US4797437A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Thermoplastic elastomer
Assignee: Hoechst Celanese Chemical Co
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Filing: 1983-12-01
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Granted: 1989-01-10
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Expires: 2003-12-01
Abstract
Abstract Segmented thermoplastic copolyester elastomers containing recurring polymeric long chain ester units derived from phthalic acids and long chain glycols and short chain ester units derived from phthalic acids and 1,4-butanediol or 1,4-butenediol. The elastomers also contain polyvinylpyrrolidone and preferably also contain guanidine stabilizer, phosphorus stabilizer and diphenylamine.
Inventors
- 👤 Michael D. Golder
- 👤 Stanley J. Gromelski, Jr.
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 22:23
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/16; C08K5/315; C08K5/17; C08K5/18; C08K5/49; C08K5/51; C08K5/52; C08K5/524; C08L; C08L67/00; C08L67/02; C08L67/025
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
303 words
Thermoplastic elastomer composition consisting essentially of: (a) segmented thermoplastic copolyester elastomer consisting essentially of a multiplicity of recurring long chain ester units and short chain ester units joined head to tail through ester linkages, said long chain units being represented by the formula ##STR10## and said short chain units being represented by the formula ##STR11## where G is a divalent radical remaining after the removal of the terminal hydroxyl groups from a difunctional polyether glycol having a number average molecular weight in the range from about 400 to about 6,000, R is a hydrocarbon radical remaining after removal of the carboxyl groups from terephthalic acid or isophthalic acid, and D is a divalent radical remaining after removal of hydroxyl groups from 1,4-butanediol or 1,4-butenediol; provided, said short chain units amount to between about 30% and about 85% by weight of the copolyester; (b) between about 0.1 and about 25% by weight of said polyester of polyvinylpyrrolidone having a K value not exceeding about 30; (c) between about 0.05 and about 5% by weight of said copolyester of cyanoguanidine or guanidine stabilizer of the formula ##STR12## where n is an integer between 2 and about 20; (d) between about 0.1 and about 5% by weight of said copolyester of diphenylamine derivative of the formula ##STR13## where R and R 1 are methyl or phenyl; and (e) between 0.05 and about 3% by weight of said copolyester of phosphorus compound of the formula ##STR14## where each of R and R 1 independently represents a hydrocarbon radical selected from the group consisting of alkyl, aryl and alkyl/aryl hydrocarbon radicals having from 1 to about 22 carbon atoms and R 3 represents hydrogen or a hydrocarbon radical selected from the group consisting of alkyl, aryl and alkyl/aryl hydrocarbon radicals having from 1 to about 22 carbon atoms.
Claim 2
Dependent Claim
303 words
Thermoplastic elastomer composition consisting essentially of: (a) segmented thermoplastic copolyester elastomer consisting essentially of a multiplicity of recurring long chain ester units and short chain ester units joined head to tail through ester linkages, said long chain units being represented by the formula ##STR10## and said short chain units being represented by the formula ##STR11## where G is a divalent radical remaining after the removal of the terminal hydroxyl groups from a difunctional polyether glycol having a number average molecular weight in the range from about 400 to about 6,000, R is a hydrocarbon radical remaining after removal of the carboxyl groups from terephthalic acid or isophthalic acid, and D is a divalent radical remaining after removal of hydroxyl groups from 1,4-butanediol or 1,4-butenediol; provided, said short chain units amount to between about 30% and about 85% by weight of the copolyester; (b) between about 0.1 and about 25% by weight of said polyester of polyvinylpyrrolidone having a K value not exceeding about 30; (c) between about 0.05 and about 5% by weight of said copolyester of cyanoguanidine or guanidine stabilizer of the formula ##STR12## where n is an integer between 2 and about 20; (d) between about 0.1 and about 5% by weight of said copolyester of diphenylamine derivative of the formula ##STR13## where R and R 1 are methyl or phenyl; and (e) between 0.05 and about 3% by weight of said copolyester of phosphorus compound of the formula ##STR14## where each of R and R 1 independently represents a hydrocarbon radical selected from the group consisting of alkyl, aryl and alkyl/aryl hydrocarbon radicals having from 1 to about 22 carbon atoms and R 3 represents hydrogen or a hydrocarbon radical selected from the group consisting of alkyl, aryl and alkyl/aryl hydrocarbon radicals having from 1 to about 22 carbon atoms.
Claim 3
Dependent Claim
20 words
Elastomer according to claim 1 wherein the D groups represent divalent radicals remaining after removal of hydroxyl groups from 1,4-butanediol.
