim
36 words
The process defined in claim 1 wherein the amount of multifunctional organosilicon compound is in the range of about 0.01 to about 5 mole equivalents of Si--H groups per one mole equivalent of carbon-carbon double bonds.
Claim 7
Dependent Claim
36 words
The process defined in claim 1 wherein the amount of multifunctional organosilicon compound is in the range of about 0.25 to about 2 mole equivalents of Si--H groups per one mole equivalent of carbon-carbon double bonds.
Claim 8
Dependent Claim
20 words
The process defined in claim 1 wherein the hydrosilylation catalyst is an organometallic complex of a Group VIII transition metal.
Claim 9
Dependent Claim
16 words
The process defined in claim 7 wherein the transition metal is rhodium, platinum, palladium, or nickel.
Claim 10
Dependent Claim
34 words
The process defined in claim 1 wherein the amount of hydrosilylation catalyst is in the range of about 5 to about 10,000 parts per million by weight based on the weight of the elastomer.
Claim 11
Dependent Claim
34 words
The process defined in claim 1 wherein the amount of hydrosilylation catalyst is in the range of about 20 to about 1000 parts per million by weight based on the weight of the elastomer.
Claim 12
Dependent Claim
31 words
The process defined in claim 1 wherein the thermoplastic homopolymer or copolymer is polyethylene, polypropylene, or a copolymer of ethylene and at least one alpha-olefin having 3 to 12 carbon atoms.
Claim 13
Dependent Claim
27 words
The process defined in claim 1 wherein the components are mixed at a temperature of at least about the melting point of the thermoplastic homopolymer or copolymer.
Claim 14
Dependent Claim
9 words
The product of the process defined in claim 1.
Claim 15
Dependent Claim
10 words
An extruded article comprising the product defined in claim 13.
Claim 16
Dependent Claim
14 words
An extrusion coated article wherein the coating is the product defined in claim 13.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1992-02-07 | 1992-08-08 | 1993-02-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-02-07 | 1996-08-08 | 1997-02-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-02-07 | 2000-08-08 | 2001-02-07 | $7700.00 | Window Closed / Lapsed |