Claim 4
Dependent Claim
27 words
Elastomer according to claim 1 wherein between about 10% and about 40% of the D groups represent divalent radicals remaining after removal of hydroxyl groups from 1,4-butenediol.
Claim 5
Dependent Claim
12 words
Elastomer composition according to claim 3 wherein the guanidine stabilizer is cyanoguanidine.
Claim 6
Dependent Claim
106 words
Elastomer composition according to claim 3 wherein: (a) G is a divalent radical remaining after removal of terminal hdroxy groups from a difunctional polyether glycol having a carbon to oxygen ratio between about 2.5 and about 4.3 to 1; (b) at least about 80% of the R groups of formulas I and II are hydrocarbon radicals remaining after removal of carboxyl groups from terephthalic acid; (c) the short chain units amount to between about 40 and about 65% by weight of the copolyester; and (d) between about 20 and about 30% of the D groups represent divalent radicals remaining after removal of hydroxyl groups from 1,4-butenediol.
Claim 7
Dependent Claim
23 words
Elastomer composition according to claim 5 wherein G is a divalent radical remaining after removal of terminal hydroxy groups from poly(tetramethylene oxide) glycol.
Claim 8
Dependent Claim
30 words
Elastomer composition according to claim 3 which also includes between about 0.1% and about 5% by weight of said copolyester of 3,5-di-tert butyl-4-hydroxyhydrocinnamic acid triester with 1,3,5-tris(2-hydroxyethyl)-s-triazine-2,4,6-(1H, 3H, 5H) trione.
Claim 9
Dependent Claim
153 words
Elastomer composition according to claim 1 wherein (a) G is a divalent radical remaining after removal of terminal hydroxyl groups from poly(tetramethylene oxide) glycol; (b) at least about 80% of the R groups of formulas I and II are hydrocarbon radicals remaining after removal of carboxyl groups from terephthalic acid; (c) the short chain units axount to between about 40 and about 65% by weight of the copolyester; (d) between about 20 and about 30% of the D groups represent divalent rdicals remaining after removal of hydroxyl groups from 1,4-butenediol; (e) the elastomer composition also includes between about 0.1% and about 5% by weight of said copolyester of 3,5-di-tert-butyl-4-hydroxy hydrocinnamic acid triester with 1,3,5-tris-(2-hydroxyethyl)-s-triazine-2,4,6-(1H, 3H, 5H) trione; (f) plyvinylpyrrolidone is present in an amount between about 0.5 and about 15 wt % based on copolyester and has a K value between about 0.5 and about 20; and (g) the guanidine stabilizer is cyanoguanidine.
Claim 10
Dependent Claim
155 words
Elastomer composition according to claim 1 wherein: (a) G is a divalent radical remaining after removal of terminal hydroxyl groups from poly(tetramethylene oxide) glycol; (b) at least about 80% of the R groups of formulas I and II are hydrocarbon radicals remaining after removal of carboxyl groups from terephthalic acid; (c) the short chain units amount to between about 40 and about 65% by weight of the copolyester; (d) between about 20 and about 30% of the D groups represent divalent radicals remaining after removal of hydroxyl groups from 1,4-butenediol; (e) the elastomer composition also includes between about 0.1% and about 5% by weight of said copolyester of 3,5-di-tert-butyl-4-hydroxy hydrocinnamic acid triester with 1,3,5-tris (2-hydroxyethyl)-s-triazine-2,4,6-(1H, 3H, 5H) trione; (f) polyvinylpyrrolidone is present in an amount between about 0.5 and about 15 wt % based on copolyester and has a K value between about 0.5 and about 20; (g) the guanidine stabilizer is 1,6 hexamethylene bis-dicyandiamide.
Claim 11
Dependent Claim
12 words
Elastomer according to claim 3 wherein the guanidine stabilizer is 1,6 hexamethylene-bis-dicyandiamide.
References Cited (Backward Citations)
US2882255A
Cited
US3524832A
Cited
US3513134A
Cited
US3640929A
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US3825620A
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US3856749A
Cited
US4048128A
Cited
US4315882A
Cited
US4221703A
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US4247427A
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US4355155A
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US4405749A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1992-01-10 | 1992-07-11 | 1993-01-10 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-01-10 | 1996-07-11 | 1997-01-10 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-01-10 | 2000-07-11 | 2001-01-10 | $7700.00 | Window Closed / Lapsed |